(7,11,15,19,22,26,30,34-八甲基-1,4-二氧杂环三十六碳n-2-基)甲醇 | 88795-41-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: (7,11,15,19,22,26,30,34-八甲基-1,4-二氧杂环三十六碳n-2-基)甲醇
• 中文别名: &amp#x3B2-D-果呋喃糖基α-D-吡喃葡萄糖苷,壬烷-1,2,9-三羧酸]氢单[3-(4-羟基癸-1-烯基)2-(2-羟基乙基)9-
• 英文名称: macrocyclic diether
• 英文别名: (7,11,15,19,22,26,30,34-Octamethyl-1,4-dioxacyclohexatriacont-2-yl)methanol
• CAS: 88795-41-9
• 化学式: C₄₃H₈₆O₃
• 分子量: 651.154
• InChiKey: SCROVKPCXMRTCT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17
• 重原子数：
  46
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  9-萘甲酰腈 、 (7,11,15,19,22,26,30,34-八甲基-1,4-二氧杂环三十六碳n-2-基)甲醇 在 4-二甲氨基吡啶 作用下， 反应 5.0h， 生成 Anthracene-9-carboxylic acid 7,11,15,19,22,26,30,34-octamethyl-1,4-dioxa-cyclohexatriacont-2-ylmethyl ester
  参考文献：
  名称：

  A method for determination of archaeal ether-linked glycerolipids by high performance liquid chromatography with fluorescence detection as their 9-anthroyl derivatives

  摘要：

  It has been described a method for determination of archaeal ether core lipids derived from 6 organisms and 2 environmental samples by high performance liquid chromatography with fluorescene detection after preparation of their corresponding 9-anthroyl derivatives. The core lipids were released from glyco- and phospholipids by 3 different hydrolysis procedures. The results were compared and found that the alkaline hydrolysis procedure was preferred in the present study. The core lipids in 6 selected archaea were detected and found to be more concentrated in phospholipid fraction than in glycolipid fraction. The minimum detection limits of this method were approximately 0.5 and 2 ng for diether and tetraether, respectively, and 0.1mg/kg, 0.4mg/kg, respectively, for environmental sample. This is compatible with gas liquid chromatographic method in terms of sensitivity and minimum detection limits. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0045-6535(97)00154-9

文献信息

• Processes and host cells for genome, pathway, and biomolecular engineering
  申请人：enEvolv, Inc.

  公开号：US10370654B2

  公开（公告）日：2019-08-06

  The present disclosure provides compositions and methods for genomic engineering.

  本公开提供了基因组工程的组合物和方法。
• PROCESSES AND HOST CELLS FOR GENOME, PATHWAY, AND BIOMOLECULAR ENGINEERING
  申请人：ENEVOLV, INC.

  公开号：US20160186168A1

  公开（公告）日：2016-06-30

  The present disclosure provides compositions and methods for genomic engineering.
• US9944925B2
  申请人：——

  公开号：US9944925B2

  公开（公告）日：2018-04-17
• A method for determination of archaeal ether-linked glycerolipids by high performance liquid chromatography with fluorescence detection as their 9-anthroyl derivatives
  作者：Q.Y. Bai、L. Zelles

  DOI：10.1016/s0045-6535(97)00154-9

  日期：1997.7

  It has been described a method for determination of archaeal ether core lipids derived from 6 organisms and 2 environmental samples by high performance liquid chromatography with fluorescene detection after preparation of their corresponding 9-anthroyl derivatives. The core lipids were released from glyco- and phospholipids by 3 different hydrolysis procedures. The results were compared and found that the alkaline hydrolysis procedure was preferred in the present study. The core lipids in 6 selected archaea were detected and found to be more concentrated in phospholipid fraction than in glycolipid fraction. The minimum detection limits of this method were approximately 0.5 and 2 ng for diether and tetraether, respectively, and 0.1mg/kg, 0.4mg/kg, respectively, for environmental sample. This is compatible with gas liquid chromatographic method in terms of sensitivity and minimum detection limits. (C) 1997 Elsevier Science Ltd.