2,5-二丁基苯胺 | 78210-23-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,5-二丁基苯胺
• 英文名称: 2,5-dibutyl-aniline
• 英文别名: 2-Amino-1.4-dibutyl-benzol；2,5-Dibutyl-anilin；2,5-Dibutylaniline
• CAS: 78210-23-8
• 化学式: C₁₄H₂₃N
• 分子量: 205.343
• InChiKey: ZYQPWICOSRDSLK-UHFFFAOYSA-N

物化性质

• 沸点：
  317.7±11.0 °C(Predicted)
• 密度：
  0.919±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,5-二丁基苯胺 在 tris(dibenzylideneacetone)dipalladium(0) chloroform complex 、 1,1'-双(二苯基膦)二茂铁 、 [(4-(N,N-二甲氨基)苯基]二叔丁基膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 2.5h， 生成
  参考文献：
  名称：

  ＯＬＥＤ素子形成用組成物及びＯＬＥＤ素子

  摘要：

  【问题】提供效率高且溶解性好的发光材料。【解决方法】具有芘骨架的芳香族胺衍生物，例如由下述化合物1表示的芳香族胺衍生物。含有上述芳香族胺衍生物的有机电致发光元件用发光材料。【选定图】图1

  公开号：

  JP2021075493A
• 作为产物：
  描述：

  1,4-二-N-丁基苯 在 硫酸 、 硝酸 、 铁粉 、 氯化铵 作用下， 以 乙醇 、 水 、 丙酮 为溶剂， 反应 2.33h， 生成 2,5-二丁基苯胺
  参考文献：
  名称：

  ＯＬＥＤ素子形成用組成物及びＯＬＥＤ素子

  摘要：

  【问题】提供效率高且溶解性好的发光材料。【解决方法】具有芘骨架的芳香族胺衍生物，例如由下述化合物1表示的芳香族胺衍生物。含有上述芳香族胺衍生物的有机电致发光元件用发光材料。【选定图】图1

  公开号：

  JP2021075493A

文献信息

• Polymer composition
  申请人：DSM N.V.

  公开号：EP0538939A1

  公开（公告）日：1993-04-28

  The invention relates to a polymer composition based on a thermoplastic polymer and a polyaniline, characterised in that the thermoplastic polymer contains functional monomeric units and the polyaniline is grafted onto the thermoplastic polymer substantially through the reaction of the terminal NH₂ group of the polyaniline with a functional monomeric unit of the thermoplastic polymer. It has been found that the polymer composition according to the invention has good thermoplastic processability as well as good conductive properties. The polymer composition according to the invention is extremely suitable for the production of all kinds of objects.

  本发明涉及一种基于热塑性聚合物和聚苯胺的聚合物组合物，其特征在于热塑性聚合物含有官能团单体单元，而聚苯胺基本上是通过聚苯胺的末端 NH₂基团与热塑性聚合物的官能团单体单元反应接枝到热塑性聚合物上的。研究发现，本发明的聚合物组合物具有良好的热塑性加工性能和导电性能。本发明的聚合物组合物非常适用于生产各种物品。
• Dispersion of electrically conductive particles in a dispersing medium
  申请人：DSM N.V.

  公开号：EP0589529A1

  公开（公告）日：1994-03-30

  The invention relates to a dispersion of electrically conductive particles, comprising a binder and an electrically conductive polymer, and a stabiliser in a dispersing medium. The dispersion according to the invention is characterised in that the particles contain a non-ionic stabiliser. It has been found that the stability of the dispersion according to the invention is very good. In addition the dispersion according to the invention is extremely suitable for providing objects with a coating in a simple manner. The applied coating has good electrically conductive properties as well as good coating properties. The applied coating is homogeneously distributed over the coated object. Moreover the applied coating appears to adhere well to the object.

  本发明涉及一种导电微粒的分散体，包括分散介质中的粘合剂、导电聚合物和稳定剂。根据本发明的分散体的特点是颗粒中含有非离子稳定剂。研究发现，本发明的分散液稳定性非常好。此外，本发明的分散体非常适合以简单的方式为物体提供涂层。涂覆的涂层具有良好的导电性能和涂覆性能。涂层均匀地分布在被涂物体上。此外，涂覆的涂层看起来与物体附着良好。
• Electrically conductive composition and elements containing solubilized polyaniline complex
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0758671A2

  公开（公告）日：1997-02-19

  Electrically conductive elements, such as imaging elements, can be prepared by applying electrically conductive coating compositions to a suitable support. The coating compositions include a polyaniline-protonic counter-ion complex in a first solvent that has certain Hansen solubility parameters, and a film-forming binder in a second common coating solvent. The total solids in the coating composition is less than or equal to 10 weight %, and the weight ratio of the binder to the complex is at least 1:1. Under these formulation conditions, the polyaniline protonic counter-ion complex is solubilized, rather than being in dispersed form, and is readily applied to form a thin, relatively transparent, electrically conductive film. Antistatic layers of photographic elements can be prepared in this manner.

  导电元件，如成像元件，可通过将导电涂层组合物涂在合适的支架上制备。涂层组合物包括在具有一定汉森溶解度参数的第一种溶剂中的聚苯胺-质子反离子复合物，以及在第二种普通涂层溶剂中的成膜粘合剂。涂层组合物中的总固体含量小于或等于 10 重量%，粘合剂与络合物的重量比至少为 1:1。在这些配制条件下，聚苯胺质子反离子络合物被溶解，而不是以分散的形式存在，并且很容易涂抹形成一层薄的、相对透明的导电薄膜。照相元件的抗静电层可以用这种方法制备。
• Aqueous coating dispersion, process for the preparation thereof and use thereof in anticorrosive paint
  申请人：DSM N.V.

  公开号：EP0821040A1

  公开（公告）日：1998-01-28

  The invention relates to an aqueous coating dispersion comprising at least electrically conductive particles, which particles comprise at least a first binder, a conductive polymer and a non-ionic stabiliser, characterised in that the coating dispersion contains 50 to 99 wt. %, relative to the total amount of solids present, of a second binder, which second binder consists of electrically non-conductive particles. The invention also relates to a process for the preparation of the aqueous coating dispersion and to the use thereof in an anticorrosive paint, to the anticorrosive paint based on the aqueous coating dispersion according to the invention and to the metals protected herewith.

  本发明涉及一种水性涂料分散体，该分散体至少包含导电颗粒，该导电颗粒至少包含第一粘合剂、导电聚合物和非离子稳定剂，其特征在于该涂料分散体包含相对于固体总量为50-99重量％的第二粘合剂，该第二粘合剂由不导电颗粒组成。本发明还涉及水性涂料分散体的制备工艺及其在防腐涂料中的应用，以及基于本发明水性涂料分散体的防腐涂料和受其保护的金属。
• Process to make a conductive composition of a fluorinated polymer which contains polyaniline
  申请人：Atofina

  公开号：EP1428857A1

  公开（公告）日：2004-06-16

  The process of the present invention is a process to make a conductive fluorinated polymer composition (also called composite) wherein : a) an aqueous solution of an anilinium salt is mixed with an aqueous dispersion of a fluorinated polymer, b) then an oxidant is added to the mixture of step a) to make a blend of said fluorinated polymer and doped polyaniline (PANI), c) by-products and unreacted aniline are removed by washing with water or an alcohol to get a blend of purified fluorinated polymer and doped PANI, d) eventually the purified fluorinated polymer and doped PANI of step c) can be mixed with an acid, e) water is removed from the purified fluorinated polymer and doped PANI of step c) or d) if any and the remaining powder is melted and shaped in films, pellets or any object.

  本发明的工艺是一种制造导电含氟聚合物组合物（又称复合材料）的工艺，其中： a) 将苯胺盐的水溶液与含氟聚合物的水分散液混合、 b) 然后向步骤 a) 的混合物中加入氧化剂，制成所述含氟聚合物和掺杂聚苯胺（PANI）的混合物、 c) 通过水或酒精洗涤去除副产物和未反应的苯胺，得到纯化的含氟聚合物和掺杂的 PANI 混合物、 d) 最终将步骤 c) 中纯化的含氟聚合物和掺杂的 PANI 与酸混合、 e) 除去步骤 c) 或 d) 中纯化的含氟聚合物和掺杂的 PANI（如有）中的水分，将剩余粉末熔化并制成薄膜、颗粒或任何物体。