1,7-bis(5-methyl-4-imidazolyl)-2,6-dithiaheptane | 91631-43-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1,7-bis(5-methyl-4-imidazolyl)-2,6-dithiaheptane
• 英文别名: 4,4'-[Propane-1,3-diylbis(sulfanediylmethylene)]bis(5-methyl-1H-imidazole)；5-methyl-4-[3-[(5-methyl-1H-imidazol-4-yl)methylsulfanyl]propylsulfanylmethyl]-1H-imidazole
• CAS: 91631-43-5
• 化学式: C₁₃H₂₀N₄S₂
• 分子量: 296.461
• InChiKey: UNEGPPSRAZOWDV-UHFFFAOYSA-N

物化性质

• 熔点：
  143-145 °C
• 沸点：
  626.1±55.0 °C(Predicted)
• 密度：
  1?+-.0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  19
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  108
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,7-bis(5-methyl-4-imidazolyl)-2,6-dithiaheptane 、 copper(ll) bromide 以 乙醇 为溶剂， 生成 {1,7-bis(5-methyl-4-imidazolyl)-2,6-dithiaheptane}bis(bromide)copper(II)
  参考文献：
  名称：

  Coordination compounds with a biomimetic N2S2 ligand, resulting in long metal-thioether bonds. The crystal and molecular structure of [1,7-bis(5-methyl-4-imidazolyl)-2,6- dithiaheptane]bis(thiocyanato-N)cobalt(II)

  摘要：

  DOI：

  10.1016/s0277-5387(00)86422-0
• 作为产物：
  描述：

  1,3-丙二硫醇 、 4-羟甲基-5-甲基咪唑 在 溶剂黄146 作用下， 生成 1,7-bis(5-methyl-4-imidazolyl)-2,6-dithiaheptane
  参考文献：
  名称：

  Bouwman, E.; Driessen, W. L., Synthetic Communications, 1988, vol. 18, # 13, p. 1581 - 1588

  摘要：

  DOI：

文献信息

• Coordination compounds with a biomimetic N2S2 ligand, resulting in long metal-thioether bonds. The crystal and molecular structure of [1,7-bis(5-methyl-4-imidazolyl)-2,6- dithiaheptane]bis(thiocyanato-N)cobalt(II)
  作者：Jacobus Van Rijn、Elisabeth Bouwman、Jim R. Empfield、Willem L. Driessen、Jan Reedijk

  DOI：10.1016/s0277-5387(00)86422-0

  日期：1989.1
• Spectroscopic investigations of the electron self-exchange reaction of the perchlorate salt of [1,7-bis(5-methylimidazol-4-yl)-2,6-dithiaheptane]copper(n+) (n = 1, 2)
  作者：C. M. Groeneveld、J. Van Rijn、J. Reedijk、G. W. Canters

  DOI：10.1021/ja00223a004

  日期：1988.7
• BOUWMAN, E.;DRIESSEN, W. L., SYNTH. COMMUN., 18,(1988) N 13, C. 1581-1588
  作者：BOUWMAN, E.、DRIESSEN, W. L.

  DOI：——

  日期：——
• Sulfur-containing and sulfur-nitrogen-containing catalysts for polymerization of olefins and polar monomers
  申请人：——

  公开号：US20030171209A1

  公开（公告）日：2003-09-11

  The inventions disclosed herein are catalyst systems comprising a complex having one of the formulas LMX 1 X 2 and LML′ and an activating cocatalyst, and use of the catalyst system in polymerizing olefinic monomers. In either of the foregoing formulas, L is a chelating ligand containing sulfur donors; M is a transition metal selected from either copper, silver, gold, manganese, iron, cobalt, palladium or nickel; X 1 and X 2 are independently selected from either halides, hydride, triflate, acetate, borate, alkyl, alkoxyl, cycloalkyl, cycloalkoxyl, aryl, thiolate, carbon monoxide, cyanate or olefins; and L′ is a bidentate ligand selected from either dithiolene, dithiolate, diphosphine, bisimine, bispyridine, phenanthroline, oxolate, catecholate, thiolatoamide, thiolatoimine or thiolatophosphine.
• US6730757B2
  申请人：——

  公开号：US6730757B2

  公开（公告）日：2004-05-04