2-(4-(10,10-dimethyl-10H-indeno[2,1-b]triphenylen-12-yl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2-(4-(10,10-dimethyl-10H-indeno[2,1-b]triphenylen-12-yl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• 英文别名: 2-[4-(18,18-dimethyl-20-hexacyclo[12.11.0.02,7.08,13.016,24.017,22]pentacosa-1(25),2,4,6,8,10,12,14,16,19,21,23-dodecaenyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• 化学式: C₃₉H₃₅BO₂
• 分子量: 546.517
• InChiKey: QNYSIBKZTKHBCY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.44
• 重原子数：
  42
• 可旋转键数：
  2
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  12-(7-bromo-9,9-dimethyl-9H-fluoren-2-yl)-10,10-dimethyl-10H-indeno[2,1-b]triphenylene 、 2-(4-(10,10-dimethyl-10H-indeno[2,1-b]triphenylen-12-yl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 在 四(三苯基膦)钯 、 sodium carbonate 作用下， 以 乙醇 、 甲苯 为溶剂， 反应 24.0h， 以61%的产率得到12-(4-(7-(10,10-dimethyl-10H-indeno[2,1-b]triphenylene-12-yl)-9,9-dimethyl-9H-fluoren-2-yl)phenyl)-10,10-dimethyl-10H-indeno[2,1-b]triphenylene
  参考文献：
  名称：

  FLUORENE COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME

  摘要：

  本发明公开了一种新的芴化合物以及使用该化合物的有机EL器件。采用新的芴化合物作为主体材料的有机EL器件可以降低驱动电压，延长半寿命。芴化合物可以作为发光层的蓝色发射主体材料，并提高蓝色发射器件的CIE色纯度。芴化合物由以下式(A)表示：其中R1至R6相同或不同。R1至R6独立地选自氢原子、卤素、具有1至20个碳原子的烷基基团、具有6至30个碳原子的取代或未取代芳基团、具有6至30个碳原子的取代或未取代芳基烷基基团、具有6至30个碳原子的取代或未取代杂环芳基团的组成。R7至R13相同或不同，R7至R13独立地选自氢原子、卤素、烷基基团、芳基团、杂环芳基团。m和n分别是0到3的整数，X选自碳或氮。

  公开号：

  US20140151645A1
• 作为产物：
  描述：

  2-联苯硼酸 在 iron(III) chloride 、 四(三苯基膦)钯 、 potassium acetate 、 sodium carbonate 作用下， 以 1,4-二氧六环 、 乙醇 、 二氯甲烷 、 甲苯 为溶剂， 反应 65.0h， 生成 2-(4-(10,10-dimethyl-10H-indeno[2,1-b]triphenylen-12-yl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
  参考文献：
  名称：

  FLUORENE COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME

  摘要：

  本发明公开了一种新的芴化合物以及使用该化合物的有机EL器件。采用新的芴化合物作为主体材料的有机EL器件可以降低驱动电压，延长半寿命。芴化合物可以作为发光层的蓝色发射主体材料，并提高蓝色发射器件的CIE色纯度。芴化合物由以下式(A)表示：其中R1至R6相同或不同。R1至R6独立地选自氢原子、卤素、具有1至20个碳原子的烷基基团、具有6至30个碳原子的取代或未取代芳基团、具有6至30个碳原子的取代或未取代芳基烷基基团、具有6至30个碳原子的取代或未取代杂环芳基团的组成。R7至R13相同或不同，R7至R13独立地选自氢原子、卤素、烷基基团、芳基团、杂环芳基团。m和n分别是0到3的整数，X选自碳或氮。

  公开号：

  US20140151645A1

文献信息

• Fluorene compound and organic electroluminescent device using the same
  申请人：Yen Feng-Wen

  公开号：US09040174B2

  公开（公告）日：2015-05-26

  The present invention discloses a new fluorene compound and organic EL device using the compound. The organic EL device employing the new fluorene compound as host material can lower driving voltage, prolong half-lifetime. The fluorene compound can functions as blue emitting host material of a light emitting layer and improve CIE color purity in blue emitting device. The fluorene compound are represented by the following formula(A): Wherein R1 to R6 are identical or different. R1 to R6 are independently selected from the group consisting of a hydrogen atom, a halide, alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 6 to 30 carbon atoms. R7˜R13 are identical or different R7 to R13 are independently selected from the group consisting of hydrogen atom, halide, alkyl group, aryl group, heteroaryl group. m and n are independently an integer of 0 to 3, X is selected from carbon or nitrogen.

  本发明揭示了一种新的芴化合物和使用该化合物的有机EL器件。采用新的芴化合物作为主体材料的有机EL器件可以降低驱动电压，延长半寿命。芴化合物可以作为发光层的蓝色发射主体材料，并提高蓝色发射器件的CIE色彩纯度。芴化合物的结构式为(A)，其中R1至R6相同或不同。R1至R6独立地选自以下组中的一种：氢原子、卤素、具有1至20个碳原子的烷基、具有6至30个碳原子的取代或未取代芳基、具有6至30个碳原子的取代或未取代芳基烷基、具有6至30个碳原子的取代或未取代杂环芳基。R7至R13相同或不同，R7至R13独立地选自以下组中的一种：氢原子、卤素、烷基、芳基、杂环芳基。m和n分别是0至3的整数，X选自碳或氮。
• MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：LUMINESCENCE TECHNOLOGY CORPORATION

  公开号：US20140175384A1

  公开（公告）日：2014-06-26

  The present invention discloses a novel material is represented by the following formula (A), the organic EL device employing the material as blue emitting layer can lower driving voltage, prolong half-lifetime and increase the efficiency. Wherein m represent an integer of 0 to 4, R 1 and R 2 are identical or different. R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms. R 3 and R 4 are identical or different, R 3 and R 4 are independently selected from the group consisting of hydrogen atom, a halide, a substituted or unsubstituted arylamine, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms.

  本发明公开了一种新型材料，其由以下式（A）所表示，采用该材料作为蓝色发射层的有机EL器件可以降低驱动电压，延长半寿命并增加效率。其中m表示0到4的整数，R1和R2相同或不同。R1和R2独立地选自由1到20个碳原子的烷基，具有6到30个碳原子的取代或未取代芳基，具有6到30个碳原子的取代或未取代芳基烷基的群。R3和R4相同或不同，R3和R4独立地选自氢原子，卤素，取代或未取代芳基胺，具有1到20个碳原子的取代或未取代烷基，具有6到30个碳原子的取代或未取代芳基的群。
• Material for organic electroluminescent device
  申请人：Luminescence Technology Corporation

  公开号：US08962160B2

  公开（公告）日：2015-02-24

  The present invention discloses a novel material is represented by the following formula (A), the organic EL device employing the material as blue emitting layer can lower driving voltage, prolong half-lifetime and increase the efficiency. Wherein m represent an integer of 0 to 4, R1 and R2 are identical or different. R1 and R2 are independently selected from the group consisting of a hydrogen atom, alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms. R3 and R4 are identical or different, R3 and R4 are independently selected from the group consisting of hydrogen atom, a halide, a substituted or unsubstituted arylamine, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms.

  本发明揭示了一种由以下公式（A）表示的新材料，采用该材料作为蓝色发射层的有机EL器件可以降低驱动电压，延长半衰期并提高效率。其中m表示0至4的整数，R1和R2相同或不同。R1和R2独立地选自由1至20个碳原子的烷基，具有6至30个碳原子的取代或未取代的芳基，具有6至30个碳原子的取代或未取代的芳基烷基。R3和R4相同或不同，R3和R4独立地选自氢原子，卤素，取代或未取代的芳基胺，具有1至20个碳原子的取代或未取代的烷基，具有6至30个碳原子的取代或未取代的芳基。
• FLUORENE COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
  申请人：YEN FENG-WEN

  公开号：US20140151645A1

  公开（公告）日：2014-06-05

  The present invention discloses a new fluorene compound and organic EL device using the compound. The organic EL device employing the new fluorene compound as host material can lower driving voltage, prolong half-lifetime. The fluorene compound can functions as blue emitting host material of a light emitting layer and improve CIE colour purity in blue emitting device. The fluorene compound are represented by the following formula(A): Wherein R 1 to R 6 are identical or different. R 1 to R 6 are independently selected from the group consisting of a hydrogen atom, a halide, alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 6 to 30 carbon atoms. R 7 ˜R 13 are identical or different R 7 to R 13 are independently selected from the group consisting of hydrogen atom, halide, alkyl group, aryl group, heteroaryl group. m and n are independently an integer of 0 to 3, X is selected from carbon or nitrogen.

  本发明公开了一种新的芴化合物以及使用该化合物的有机EL器件。采用新的芴化合物作为主体材料的有机EL器件可以降低驱动电压，延长半寿命。芴化合物可以作为发光层的蓝色发射主体材料，并提高蓝色发射器件的CIE色纯度。芴化合物由以下式(A)表示：其中R1至R6相同或不同。R1至R6独立地选自氢原子、卤素、具有1至20个碳原子的烷基基团、具有6至30个碳原子的取代或未取代芳基团、具有6至30个碳原子的取代或未取代芳基烷基基团、具有6至30个碳原子的取代或未取代杂环芳基团的组成。R7至R13相同或不同，R7至R13独立地选自氢原子、卤素、烷基基团、芳基团、杂环芳基团。m和n分别是0到3的整数，X选自碳或氮。