1-(diallylamino)propan-2-one | 73813-61-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(diallylamino)propan-2-one
• 英文别名: Diallylamino-aceton；N,N-Diallylamino-propanon；diallylamino-acetone；Diallyl-acetonyl-amin；1-(di-2-propenylamino)-2-propanone；Diallylaminoacetone；1-[bis(prop-2-enyl)amino]propan-2-one
• CAS: 73813-61-3
• 化学式: C₉H₁₅NO
• mdl: MFCD24388606
• 分子量: 153.224
• InChiKey: NMQNNHLPNMVSQB-UHFFFAOYSA-N

物化性质

• 沸点：
  196.7±28.0 °C(Predicted)
• 密度：
  0.892±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.444
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  二烯丙基胺 在 水 作用下， 生成 1-(diallylamino)propan-2-one
  参考文献：
  名称：

  Perveev,F.Ya.; Statsevich,V.Ya., Journal of general chemistry of the USSR, 1964, vol. 34, p. 1747 - 1750

  摘要：

  DOI：

文献信息

• Electrochemical, Iodine-Mediated α-CH Amination of Ketones by Umpolung of Silyl Enol Ethers
  作者：Julia Strehl、Gerhard Hilt

  DOI：10.1021/acs.orglett.0c02068

  日期：2020.8.7

  oxidative Umpolung reaction of silyl enol ethers utilizing simple iodide salts for the synthesis of α-amino ketones is described. The products were isolated in excellent yields of up to 100%, and various functionalized starting materials were accepted in an undivided electrochemical cell design. Moreover, a sensitivity assessment to ensure an improved reproducibility of the reaction and cyclic voltammetry

  描述了利用简单的碘盐合成的α-氨基酮的甲硅烷基烯醇醚的电化学氧化Umpolung反应。分离出的产物的收率高达100％，且功能齐全的起始材料已被接受用于未拆分的电化学电池设计中。此外，为了确保反应的再现性得到改善，进行了敏感性评估，并进行了循环伏安法实验，以根据其基础推测出合理的反应机理。
• [EN] METAL FREE BLEACHING COMPOSITION<br/>[FR] COMPOSITION DE BLANCHIMENT DÉPOURVUE DE MÉTAL
  申请人：BASF SE

  公开号：WO2012000846A1

  公开（公告）日：2012-01-05

  The present invention relates to the use of a composition comprising specific a-amino- ketones, H2O2, a H2O2 precursor or a peracid and optionally an activator as a bleaching mixture for textile materials or dishes either manually or in an automatic washing machine or dish washer. Further aspects of the invention are the composition comprising specific a- aminoketones and H2O2, a H2O2 precursor or a peracid and a process for bleaching of stains or of soiling on textile materials or dishes in the context of a washing process either manually or in an automatic washing machine or dish washer. Also aspects of the invention are detergent formulations comprising such a composition and novel compounds.

  本发明涉及使用包含特定α-氨基酮、H2O2、H2O2前体或过氧酸以及可选的活化剂作为漂白混合物，用于手工或自动洗衣机或洗碗机中的纺织材料或餐具的漂白。该发明的其他方面包括包含特定α-氨基酮和H2O2、H2O2前体或过氧酸的组合物，以及用于手工或自动洗衣机或洗碗机中的洗涤过程中漂白纺织材料或餐具上的污渍或污垢的方法。此外，该发明的方面还包括包含这种组合物和新化合物的洗涤剂配方。
• Use Of Aminoacetones And Salts Thereof As Bleaching Boosters For Peroxygen Compounds
  申请人：Reinhardt Gerd

  公开号：US20090289221A1

  公开（公告）日：2009-11-26

  The use is claimed of aminoacetones or salts thereof of the general formulae (I) and (II) in which R 1 and R 2 are each independently hydrogen, C 1 -C 22 -alkyl, C 2 -C 22 -alkenyl, phenyl or C 5 -C 8 -cycloalkyl, or R 1 and R 2 , together with the nitrogen atom, form a 5-, 6- or 7-membered ring system, X′ is anion, for example chloride, bromide, iodide, toluenesulfonate, benzenesulfonate, cumenesulfonate, mesitylsulfonate, sulfate, hydrogensulfate, acetate, fatty acid anion or anion of polycarboxylates, as a bleaching booster for inorganic peroxygen compounds in the pH range from 7 to 9.

  使用一般式（I）和（II）的氨基酮或其盐，其中R1和R2分别独立地为氢、C1-C22烷基、C2-C22烯基、苯基或C5-C8环烷基，或R1和R2与氮原子一起形成5、6或7成员环系统，X'为阴离子，例如氯化物、溴化物、碘化物、甲苯磺酸盐、苯磺酸盐、叔丁基苯磺酸盐、二甲苯基磺酸盐、硫酸盐、氢硫酸盐、乙酸盐、脂肪酸阴离子或多羧酸盐的漂白增白剂，用于pH在7至9的无机过氧化物化合物。
• METAL FREE BLEACHING COMPOSITION
  申请人：Frey Markus

  公开号：US20130117941A1

  公开（公告）日：2013-05-16

  The present invention relates to the use of a composition comprising specific a-amino-ketones, H 2 O 2 , a H 2 O 2 precursor or a peracid and optionally an activator as a bleaching mixture for textile materials or dishes either manually or in an automatic washing machine or dish washer. Further aspects of the invention are the composition comprising specific a-aminoketones and H 2 O 2 , a H 2 O 2 precursor or a peracid and a process for bleaching of stains or of soiling on textile materials or dishes in the context of a washing process either manually or in an automatic washing machine or dish washer. Also aspects of the invention are detergent formulations comprising such a composition and novel compounds.

  本发明涉及使用一种包含特定α-氨基酮、H2O2、H2O2前体或过氧酸和可选激活剂的组合物作为漂白混合物，用于手动或自动洗衣机或洗碗机中的纺织材料或餐具。本发明的进一步方面是包含特定α-氨基酮和H2O2、H2O2前体或过氧酸的组合物的漂白过程，用于手动或自动洗衣机或洗碗机中的纺织材料或餐具上的污渍或污垢。此外，本发明的方面还包括包含这种组合物的洗涤剂配方和新化合物。
• Magee; Henze, Journal of the American Chemical Society, 1938, vol. 60, p. 2149,2150
  作者：Magee、Henze

  DOI：——

  日期：——

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