2-[(E)-N-[(E)-3-chloroallyloxy]-C-ethyl-carbonimidoyl]-5-(2-ethylsulfanylpropyl)cyclohexane-1,3-dione

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-[(E)-N-[(E)-3-chloroallyloxy]-C-ethyl-carbonimidoyl]-5-(2-ethylsulfanylpropyl)cyclohexane-1,3-dione
• 英文别名: 2-[(E)-N-[(E)-3-chloroprop-2-enoxy]-C-ethylcarbonimidoyl]-5-(2-ethylsulfanylpropyl)cyclohexane-1,3-dione
• 化学式: C₁₇H₂₆ClNO₃S
• 分子量: 359.9
• InChiKey: YWTHVAKOGDVEOS-KUZBFYBWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  23
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  81
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2-[(E)-N-[(E)-3-chloroallyloxy]-C-ethyl-carbonimidoyl]-5-(2-ethylsulfanylpropyl)cyclohexane-1,3-dione 生成 sodium;2-[(E)-N-[(E)-3-chloroprop-2-enoxy]-C-ethylcarbonimidoyl]-5-(2-ethylsulfanylpropyl)-3-oxocyclohexen-1-olate
  参考文献：
  名称：

  摘要：

  DOI：
• 作为产物：
  描述：

  (2-丙酰-5-((2-乙基硫代)丙基)-环己烷-1,3-二酮 、 O-3-氯-2-丙烯基羟胺 生成 2-[(E)-N-[(E)-3-chloroallyloxy]-C-ethyl-carbonimidoyl]-5-(2-ethylsulfanylpropyl)cyclohexane-1,3-dione
  参考文献：
  名称：

  LUO, T.

  摘要：

  DOI：

文献信息

• LUO, TATAO
  作者：LUO, TATAO

  DOI：——

  日期：——
• ——
  作者：LUO TATAO

  DOI：——

  日期：——
• Adjuvants for use with crop protection agents
  申请人：BASF Corporation

  公开号：EP0356812B1

  公开（公告）日：1993-08-04
• [EN] HERBICIDAL COMPOSITION COMPRISING POLYMERIC MICROPARTICLES CONTAINING A SYNTHETIC AUXIN OR ALS INHIBITOR HERBICIDE, AND METHOD OF CONTROLLING WEEDS<br/>[FR] COMPOSITION HERBICIDE COMPRENANT DES MICROPARTICULES DE POLYMÈRE CONTENANT UNE AUXINE SYNTHÉTIQUE OU UN INHIBITEUR D'ACÉTOLACTATE SYNTHASE (ALS), ET PROCÉDÉ DE LUTTE CONTRE LES MAUVAISES HERBES
  申请人：SYNGENTA PARTICIPATIONS AG

  公开号：WO2014140227A1

  公开（公告）日：2014-09-18

  The invention provides a herbicidal composition comprising a mixture of: (a) polymeric microparticles containing a first herbicide, wherein the first herbicide is a synthetic auxin herbicide (e.g. dicamba) or an acetolactate synthase (ALS) inhibitor herbicide; wherein the first herbicide, when in a salt-free form and when not contained within polymeric microparticles, antagonises the herbicidal activity of an ACCase inhibitor herbicide, wherein the ACCase inhibitor herbicide is clethodim, fluazifop-butyl, fenoxaprop-ethyl, haloxyfop-methyl, haloxyfop-etotyl, quizalofop-ethyl, quizalofop-tefuryl, and/or propaquizafop, and/or an agrochemically acceptable salt of any of these; and (b)an ACCase inhibitor herbicide, wherein the ACCase inhibitor herbicide is clethodim, fluazifop-butyl, fenoxaprop-ethyl, haloxyfop-methyl, haloxyfop-etotyl, quizalofop-ethyl, quizalofop-tefuryl, and/or propaquizafop, and/or an agrochemically acceptable salt of any of these; wherein the polymeric microparticles are controlled-release matrices, within which is the first herbicide, and which function in such a way as to control and/or slow down the release of the first herbicide from the polymeric microparticles into a liquid medium when the polymeric microparticles are placed in and in contact with the liquid medium. Preferably, the polymer microparticles comprise a polymeric matrix or matrices comprising a crosslinked polyester polymer formed from the polymerization of an unsaturated (alkene- containing) polyester resin mixed with a vinyl-group-containing monomer such as styrene. Results demonstrate interalia that it is possible to mitigate dicamba-caused antagonism of the grass-herbicidal activity of clethodim in the glasshouse when a crosslinked polyester polymeric microparticle formulation of dicamba is applied in a tank-mix combination with clethodim.