(+)-N,N-二烯丙基酒石酸二酰胺 | 28843-34-7

• 物质功能分类: 生物 - 生化试剂盒
• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: (+)-N,N-二烯丙基酒石酸二酰胺
• 中文别名: (+)-N,Nˊ-二烯丙基酒石酸二酰胺
• 英文名称: (-)-N,N-diallyltartramide
• 英文别名: N,N'-Diallyltartramide；2,3-dihydroxy-N,N'-bis(prop-2-enyl)butanediamide
• CAS: 28843-34-7
• 化学式: C₁₀H₁₆N₂O₄
• mdl: MFCD00065384
• 分子量: 228.248
• InChiKey: ZRKLEAHGBNDKHM-UHFFFAOYSA-N

物化性质

• 熔点：
  184.5°C
• 沸点：
  370.05°C (rough estimate)
• 密度：
  1.2265 (rough estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  -1.1
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  98.7
• 氢给体数：
  4
• 氢受体数：
  4

安全信息

• 危险品标志：
  Xi
• 安全说明：
  S26,S37/39
• 危险类别码：
  R36/37/38
• 海关编码：
  2924199090

SDS

Name:	N N -Diallyltartardiamide 99+% Material Safety Data Sheet
Synonym:	N,N'-Diallyltartramide
CAS:	28843-34-7

Section 1 - Chemical Product MSDS Name:N N -Diallyltartardiamide 99+% Material Safety Data Sheet
Synonym:N,N'-Diallyltartramide

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
28843-34-7	N,N'-Diallyltartardiamide	99+%	249-267-7

Hazard Symbols: None Listed.
Risk Phrases: None Listed.

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

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Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 28843-34-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Flakes
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 186.00 - 188.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C10H16N2O4
Molecular Weight: 228.25

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 28843-34-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N,N'-Diallyltartardiamide - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 28843-34-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 28843-34-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 28843-34-7 is not listed on the TSCA inventory.
It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  (+)-N,N-二烯丙基酒石酸二酰胺 、 对叔丁基苯甲酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 生成 O,O'-di-tert-butylbenzoyl-L-diallyltartramide
  参考文献：
  名称：

  Crosslinked three-dimensional polymer network, method for preparing same, support material comprising same and uses thereof

  摘要：

  该发明涉及一种交联的具有光学活性的三维聚合物网络，由第一选择器的同手性单元和至少一种与第一选择器结构不同的第二选择器的同手性单元组成，第一选择器的同手性单元包括至少三个可聚合或交联的官能团，而第二选择器的同手性单元包括至少两个可聚合或交联的官能团，这些同手性基团在化学上相互结合。该发明还涉及制备这种聚合物网络的方法及其用途。

  公开号：

  US20040260081A1

文献信息

• Superporous Hydrogels for Heavy-Duty Applications
  申请人：Omidian Hossein

  公开号：US20080089940A1

  公开（公告）日：2008-04-17

  The present invention features modified superporous hydrogels (SPHs) and methods for their formation. The SPHs of the present invention are prepared by careful selection of the hydrophobic/hydrophilic reactive ingredients and by harmonizing the foaming and polymerization reactions, which results in the formation of SPHs having a homogeneous structure and favorable physical and mechanical properties, including swelling, strength, ruggedness, and resiliency. The SPHs of the present invention are particularly useful when employed in very harsh swelling environments, such as the low pH environment of the gastric fluid of the stomach, for extended periods of time.

  本发明涉及改性超多孔水凝胶（SPHs）及其制备方法。本发明的SPHs通过精选疏水/亲水反应成分并协调发泡和聚合反应制备而成，从而形成具有均匀结构和良好物理和机械性能的SPHs，包括膨胀性、强度、坚固性和弹性。本发明的SPHs在非常恶劣的膨胀环境中特别有用，如胃液的低pH环境，在较长时间内使用。
• Encapsulation of emulsions
  申请人：——

  公开号：US20040043078A1

  公开（公告）日：2004-03-04

  Processes for encapsulating emulsions comprise: (a) providing e a mixture of (i) a polymerizable emulsifier, (ii) at least one polyfunctional comonomer, (iii) at least one hydrophilic component, and (iv) at least one hydrophobic component; and (b) polymerizing the mixture.

  封装乳液的过程包括：(a)提供一个混合物，包括(i)可聚合的乳化剂，(ii)至少一种多官能团共聚物，(iii)至少一种亲水性成分，以及(iv)至少一种疏水性成分；以及(b)聚合混合物。
• Surfactant-Based Monolithic Columns, Methods for Making the Same, and Method for Using the Same
  申请人：Shamsi Shahab Ahmed

  公开号：US20110086409A1

  公开（公告）日：2011-04-14

  A method for making a surfactant-based monolithic column is provided. The method comprises providing a mixture comprising at least one surfactant monomer, at least one crosslinker, at least one initiator, and at least one porogen and polymerizing the mixture to form the surfactant-based monolithic column. The present disclosure also provides a surfactant-based monolithic column, a method for separating molecules, and a process for preparing a surfactant monomer.

  提供了一种制备基于表面活性剂的单体柱的方法。该方法包括提供一种混合物，其中包括至少一种表面活性剂单体、至少一种交联剂、至少一种引发剂和至少一种孔原。将该混合物聚合成表面活性剂基的单体柱。本公开还提供了一种基于表面活性剂的单体柱、分离分子的方法和制备表面活性剂单体的过程。
• NANOPOROUS AND MICROPOROUS SOLVOGELS AND NONOLATEXES BY MICROEMULSION POLYMERIZATION
  申请人：Yan Feng

  公开号：US20090176915A1

  公开（公告）日：2009-07-09

  The present invention relates to microemulsions of immiscible fluids stabilized by reactive ionic liquid surfactant wherein the ionic liquid surfactant has a melting point less than 80° C. The invention also relates to composite materials comprising a copolymer of ethylenically reactive species, wherein one of the species is a reactive ionic liquid surfactant having a melting point less than 80° C., and wherein the material also comprises non-reactive Class I fluid. The invention further relates to methods for synthesizing the composite materials comprising preparing a microemulsion of immiscible Class I fluid and Class II fluid stabilized by reactive ionic liquid surfactant wherein the ionic liquid surfactant has a melting point less than 80° C., and polymerizing the microemulsion to form a composite material.

  本发明涉及由具有熔点低于80°C的反应性离子液体表面活性剂稳定的不相容流体的微乳液。本发明还涉及复合材料，包括乙烯基反应性物种的共聚物，其中一种物种是具有熔点低于80°C的反应性离子液体表面活性剂，并且该材料还包括非反应性的一类流体。本发明还涉及制备复合材料的方法，包括制备由具有熔点低于80°C的反应性离子液体表面活性剂稳定的不相容的一类流体和二类流体的微乳液，并聚合微乳液以形成复合材料。
• Nouveaux copolymères hydrophiles à base de N- tris (hydroxyméthyl) méthyl acrylamide, procédés pour leur préparation, gels aqueux desdits copolymères et leur utilisation comme échangeurs d'ions
  申请人：PHARMUKA LABORATOIRES

  公开号：EP0040124A1

  公开（公告）日：1981-11-18

  Copolymères statistiques réticulés tridimensionnels, insolubles dans l'eau, contenant sous forme copolymérisée: a) 25% à 98 % en poids de N-[tris(hydroxyméthyl)méthyl]acrylamide ou de N-[tris(hydroxyméthyl)méthyl]méthacrylamide, ou d'un mélange de ces deux composés, b) 2%à 50%en poids d'un ou plusieurs monomères possédant plusieurs doubles liaisons éthyléniques polymérisables et exempts de groupes fonctionnels anioniques ou cationiques, c) 0,1 % à 50% en poids d'un ou plusieurs monomères possédant une double liaison éthylénique polymérisable et un ou plusieurs groupes amino mono- ou disubstitué, pyrimidinyle, guanidyle, purinyle, ammonium quaternaire, SO3H ou SO3M, M étant un métal alcalin. Ces copolymères sont utilisables, sous forme de gels aqueux, comme échangeurs d'ions.

  不溶于水的三维交联无规共聚物，含有共聚物形态： a) 25%至 98%（按重量计）的 N-[三（羟甲基）甲基]丙烯酰胺或 N-[三（羟甲基）甲基]甲基丙烯酰胺，或这两种化合物的混合物、 b) 2%至 50%（按重量计）的一种或多种单体，这些单体具有多个可聚合的乙 烯双键，且不含阴离子或阳离子官能团、 c) 0.1%至 50%（按重量计）的一种或多种单体，具有一个可聚合的乙烯双键和一 个或多个单取代或二取代的氨基、嘧啶基、胍基、嘌呤基、季铵基、SO3H 或 SO3M 基团，其中 M 为碱金属。 这些共聚物可以水凝胶的形式用作离子交换剂。

表征谱图