1,2,3,4,11,12-hexahydrochrysene

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 1,2,3,4,11,12-hexahydrochrysene
• 化学式: C₁₈H₁₈
• 分子量: 234.341
• InChiKey: QBVHQMWGHQXEKI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  屈 在 四乙基溴化铵 作用下， 以 乙醇 为溶剂， 以21%的产率得到5,6-dihydrochrysene
  参考文献：
  名称：

  Electroreduction of organic compounds. 28. Partial Hydrogenation of Polycyclic Aromatic Hydrocarbons by electroreduction in protic solvents

  摘要：

  Polycyclic aromatic hydrocarbons (PAH) such as anthracene (1), phenanthrene (5), acenaphthylene (15), pyrene (17), chrysene (22), and fluoranthene (28) are selectively hydrogenated upon electroreduction at a lead cathode in ethanolic solution. The degree of hydrogenation and the structure of the products depend on the reaction conditions, in particular on the applied reduction potential.

  DOI：

  10.1002/prac.19963380166

文献信息

• Electroreduction of organic compounds. 28. Partial Hydrogenation of Polycyclic Aromatic Hydrocarbons by electroreduction in protic solvents
  作者：S. Anowski、J. Voss

  DOI：10.1002/prac.19963380166

  日期：——

  Polycyclic aromatic hydrocarbons (PAH) such as anthracene (1), phenanthrene (5), acenaphthylene (15), pyrene (17), chrysene (22), and fluoranthene (28) are selectively hydrogenated upon electroreduction at a lead cathode in ethanolic solution. The degree of hydrogenation and the structure of the products depend on the reaction conditions, in particular on the applied reduction potential.