氧杂环壬烷均聚物 | 50862-53-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 氧杂环壬烷均聚物
• 中文别名: 噁壬环
• 英文名称: Oxonane
• CAS: 50862-53-8
• 化学式: C₈H₁₆O
• 分子量: 128.21
• InChiKey: YVQBOKCDPCUWSP-UHFFFAOYSA-N

物化性质

• 保留指数：
  974

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Perfluorinated amide salts and their uses as ionic conducting materials
  申请人：——

  公开号：US20020009650A1

  公开（公告）日：2002-01-24

  The invention concerns ionic compounds in which the anionic load has been delocalized. A compound disclosed by the invention is comprised of an amide or one of its salts, including an anionic portion combined with at least one cationic portion M +m in sufficient numbers to ensure overall electronic neutrality; the compound is further comprised of M as a hydroxonium, a nitrosonium NO + , an ammonium —NH 4 +, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic portion matches the formula R F —SO x —N − Z, wherein R F is a perfluorinated group, x is 1 or 2, and Z is an electroattractive substituent. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorants, and the catalysis of various chemical reactions.

  该发明涉及离子化合物，其中阴离子载荷已被解离。该发明揭示的一种化合物由酰胺或其盐之一组成，包括与至少一个阳离子部分M+min结合以确保整体电子中性；该化合物进一步由M作为氢氧离子、亚硝基 NO+、铵离子—NH4+、具有价态m的金属阳离子、具有价态m的有机阳离子，或具有价态m的有机金属阳离子组成。阴离子部分符合公式RF—SOx—N−Z，其中RF是全氟化基团，x为1或2，Z是一个电子吸引取代基。这些化合物可以用于离子导电材料、电子导电材料、着色剂以及各种化学反应的催化。
• PROCESS FOR THE PURIFICATION OF POLYETHERS
  申请人：——

  公开号：US20020049356A1

  公开（公告）日：2002-04-25

  A process for the purification of polyethers prepared by acid catalyzed condensation of polyhydroxy compounds includes the steps of: (a) heating the polyether with water for a time and at temperature sufficient to substantially hydrolyze esters formed during polymerization; and (b) separating the polyether from the water. The heating of the polyether and water may be conducted under reflux at a temperature of 60 to 100° C. for a period of 2 to 20 hours. The polyether recovered from step (b) may be subjected to further washing with hot water to remove residual acid.

  通过酸催化缩合聚羟基化合物制备的聚醚的纯化过程包括以下步骤：(a)将聚醚与水加热，时间和温度足以在聚合过程中形成的酯基本水解;和(b)将聚醚与水分离。聚醚和水的加热可以在60至100°C的温度下回流进行，持续时间为2至20小时。从步骤(b)中回收的聚醚可以进一步用热水洗涤以去除残留酸。
• PROCESS OF MANUFACTURING POLYOLS
  申请人：Dow Global Technologies LLC

  公开号：US20200354383A1

  公开（公告）日：2020-11-12

  A method of producing a polyether polyol includes reacting a low molecular weight initiator with ethylene oxide in the presence of a polymerization catalyst, and the low molecular weight initiator has a nominal hydroxyl functionality at least 2. The polymerization catalyst is a Lewis acid catalyst having the general formula M(R 1 ) 1 (R 2 ) 1 (R 3 ) 1 (R 4 )0 or 1, whereas M is boron, aluminum, indium, bismuth or erbium, R 1 , R 2 , R 3 , and R 4 are each independent, R 1 includes a fluoroalkyl-substituted phenyl group, R 2 incudes a fluoroalkyl-substituted phenyl group or a fluoro/chloro-substituted phenyl group, R 3 includes a fluoroalkyl-substituted phenyl group or a fluoro/chloro-substituted phenyl group, and optional R 4 includes a functional group or functional polymer group, R 1 being different from at least one of R 2 and R 3 .

  一种生产聚醚多元醇的方法包括在聚合催化剂存在下，将低分子量启始剂与环氧乙烷反应，其中低分子量启始剂的名义羟基官能度至少为2。聚合催化剂是具有一般式M(R1)1(R2)1(R3)1(R4)0或1的路易斯酸催化剂，其中M为硼、铝、铟、铋或铒，R1、R2、R3和R4各自独立，R1包括氟烷基取代的苯基，R2包括氟烷基取代的苯基或氟/氯取代的苯基，R3包括氟烷基取代的苯基或氟/氯取代的苯基，可选的R4包括功能基或功能聚合物基，R1与至少一个R2和R3不同。
• Lewis acid polymerization catalyst
  申请人：Dow Global Technologies LLC

  公开号：US11001669B2

  公开（公告）日：2021-05-11

  A Lewis acid polymerization catalyst has a general formula M(R1)1(R2)1(R3)1(R4)0 or 1, whereas M is boron, R1, R2, R3, and R4 are each independent, R1 is a 3,5-bis(trifluoromethyl)-substituted phenyl group, R2 is the 3,5-bis(trifluoromethyl)-substituted phenyl group or a first fluoro-substituted phenyl group selected from Set 1 structures, R3 is independently a second fluoro-substituted phenyl group selected from the Set 1 structures, and optional R4 includes a third functional group or functional polymer group.

  一个路易斯酸聚合催化剂的一般公式是 M(R1)1(R2)1(R3)1(R4)0或1，其中 M 为硼，R1、R2、R3 和 R4 分别是独立的，R1 是一个3,5-双(三氟甲基)取代的苯基，R2 是3,5-双(三氟甲基)取代的苯基或从 Set 1 结构中选择的第一氟取代的苯基，R3 是从 Set 1 结构中选择的第二氟取代的苯基，可选的 R4 包括第三功能基或功能聚合物基团。
• Alkoxylated amine and process therefor
  申请人：Coates S. John

  公开号：US20050159625A1

  公开（公告）日：2005-07-21

  A composition that can be used as a component in auto clear coat and primer is disclosed. The composition comprises or is an alkoxylated amine having the formula of (A)[N(R 1 H) 2 ] p including an isomer or mixture of isomers thereof. Also disclosed is a process, which comprises contacting an amine with an epoxide under a condition sufficient to produce an alkoxylated amine. Further disclosed is a composition that can be used as coating composition and primer, which comprises an alkoxylated amine and an organic polyisocyanate.

  本发明公开了一种可用作汽车清漆和底漆组分的组合物。该组合物包括或是具有以下式子的烷氧基化胺物质(A)[N(R1H)2]pi，其中包括其异构体或混合物。本发明还公开了一种工艺，包括将胺物质与环氧化合物接触在足以生成烷氧基化胺的条件下。此外，本发明还公开了一种可用作涂层组分和底漆的组合物，包括烷氧基化胺和有机聚异氰酸酯。