己-5-烯-2-炔醛 | 84004-86-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 己-5-烯-2-炔醛
• 英文名称: Hex-5-en-2-ynal
• CAS: 84004-86-4
• 化学式: C₆H₆O
• 分子量: 94.113
• InChiKey: CRQBSSGCRLPREB-UHFFFAOYSA-N

物化性质

• 沸点：
  157.5±19.0 °C(Predicted)
• 密度：
  0.911±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  7
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  乙氧甲酰基亚甲基三苯基膦 、 己-5-烯-2-炔醛 以 苯 为溶剂， 反应 6.0h， 以62%的产率得到
  参考文献：
  名称：

  Synthesis and modification of ED-20 epoxy-4,4′-isopropylidenediphenol resin with highly unsaturated esters

  摘要：

  Esters of the dienyne series with a trans-ethylene bond were prepared in 70-80% yield by reactions of enyne aldehydes with ethoxycarbonylmethy lenetriphenylphosphorane. The compounds were studied bv IR and H-1 NMR spectroscopy, and their modifying effect on ED-20 epoxy-4,4'-isopropylidenediphenol resin was revealed.

  DOI：

  10.1134/s1070427208060177
• 作为产物：
  描述：

  5-己烯-2-炔基-1-醇 以31%的产率得到
  参考文献：
  名称：

  MINASYAN, T. T.;KINOYAN, F. S.;BADANYAN, SH. O., ARM. XIM. ZH., 1983, 35, N 7, 448-452

  摘要：

  DOI：

文献信息

• A stereoselective synthesis of anti-γ,δ-alkynyl- and -alkenyl-β-hydroxy-α-amino esters from tin(<scp>ii</scp>) enolates of glycinate
  作者：Jonathan J. Gridley、Michael P. Coogan、David W. Knight、K. M. Abdul Malik、Christopher M. Sharland、Jirada Singkhonrat、Siân Williams

  DOI：10.1039/b306291k

  日期：——

  Condensations between the tin(II) enolate 11 of ethyl N-tosylglycinate and conjugated ynals 12 and ynones 14 are highly diastereoselective, in favour of the anti-isomers 13 and 15; similar reactions of enals and enones 17 show lower but still useful levels of anti-stereoselectivity.

  乙基N-对甲苯磺酰甘氨酸盐的锡(II)烯醇化物11与共轭炔醛12和炔酮14之间的缩合反应具有高度的非对映选择性，有利于反式异构体13和15的生成；类似的烯醛和烯酮17反应也表现出较低但仍然有用的反式立体选择性。
• Synthesis and modification of ED-20 epoxy-4,4′-isopropylidenediphenol resin with highly unsaturated esters
  作者：M. G. Veliev、M. I. Shatirova、N. Ya. Ishchenko、Z. N. Guseinova、A. I. Ibragimova

  DOI：10.1134/s1070427208060177

  日期：2008.6

  Esters of the dienyne series with a trans-ethylene bond were prepared in 70-80% yield by reactions of enyne aldehydes with ethoxycarbonylmethy lenetriphenylphosphorane. The compounds were studied bv IR and H-1 NMR spectroscopy, and their modifying effect on ED-20 epoxy-4,4'-isopropylidenediphenol resin was revealed.
• MINASYAN, T. T.;KINOYAN, F. S.;BADANYAN, SH. O., ARM. XIM. ZH., 1983, 35, N 7, 448-452
  作者：MINASYAN, T. T.、KINOYAN, F. S.、BADANYAN, SH. O.

  DOI：——

  日期：——