4-acryloyloxymethyl-2-methoxy-2-methyl-1,3-dioxolane | 139995-55-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-acryloyloxymethyl-2-methoxy-2-methyl-1,3-dioxolane
• 英文别名: 4-acryloyloxymethyl-2-methoxy-2-methyl-1,3-dioxolan；(2-Methoxy-2-methyl-1,3-dioxolan-4-yl)methyl prop-2-enoate
• CAS: 139995-55-4
• 化学式: C₉H₁₄O₅
• 分子量: 202.207
• InChiKey: WSSDTBVNFVYNQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  54
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  原乙酸三甲酯 、 缩水甘油 、 丙烯酸 在 对甲苯磺酸 对苯二酚 作用下， 反应 1.75h， 以56%的产率得到4-acryloyloxymethyl-2-methoxy-2-methyl-1,3-dioxolane
  参考文献：
  名称：

  EP1714964

  摘要：

  公开号：

文献信息

• Method for making orthoester monomers
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0747375A1

  公开（公告）日：1996-12-11

  A method for making substituted orthoester monomers comprising the step of contacting diols having at least one graftable pi bond such as 1-allyloxy-2,3-propanediol, and orthocarboxylates such as trimethylorthoacetate in the absence or presence of inert solvents.

  一种制备取代的orthoester单体的方法，包括将至少具有一个可嫁接π键的二元醇（例如1-烯丙氧基-2,3-丙二醇）和ortho酯（例如三甲基正交酸酯）在惰性溶剂的存在或缺席下接触的步骤。
• Process for preparing unsaturated, cyclic orthoesters
  申请人：Ruwwe Johannes

  公开号：US20060281930A1

  公开（公告）日：2006-12-14

  An unsaturated, cyclic orthoester is prepared by reacting an unsaturated carboxylic acid with glycidol, thereby obtaining a reaction mixture; and adding an orthoester to the reaction mixture, thereby obtaining said unsaturated, cyclic orthoester.

  通过将不饱和羧酸与环氧丙醇反应制备出一种不饱和的环状正酯，从而获得反应混合物；然后将正酯加入反应混合物中，从而获得所述的不饱和环状正酯。
• Polymers of ethylenically unsaturated cyclic ortho esters
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0496116A1

  公开（公告）日：1992-07-29

  Ethylenically unsaturated cyclic ortho esters are prepared by the reaction of a hydroxy-substituted cyclic ortho ester such as 4-hydroxymethyl-2-methoxy-2-methyl-1,3-dioxolane with acryloyl chloride, methacryolyl chloride, vinylbenzyl chloride or the like. They form polymers, especially random copolymers with styrene and EPDM graft copolymers; the latter are useful in the formation of copolymer-containing compositions with polyesters, polyamides and the like. The copolymer-containing compositions have excellent physical properties and may be employed to compatibilize blends of the same polymers.

  乙烯基不饱和环原生酯是由羟基取代的环原生酯（如 4-羟甲基-2-甲氧基-2-甲基-1,3-二氧戊环）与丙烯酰氯、甲基丙烯酰氯、乙烯基苄基氯或类似物质反应制备而成。它们可形成聚合物，特别是与苯乙烯的无规共聚物和三元乙丙橡胶接枝共聚物；后者可与聚酯、聚酰胺等形成含共聚物的组合物。含共聚物的组合物具有优异的物理特性，可用于相容相同聚合物的混合物。
• Ethylenically unsaturated cyclic ortho esters
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0499717A1

  公开（公告）日：1992-08-26

  Ethylenically unsaturated cyclic ortho esters are prepared by the reaction of a hydroxy-substituted cyclic ortho ester such as 4-hydroxymethyl-2-methoxy-2-methyl-1,3-dioxolane with acryloyl chloride, methacryolyl chloride, vinylbenzyl chloride or the like. They form polymers, especially EPDM graft copolymers, which are useful in the formation of copolymer-containing compositions with polyesters, polyamides and the like. The copolymer-containing compositions have excellent physical properties and may be employed to compatibilize blends of the same polymers.

  乙烯基不饱和环原生酯是由羟基取代的环原生酯（如 4-羟甲基-2-甲氧基-2-甲基-1,3-二氧戊环）与丙烯酰氯、甲基丙烯酰氯、乙烯基苄基氯或类似物反应制备而成。它们形成的聚合物，特别是三元乙丙橡胶（EPDM）接枝共聚物，可用于与聚酯、聚酰胺等形成含共聚物的组合物。含共聚物的组合物具有优异的物理性能，可用于相容相同聚合物的混合物。
• Polyphenylene ether-graft-orthoester copolymer blends
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0564243A1

  公开（公告）日：1993-10-06

  A method for forming polyphenylene ether-graft-orthoester copolymer blends comprises blending functionalized polyphenylene ethers made with graftable orthoester moieties with nucleophilic polymers. Preferably the orthoester is 4-acryloyloxymethyl-2-methoxy-2-methyl-1,3-dioxolane monomer, and the nucleophilic polymers are selected from polyesters, polyamides, or functionalized polyolefins. The preferred method for blending is by a one-step process, in which all reactions occur in one pass.

  形成聚苯醚-接枝-邻位酯共聚物混合物的方法包括将具有可接枝邻位酯分子的官能化聚苯醚与亲核聚合物混合。邻位酯最好是 4-丙烯酰氧基甲基-2-甲氧基-2-甲基-1,3-二氧戊环单体，而亲核聚合物则选自聚酯、聚酰胺或官能化聚烯烃。优选的混合方法是一步法，即所有反应都在一次反应中完成。