1-(苯甲酰氧基)-2,2,6,6-四甲基-4-哌啶酮 | 7031-85-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-(苯甲酰氧基)-2,2,6,6-四甲基-4-哌啶酮
• 英文名称: 1-benzoyloxy-2,2,6,6-tetramethyl-piperidin-4-one
• 英文别名: 1-Benzoyloxy-2,2,6,6-tetramethyl-piperidin-4-on；1-Benzoyloxy-2,2,6,6-tetramethyl-4-oxopiperidine；(2,2,6,6-tetramethyl-4-oxopiperidin-1-yl) benzoate
• CAS: 7031-85-8
• 化学式: C₁₆H₂₁NO₃
• 分子量: 275.348
• InChiKey: PLNDMBJJIUIABY-UHFFFAOYSA-N

物化性质

• 熔点：
  91 °C
• 沸点：
  366.3±52.0 °C(Predicted)
• 密度：
  1.13±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  46.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-(苯甲酰氧基)-2,2,6,6-四甲基-4-哌啶酮 在 sodium hydroxide 、 copper(l) iodide 、 四(三苯基膦)钯 、 lead dioxide 、 三乙胺 、 一氯丙酮 、 lithium chloride 、 lithium diisopropyl amide 作用下， 以 四氢呋喃 、 甲醇 、 二氯甲烷 、 苯 为溶剂， 反应 31.0h， 生成 bis-(1-oxyl-2,2,6,6-tetramethyl-Δ3-piperidyl-4)diacetylene
  参考文献：
  名称：

  Synthesis of terminal-biradical compounds consisting of two N-oxyl groups connected with conjugated π-systems

  摘要：

  Terminal-biradical compounds 1 having two N-oxyl groups connected with conjugated pi-systems were synthesized by (1) addition of magnesium acetylide to 4-oxo-TEMPO, followed by dehydration, or (2) cross-coupling between acetylene and vinyl triflate derived from 4-oxo-TEMPO. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)01732-2
• 作为产物：
  描述：

  4-氧-2,2,6,6-四甲基哌啶-1-氧自由基 在 吡啶 、 1,2-二苯肼 作用下， 以 二氯甲烷 为溶剂， 反应 6.0h， 生成 1-(苯甲酰氧基)-2,2,6,6-四甲基-4-哌啶酮
  参考文献：
  名称：

  Synthesis of terminal-biradical compounds consisting of two N-oxyl groups connected with conjugated π-systems

  摘要：

  Terminal-biradical compounds 1 having two N-oxyl groups connected with conjugated pi-systems were synthesized by (1) addition of magnesium acetylide to 4-oxo-TEMPO, followed by dehydration, or (2) cross-coupling between acetylene and vinyl triflate derived from 4-oxo-TEMPO. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)01732-2

文献信息

• METHOD OF GRAFTING ETHYLENICALLY UNSATURATED CARBOXYLIC ACID DERIVATIVES ONTO THERMOPLASTIC POLYMERS USING HYDROXYLAMINE ESTERS
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1404729B1

  公开（公告）日：2007-11-21
• CROSSLINKING OF UNSATURATED POLYESTERS BY THE USE OF HYDROXYLAMINE-ESTERS
  申请人：Ciba Holding Inc.

  公开号：EP1440115B1

  公开（公告）日：2009-08-05
• METHOD OF PREPARING ETHYLENE POLYMERS BY CONTROLLED HIGH PRESSURE POLYMERIZATION
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1727837B1

  公开（公告）日：2007-12-12
• Method of Preparing Ethylene Polymers by Controlled High Pressure Polymerization
  申请人：Roth Michael

  公开号：US20080234453A1

  公开（公告）日：2008-09-25

  The present invention relates to a method for the radical polymerization or copolymerization of ethylene at high pressures using a hydroxylamine ester as radical initiator. The hydroxylamine esters according to the invention are suitable initiators for the high pressure polymerization of ethylene leading to high molecular weight polyethylenes with narrow molecular weight distributions (Polydispersed Index PD=1.2−4.5).
• Method Of Preparing Ethylene Polymers By Controlled High Pressure Polymerization
  申请人：BASF SE

  公开号：US20130150542A1

  公开（公告）日：2013-06-13

  The present invention relates to a method for the radical polymerization or copolymerization of ethylene at high pressures using a hydroxylamine ester as radical initiator. The hydroxylamine esters according to the invention are suitable initiators for the high pressure polymerization of ethylene leading to high molecular weight polyethylenes with narrow molecular weight distributions (Poyldispersity Index PD=1,2−4.5).