2,2,6-三甲基环己基甲基酮 | 26383-28-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 2,2,6-三甲基环己基甲基酮
• 英文名称: 1-Acetyl-2,6,6-trimethylcyclohexan
• 英文别名: 2,2,6-trimethylcyclohexyl methyl ketone；1-acetyl-2,2,6-trimethyl cyclohexane；1-(2,2,6-Trimethylcyclohexyl)ethanone
• CAS: 26383-28-8
• 化学式: C₁₁H₂₀O
• 分子量: 168.279
• InChiKey: LGEFCQRTSXYJAD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Process for Conducting an Organic Reaction in Ionic Liquids
  申请人：Bourgeois Daniel Martin

  公开号：US20110152566A1

  公开（公告）日：2011-06-23

  The present disclosure describes processes for producing cyclohexenes using Lewis acidic ionic liquids comprising the steps of providing to a reactor an α,β-unsaturated carbonyl dienophile, providing to the reactor a 1,3-diene, providing a Lewis acidic ionic liquid to the reactor; and reacting the α,β-unsaturated carbonyl dienophile with 1,3-diene to form a substituted cyclohexene product. The α,β-unsaturated carbonyl dienophile can be mesityl oxide, the 1,3-diene can be piperylene; and the Lewis acidic ionic liquid can be AlCl 3 :[C 2 mim]Cl; AlCl 3 :[C 8 mim]Cl; or mixtures thereof.

  本公开描述了使用含有Lewis酸性离子液体的方法生产环己烯的过程，包括向反应器提供α，β-不饱和羰基二烯亲受体，向反应器提供1,3-二烯，向反应器提供Lewis酸性离子液体；并将α，β-不饱和羰基二烯亲受体与1,3-二烯反应以形成取代环己烯产物。α，β-不饱和羰基二烯亲受体可以是甲苯酮氧，1,3-二烯可以是戊二烯；Lewis酸性离子液体可以是AlCl3:[C2mim]Cl；AlCl3:[C8mim]Cl；或它们的混合物。
• [EN] SELECTIVE CHROMOPHORES<br/>[FR] CHROMOPHORES SELECTIFS
  申请人：CHALMERS TECHNOLOGY LICENSING

  公开号：WO2003104210A1

  公开（公告）日：2003-12-18

  The present invention relates to chromophores for selective staining of cells or cell parts comprising a fluorescent chromophore of the general formulae I. The invention further comprises a method for cell sorting, a method for cell targeting, as well as a method for cell identification.

  本发明涉及用于选择性染色细胞或细胞部分的色素，包括一种通用式I的荧光色素。该发明还包括一种细胞分选方法、一种细胞靶向方法，以及一种细胞鉴定方法。
• (1S,6R)-2,2,6-Trimethylcyclohexyl methyl ketone and/or (1R,6S)-2,2,6-trimethylcyclohexyl methyl ketone, process for producing the same, and perfume composition containing the same
  申请人：——

  公开号：US20020042356A1

  公开（公告）日：2002-04-11

  Trans-2,2,6-trimethylcyclohexyl methyl ketone, including (1S,6R)-2,2,6-trimethylcyclohexyl methyl ketone represented by the formula (1a): 1 and (1R,6S)-2,2,6-trimethylcyclohexyl methyl ketone represented by the formula (1b): 2 are useful components in a perfume composition. A process for producing the same is also described. A unique eucalyptus, mint-like and white floral perfume material is provided using the ketone compounds disclosed in the present invention. The process of the present invention produces the optically active ketone compounds having optical purity up to at least 98.0% e.e.

  2,2,6-三甲基环己基甲基酮，包括由化学式表示的(1S,6R)-2,2,6-三甲基环己基甲基酮（1a）和由化学式表示的(1R,6S)-2,2,6-三甲基环己基甲基酮（1b）是香水配方中有用的成分。本文还描述了一种生产这些成分的方法。使用本发明中披露的酮化合物提供了一种独特的桉树、薄荷和白色花香调的香料原料。本发明的方法产生光学活性的酮化合物，其光学纯度至少可达98.0% e.e.
• Isomer composition containing optically active ethyl trans-2,2,6-trimethylcyclohexylcarboxylate and fragrance composition containing the isomer composition
  申请人：Takasago International Corporation

  公开号：US20030207789A1

  公开（公告）日：2003-11-06

  A geometrical isomer composition excellent in odor and in chemical resistance, which is applicable to a base material containing a strongly alkaline chemical or a strongly acidic chemical, which can suppress the deterioration with time and the color change of the base material in the case that the material is exposed to light, and which also have highly palatable and unique fruity floral fragrance. The composition is produced by mixing 93 to 99% by weight of optically active ethyl trans-2,2,6-trimethylcyclohexylcarboxylate represented by Formula-1 or a mixture thereof and 7 to 1% by weight of optically active ethyl cis-2,2,6-trimethylcyclohexylcarboxylate represented by Formula-2 or a mixture thereof, respectively. 1

  本发明涉及一种几何异构体组成物，其气味和化学耐性均优异，适用于含有强碱性化学物质或强酸性化学物质的基材料，可以抑制材料暴露在光线下时的时间劣化和颜色变化，并具有高度可口和独特的果香花香味。该组成物是通过混合93至99重量％的由式-1表示的光学活性乙基顺-2,2,6-三甲基环己基羧酸乙酯或其混合物和7至1重量％的由式-2表示的光学活性乙基顺-2,2,6-三甲基环己基羧酸乙酯或其混合物制成的。
• Isomer composition excellent in chemical resistance containing optically active trans-1-(2,2,6-trimethylcyclohexyl)-2-buten-1-one and fragrance compositions containing the isomer composition
  申请人：Takasago International Corporation

  公开号：US20030207790A1

  公开（公告）日：2003-11-06

  A geometrical isomer composition excellent in odor and in chemical resistance, which is applicable to a base material containing a strongly alkaline chemical or a strongly acidic chemical, which can suppress the deterioration with time and the color change of the base material in the case that the material is exposed to light, and which also have highly tasteful and unique fruity floral fragrance. A geometrical isomer composition containing 93 to 99% by weight of optically active trans-1-(2,2,6-trimethylcyclohexyl)-2-buten-1-one represented by Formula-1 or a mixture thereof and 7 to 1% by weight of optically active cis-1-(2,2,6-trimethylcyclohexyl)-2-buten-1-one represented by Formula-2 or a mixture thereof is, respectively, used. 1

  一种几何异构体组成物，具有优异的气味和化学耐受性，适用于含有强碱性化学物质或强酸性化学物质的基材料，能够抑制基材料在光照下的时间劣化和颜色变化，并且具有高度美味和独特的果香花香味。该几何异构体组成物分别含有93至99%重量的光学活性反式-1-(2,2,6-三甲基环己基)-2-丁烯-1-酮（化学式1）或其混合物，以及7至1%重量的光学活性顺式-1-(2,2,6-三甲基环己基)-2-丁烯-1-酮（化学式2）或其混合物。