1-烯丙基-5-乙烯基-1H-咪唑 | 543719-55-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 中文名称: 1-烯丙基-5-乙烯基-1H-咪唑
• 英文名称: 1-allyl-5-vinyl-1H-imidazole
• 英文别名: 5-Ethenyl-1-prop-2-enylimidazole
• CAS: 543719-55-7
• 化学式: C₈H₁₀N₂
• mdl: MFCD18808456
• 分子量: 134.181
• InChiKey: AOILSTWHMSRZQP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.125
• 拓扑面积：
  17.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-烯丙基-5-乙烯基-1H-咪唑 在 Grubbs catalyst first generation 对甲苯磺酸 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 以32%的产率得到5H-pyrrolo[1,2-c]imidazole
  参考文献：
  名称：

  Synthesis of fused bicyclic imidazoles by ring-closing metathesis

  摘要：

  The preparation of a number of dienylimidazole via chemoselective metal-halogen exchange and their utility in ring-closing metathesis is described. Essentially all regioisomeric permutations participate in metathesis with the notable exception of 4-vinyl-5-allylimidazoles, provided that the imidazole N3 atom is protonated. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)02864-2
• 作为产物：
  描述：

  1-allyl-4-iodo-5-vinyl-1H-imidazole 在 乙基溴化镁 、 水 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 以56%的产率得到1-烯丙基-5-乙烯基-1H-咪唑
  参考文献：
  名称：

  Synthesis of fused bicyclic imidazoles by ring-closing metathesis

  摘要：

  The preparation of a number of dienylimidazole via chemoselective metal-halogen exchange and their utility in ring-closing metathesis is described. Essentially all regioisomeric permutations participate in metathesis with the notable exception of 4-vinyl-5-allylimidazoles, provided that the imidazole N3 atom is protonated. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)02864-2

文献信息

• Polymeric adhesive and anti-corrosion agents
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0471336A2

  公开（公告）日：1992-02-19

  In the adhesion of metallic materials to polymers, new adhesive agents of nitrogen containing hetrocyclic polymers such as compositions of imidazole-pyrridine, pyrrolidone-pyridine, and imidazole-pyrrolidone solutions have been discovered as useful. These agents also exhibit anti-corrosion effects. Adhesion and/or reduction of anti-corrosion can be accomplished by pre-coating the metal material with at least one of these agents prior to applying the polymer, or by preblending the polymer with at least one of these agents followed by applying the blend to the metal, under suitable conditions.

  在金属材料与聚合物的粘合过程中，人们发现了新的含氮杂环聚合物粘合剂，如咪唑-吡啶、吡咯烷酮-吡啶和咪唑-吡咯烷酮溶液的组合物。这些制剂还具有防腐蚀效果。在涂抹聚合物之前，用至少一种这些制剂预涂金属材料，或在适当条件下将聚合物与至少一种这些制剂预混，然后将混合物涂抹到金属上，都可以达到粘附和/或降低防腐效果的目的。
• Synthesis of fused bicyclic imidazoles by ring-closing metathesis
  作者：Yingzhong Chen、H.V.Rasika Dias、Carl J. Lovely

  DOI：10.1016/s0040-4039(02)02864-2

  日期：2003.2

  The preparation of a number of dienylimidazole via chemoselective metal-halogen exchange and their utility in ring-closing metathesis is described. Essentially all regioisomeric permutations participate in metathesis with the notable exception of 4-vinyl-5-allylimidazoles, provided that the imidazole N3 atom is protonated. (C) 2003 Elsevier Science Ltd. All rights reserved.
• 1-CARBOXY-1-VYNILOXYIMINOAMINOTHIAZOLE CEPHALOSPORING DERIVATIVES AND PROCESS FOR THEIR PREPARATION
  申请人：BANYU PHARMACEUTICAL CO., LTD.

  公开号：EP0346465B1

  公开（公告）日：1993-08-11
• POLYMERS FOR PHOTOGRAPHIC ELEMENTS
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0541548A1

  公开（公告）日：1993-05-19
• US5006450A
  申请人：——

  公开号：US5006450A

  公开（公告）日：1991-04-09