1H,1H,8H-全氟-1-辛醇 | 10331-08-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代醇
• 中文名称: 1H,1H,8H-全氟-1-辛醇
• 英文名称: 1H,1H,8H-Perfluorooctan-1-ol
• 英文别名: 1h,1h,8h-Perfluoro-1-octanol；2,2,3,3,4,4,5,5,6,6,7,7,8,8-tetradecafluorooctan-1-ol
• CAS: 10331-08-5
• 化学式: C₈H₄F₁₄O
• 分子量: 382.097
• InChiKey: ISIIJJQHILZBPB-UHFFFAOYSA-N

物化性质

• 沸点：
  180.7±40.0 °C(Predicted)
• 密度：
  1.625±0.06 g/cm3(Predicted)
• 溶解度：
  可溶于氯仿（少许）、甲醇（少许）

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  23
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  15

安全信息

• 危险品标志：
  Xi
• 海关编码：
  2905590090

反应信息

• 作为反应物：
  描述：

  3-(2-vinyloxyethoxy)propylene 1,2-carbonate 、 1H,1H,8H-全氟-1-辛醇 在 C₃F₇CO₂H 作用下， 生成 4-{2-[1-(2,2,3,3,4,4,5,5,6,6,7,7,8,8-Tetradecafluoro-octyloxy)-ethoxy]-ethoxymethyl}-[1,3]dioxolan-2-one
  参考文献：
  名称：

  Nedolya, N. A.; Zinov'eva, V. P., Russian Journal of Organic Chemistry, 1994, vol. 30, # 8, p. 1220 - 1223

  摘要：

  DOI：

文献信息

• Process for producing compound, catalyst component for addition polymerization, process for producing catalyst for addition polymerization, and process for producing addition polymer
  申请人：Oshima Hideki

  公开号：US20050222351A1

  公开（公告）日：2005-10-06

  There are provided (1) a process for producing a compound, which comprises the step of contacting a compound (A) defined by the formula, M 1 L 1 3 , a compound (B) defined by the formula, R 1 t-1 TH, and a compound (C) defined by the formula, R 2 t-2 TH 2 ; (2) a catalyst component for addition polymerization, which comprises a compound produced by said process; (3) a process for producing a polymerization catalyst, which comprises the step of contacting said catalyst component with a transition metal compound and an optional organoaluminum compound; and (4) a process for producing an addition polymer, which comprises the step of addition polymerizing an addition polymerizable monomer in the presence of a catalyst produced by said process.

  提供以下内容：（1）生产化合物的过程，包括将由M1L13公式定义的化合物（A）、由R1t-1TH公式定义的化合物（B）和由R2t-2TH2公式定义的化合物（C）接触的步骤；（2）用于加成聚合的催化剂组分，包括通过上述过程产生的化合物；（3）生产聚合催化剂的过程，包括将催化剂组分与过渡金属化合物和可选的有机铝化合物接触的步骤；（4）生产加成聚合物的过程，包括在上述过程产生的催化剂存在下加成聚合可聚合单体的步骤。
• POLYCARBONATE-BASE POLYMER, PRODUCTION PROCESS, RESIN COATING FLUID PREPARED THEREFROM, AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR PREPARED THEREFROM
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0837085A1

  公开（公告）日：1998-04-22

  A polymer comprising mainly repeating units (1) and/or repeating units (2), containing optionally terminal groups (3) and/or repeating units (4), and having a reduced viscosity [ηsp/c] of 0.2 to 10.0 dl/g as measured in a 0.5 g/dl solution thereof in methylene chloride at 20°C; a resin coating fluid containing the polymer, a charge-transfer substance and a solvent; and an electrophotographic photoreceptor containing the polymer as a binder resin in a photosensitive layer, wherein Rf1 represents a group that is composed of at least carbon atoms and fluorine atoms and bonded directly to the two oxygen atoms of the carbonate linkage in the general formula (1) without any intervening arylene group; and Rf2 represents a group that is composed of at least carbon atoms and fluorine atoms and bonded directly to one of the oxygen atoms of the carbonate linkage in the general formula (3) without any intervening arylene group.

  一种主要由重复单元（1）和/或重复单元（2）组成的聚合物，含有任选的末端基团（3）和/或重复单元（4），在 0.其中 Rf1 代表至少由碳原子和氟原子组成并直接与通式（1）中碳酸酯连接的两个氧原子键合的基团，而没有任何芳基介入；Rf2 代表一个至少由碳原子和氟原子组成的基团，直接与通式（3）中碳酸酯链节的一个氧原子键合，中间不含任何芳烯基。
• Novel aerosol formulation containing a polar fluorinated molecule
  申请人：——

  公开号：US20030194378A1

  公开（公告）日：2003-10-16

  The present invention relates to a stable pharmaceutical aerosol formulation intended for inhalation. The formulation contains an active substance, an aerosol propellant, a polar flurorinated molecule and an excipient. The preferred propellant is HFA 134a or HFA 227 or a mixture thereof.

  本发明涉及一种用于吸入的稳定药用气溶胶制剂。该制剂含有一种活性物质、一种气溶胶推进剂、一种极性氟化分子和一种赋形剂。优选的推进剂是 HFA 134a 或 HFA 227 或它们的混合物。
• Metal compound, and catalyst component and catalyst for addition polymerization, and process for producing addition polymer
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20040209762A1

  公开（公告）日：2004-10-21

  A metal compound obtained by a process comprising the step of contacting, in a specific ratio, a compound represented by the formula M 1 L 1 r , a compound represented by the formula R 1 s-1 TH, and a compound represented by the formula R 2 4-n J(OH) n ; a catalyst component for addition polymerization comprising the metal compound; a catalyst for addition polymerization using the catalyst component; and a process for producing an addition polymer using the catalyst.

  一种金属化合物，通过以下工艺获得，该工艺包括以下步骤：按特定比例将式 M 所代表的化合物与以下物质接触 1 L 1 r 和式 R 1 s-1 TH 所代表的化合物，以及由式 R 2 4-n J(OH) n 由金属化合物组成的加成聚合催化剂组分；使用该催化剂组分进行加成聚合的催化剂；以及使用该催化剂生产加成聚合物的工艺。
• Process for producing modified particle, carrier or catalyst component for addition polymerization, pre-polymerized catalyst component therefor, catalyst therefor, and addition polymer
  申请人：Oshima Hideki

  公开号：US20050148459A1

  公开（公告）日：2005-07-07

  A process for producing a modified particle, a carrier or a catalyst component for addition polymerization, which comprises the steps of (1) contacting a compound (a) represented by the defined formula M 1 L 1 3 with a compound (b) represented by the defined formula R 1 t-1 TH, thereby producing a contact product, and (2) contacting the contact product with a compound (c) represented by the defined formula R 2 t-2 TH 2 in the presence of a particle (d); a process for producing a pre-polymerized catalyst component or a catalyst for addition polymerization, which comprises the steps of (1) contacting the above modified particle with a transition metal compound and optionally an organoaluminum compound, thereby producing a primary catalyst, and (2) pre-polymerizing an olefin in the presence of the primary catalyst; a process for producing a catalyst for addition polymerization, which comprises the step of contacting the above catalyst component with a transition metal compound and optionally an organoaluminum compound; and a process for producing an addition polymer, which comprises the step of addition polymerizing an addition polymerizable monomer in the presence of the above catalyst.

  一种生产加成聚合用改性粒子、载体或催化剂组分的工艺，包括以下步骤 (1) 将定义式 M 所代表的化合物 (a) 1 L 1 3 与由定义式 R 1 t-1 TH 所代表的化合物 (b) 接触，从而生成接触产物，以及 (2) 将接触产物与由定义式 R 2 t-2 TH 2 一种生产预聚合催化剂组分或加成聚合催化剂的工艺，包括以下步骤：(1) 将上述改性颗粒与过渡金属化合物和可选的有机铝化合物接触，从而制得一级催化剂；(2) 在一级催化剂存在下预聚合烯烃；一种生产加成聚合催化剂的工艺，包括将上述催化剂组分与过渡金属化合物和有机铝化合物接触的步骤；以及一种生产加成聚合物的工艺，包括在上述催化剂存在下对可加成聚合的单体进行加成聚合的步骤。