1-苯基-3-(三氯甲基)吡唑 | 83959-41-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 中文名称: 1-苯基-3-(三氯甲基)吡唑
• 英文名称: 1-phenyl-3-trichloromethyl-1H-pyrazole
• 英文别名: 1-Phenyl-3-trichlormethyl-1H-pyrazol；1-phenyl-3-trichloromethyl-pyrazole；1-Phenyl-3-(trichloromethyl)pyrazole
• CAS: 83959-41-5
• 化学式: C₁₀H₇Cl₃N₂
• 分子量: 261.538
• InChiKey: PDEMFAXJHHSQET-UHFFFAOYSA-N

物化性质

• 沸点：
  344.3±37.0 °C(Predicted)
• 密度：
  1.41±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  17.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-苯基-3-(三氯甲基)吡唑 在 sodium hydroxide 作用下， 生成 1-苯基-3-吡唑甲酸
  参考文献：
  名称：

  Roedig; Becker, Justus Liebigs Annalen der Chemie, 1955, vol. 597, p. 214,224

  摘要：

  DOI：
• 作为产物：
  描述：

  1,1,1,4-四氯-丁-3-烯-2-酮 、 苯肼 在 乙醚 作用下， 生成 1-苯基-3-(三氯甲基)吡唑
  参考文献：
  名称：

  Roedig; Becker, Justus Liebigs Annalen der Chemie, 1955, vol. 597, p. 214,224

  摘要：

  DOI：

文献信息

• USE OF 4-SUBSTITUTED 1-PHENYLPYRAZOLE-3-CARBOXYLIC ACID DERIVATIVES AS AGENTS AGAINST ABIOTIC PLANT STRESS
  申请人：BAYER INTELLECTUAL PROPERTY GMBH

  公开号：US20140329684A1

  公开（公告）日：2014-11-06

  The invention relates to the use of 4-substituted 1-phenylpyrazole-3-carboxylic acid derivatives of the general formula (I), or salts thereof, where the radicals in the general formula (I) correspond to the definitions given in the description, for enhancing stress tolerance in plants to abiotic stress, for strengthening plant growth and/or for increasing plant yield, and to selected processes for preparing the compounds mentioned above.

  本发明涉及使用4-取代的1-苯基吡唑-3-羧酸衍生物（I）或其盐，其中一般式（I）中的基团对应于描述中给出的定义，用于增强植物对非生物胁迫的耐受性，加强植物生长和/或增加植物产量，并涉及选定的制备上述化合物的过程。
• Ultraviolet-sensing sheet, ultraviolet-sensing set, and ultraviolet-sensing method
  申请人：FUJIFILM Corporation

  公开号：US10113907B2

  公开（公告）日：2018-10-30

  Provided are an ultraviolet-sensing sheet, an ultraviolet-sensing set, and an ultraviolet-sensing method, in which color gradation properties which are suitable for detecting an ultraviolet dose are obtained and in which the coloring of an ultraviolet-sensing layer caused by the effect of light other than ultraviolet light is prevented. An ultraviolet-sensing sheet 1 includes: a filter layer 10 that selectively allows transmission of light having a specific wavelength; and an ultraviolet-sensing layer 20 that includes a capsule including a color-forming dye and a photooxidant. It is preferable that the filter layer 10 has a maximum value of the transmittance in a wavelength range of 300 nm or longer and shorter than 380 nm.

  本发明提供了一种紫外线传感片材、紫外线传感装置和紫外线传感方法，其中可获得适合检测紫外线剂量的色阶特性，并可防止紫外线传感层因紫外线以外的光的影响而着色。 紫外线传感片 1 包括：过滤层 10，可选择性地允许特定波长的光透过；紫外线传感层 20，包括一个胶囊，内含成色染料和光氧化剂。滤光层 10 最好在 300 纳米或更长且短于 380 纳米的波长范围内具有最大透射率值。
• Ultraviolet-sensitive sheet, method for manufacturing ultraviolet-sensing sheet, and method for sensing ultraviolet
  申请人：FUJIFILM Corporation

  公开号：US10203245B2

  公开（公告）日：2019-02-12

  Provided an ultraviolet-sensing sheet that facilitates measurement of ultraviolet irradiance over a wide area, that is suitable in ultraviolet irradiance in a range from 1 to 1,000 mJ/cm2, a method for manufacturing such an ultraviolet-sensing sheet, and a method for sensing ultraviolet. The ultraviolet-sensing sheet has a change in reflection density ΔD1 of 0.2 or more over a range of cumulative illuminance 1 mJ/cm2 or more and less than 10 mJ/cm2, a change in reflection density ΔD2 of 0.2 or more over a range of cumulative illuminance 10 mJ/cm2 or more and less than 100 mJ/cm2, and a change in reflection density ΔD3 of 0.2 or more over a range of cumulative illuminance 100 mJ/cm2 or more and 1,000 mJ/cm2 or less, as measured at a wavelength of 365 nm when the ultraviolet-sensing sheet is irradiated with a high-pressure mercury lamp.

  提供了一种便于测量大面积紫外线辐照度的紫外线传感片，该传感片适用于紫外线辐照度在1至1,000 mJ/cm2范围内的情况，还提供了制造这种紫外线传感片的方法以及传感紫外线的方法。紫外线传感片在累积照度为 1 mJ/cm2 或以上、10 mJ/cm2 以下的范围内，反射密度 ΔD1 的变化为 0.2 或以上、 在累积照度为 10 mJ/cm2 或以上且小于 100 mJ/cm2 的范围内，反射密度 ΔD2 的变化为 0.2 或以上；以及 在累积照度为 100 mJ/cm2 或以上且小于 1,000 mJ/cm2 的范围内，反射密度 ΔD3 的变化为 0.2 或以上、 用高压汞灯照射紫外线传感片时，在 365 纳米波长处测得。
• ULTRAVIOLET-SENSITIVE SHEET, METHOD FOR MANUFACTURING ULTRAVIOLET-SENSING SHEET, AND METHOD FOR SENSING ULTRAVIOLET
  申请人：FUJIFILM Corporation

  公开号：US20170089760A1

  公开（公告）日：2017-03-30

  Provided an ultraviolet-sensing sheet that facilitates measurement of ultraviolet irradiance over a wide area, that is suitable in ultraviolet irradiance in a range from 1 to 1,000 mJ/cm 2 , a method for manufacturing such an ultraviolet-sensing sheet, and a method for sensing ultraviolet. The ultraviolet-sensing sheet has a change in reflection density ΔD1 of 0.2 or more over a range of cumulative illuminance 1 mJ/cm 2 or more and less than 10 mJ/cm 2 , a change in reflection density ΔD2 of 0.2 or more over a range of cumulative illuminance 10 mJ/cm 2 or more and less than 100 mJ/cm 2 , and a change in reflection density ΔD3 of 0.2 or more over a range of cumulative illuminance 100 mJ/cm 2 or more and 1,000 mJ/cm 2 or less, as measured at a wavelength of 365 nm when the ultraviolet-sensing sheet is irradiated with a high-pressure mercury lamp.
• ULTRAVIOLET-SENSING SHEET, ULTRAVIOLET-SENSING SET, AND ULTRAVIOLET-SENSING METHOD
  申请人：FUJIFILM Corporation

  公开号：US20170131144A1

  公开（公告）日：2017-05-11

  Provided are an ultraviolet-sensing sheet, an ultraviolet-sensing set, and an ultraviolet-sensing method, in which color gradation properties which are suitable for detecting an ultraviolet dose are obtained and in which the coloring of an ultraviolet-sensing layer caused by the effect of light other than ultraviolet light is prevented. An ultraviolet-sensing sheet 1 includes: a filter layer 10 that selectively allows transmission of light having a specific wavelength; and an ultraviolet-sensing layer 20 that includes a capsule including a color-forming dye and a photooxidant. It is preferable that the filter layer 10 has a maximum value of the transmittance in a wavelength range of 300 nm or longer and shorter than 380 nm.