3,3,6,6-tetramethyl-1,2,3,4,5,6,7,8-octahydroacridine-1,8-dione dioxime

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 3,3,6,6-tetramethyl-1,2,3,4,5,6,7,8-octahydroacridine-1,8-dione dioxime
• 英文别名: N-(8-hydroxyimino-3,3,6,6-tetramethyl-2,4,5,7-tetrahydroacridin-1-ylidene)hydroxylamine
• 化学式: C₁₇H₂₃N₃O₂
• 分子量: 301.389
• InChiKey: LINIWRGLYMGZEX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  22
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.59
• 拓扑面积：
  78.1
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  3-氨基-5,5-二甲基-2-环己烯-1-酮 在 盐酸羟胺 、 sodium acetate 、 phosphorus pentoxide 作用下， 以 异丙醇 为溶剂， 生成 3,3,6,6-tetramethyl-1,2,3,4,5,6,7,8-octahydroacridine-1,8-dione dioxime
  参考文献：
  名称：

  摘要：

  DOI：

  10.1023/a:1013845426393

文献信息

• Synthesis and transformations of new 1,2,3,4,5,6,7,8,9,10-decahydroacridine-1,8-dione derivatives
  作者：A. N. Pyrko

  DOI：10.1134/s1070428008080198

  日期：2008.8

  Reactions of cyclohexane-1,3-diones with amines and aldehydes led to the formation of 1,21,3,4,5,16,7,8,9, 10-decahydroacridine-1,8-diones containing alkylaryl, aryl, and hydroxy substituents in position 10. Transformations of 10-hydroxy-1,2,3,4,5,6,7,8,9,10-decahydroacridine-1,8-diones under oxidation with nitrous acid, reduction with zinc powder, as well as on heating in aprotic solvents and acetic, phosphoric, and polyphosphoric acids, were studied. NMR spectra of 1,2,3,4,5,6,7,8,9,10-decaliydroacridine-1,8-diones having different substituents in positions 9 and 10 were analyzed.
• Transformations of sym-octahydroxanthene-1,8-diones and 1,8-dioxo-sym-octahydroxanthylium salts in recyclization under the influence of amines
  作者：Yu. M. Shchekotikhin、T. G. Nikolaeva

  DOI：10.1007/s10593-006-0042-1

  日期：2006.1
• ——
  作者：Yu. M. Shchekotikhin、Yu. A. Getmanenko、T. G. Nikolaeva、A. P. Kriven'ko

  DOI：10.1023/a:1013845426393

  日期：——