(Z,Z)-2,5-di(9-oxo-9,10-dihydro-10-phenanthrylidene)-2,5-dihydrothiophene

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: (Z,Z)-2,5-di(9-oxo-9,10-dihydro-10-phenanthrylidene)-2,5-dihydrothiophene
• 英文别名: (10Z)-10-[(5Z)-5-(10-oxophenanthren-9-ylidene)thiophen-2-ylidene]phenanthren-9-one
• 化学式: C₃₂H₁₈O₂S
• 分子量: 466.56
• InChiKey: NNBYRYAWLNNQSP-ZUELCTOOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  35
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  59.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (Z,Z)-2,5-di(9-oxo-9,10-dihydro-10-phenanthrylidene)-2,5-dihydrothiophene 、 乙酸酐 在 三乙胺 、 锌 作用下， 反应 0.75h， 生成 Acetic acid 10-[5-(10-acetoxy-phenanthren-9-yl)-thiophen-2-yl]-phenanthren-9-yl ester
  参考文献：
  名称：

  Coloured products from thiophene and aromatic 1,2-diketones

  摘要：

  Thiophene and phenanthrene-9,10-quinone react in acidic solution to produce the deep blue extended quinone (Z,Z)-2,5-di(9-oxo-9,10-dihydro-10-phenanthrylidene)-2,5-dihydrothiophene the structure of which is confirmed by X-ray crystallography. Other aromatic 1,2-diketones give rise to related products. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2004.07.066
• 作为产物：
  描述：

  噻吩 、 菲醌 在 硫酸 作用下， 以 溶剂黄146 为溶剂， 反应 4.0h， 以47%的产率得到(Z,Z)-2,5-di(9-oxo-9,10-dihydro-10-phenanthrylidene)-2,5-dihydrothiophene
  参考文献：
  名称：

  Coloured products from thiophene and aromatic 1,2-diketones

  摘要：

  Thiophene and phenanthrene-9,10-quinone react in acidic solution to produce the deep blue extended quinone (Z,Z)-2,5-di(9-oxo-9,10-dihydro-10-phenanthrylidene)-2,5-dihydrothiophene the structure of which is confirmed by X-ray crystallography. Other aromatic 1,2-diketones give rise to related products. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2004.07.066

文献信息

• Coloured products from thiophene and aromatic 1,2-diketones
  作者：William T.A. Harrison、Brian J. Morrison、Oliver C. Musgrave

  DOI：10.1016/j.tet.2004.07.066

  日期：2004.10

  Thiophene and phenanthrene-9,10-quinone react in acidic solution to produce the deep blue extended quinone (Z,Z)-2,5-di(9-oxo-9,10-dihydro-10-phenanthrylidene)-2,5-dihydrothiophene the structure of which is confirmed by X-ray crystallography. Other aromatic 1,2-diketones give rise to related products. (C) 2004 Elsevier Ltd. All rights reserved.