2-(phthalimidomethyl)triphenylene | 166898-50-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2-(phthalimidomethyl)triphenylene
• 英文别名: 2-(Triphenylen-2-ylmethyl)isoindole-1,3-dione；2-(triphenylen-2-ylmethyl)isoindole-1,3-dione
• CAS: 166898-50-6
• 化学式: C₂₇H₁₇NO₂
• 分子量: 387.437
• InChiKey: DWPIRXHLEVVPMA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  30
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-(phthalimidomethyl)triphenylene 在 一水合肼 作用下， 以 乙醇 为溶剂， 反应 2.0h， 以94%的产率得到2-(aminomethyl)triphenylene
  参考文献：
  名称：

  New Sensitizer-Modified Calix[4]arenes Enabling Near-UV Excitation of Complexed Luminescent Lanthanide Ions

  摘要：

  The synthesis is described of a series of calix[4]arenes with three different sensitizer chromophores (''antenna'') attached to the lower rim via a short spacer. In the Eu3+ and Tb3+ complexes of these calixarenes, photoexcitation of the antenna can induce lanthanide emission via intramolecular energy transfer. Although the higher energy of the Tb3+ luminescent state makes it more difficult to sensitize than in the case of Eu3+, especially a triphenylene antenna is found to have strong sensitizing ability toward not only Eu3+ but also Tb3+, allowing excitation of the lanthanide with wavelengths extending to 350 nm.

  DOI：

  10.1021/ja00142a004
• 作为产物：
  描述：

  9,10-苯并菲 在 硼烷四氢呋喃络合物 、 三溴化磷 、 四氯化钛 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 7.0h， 生成 2-(phthalimidomethyl)triphenylene
  参考文献：
  名称：

  New Sensitizer-Modified Calix[4]arenes Enabling Near-UV Excitation of Complexed Luminescent Lanthanide Ions

  摘要：

  The synthesis is described of a series of calix[4]arenes with three different sensitizer chromophores (''antenna'') attached to the lower rim via a short spacer. In the Eu3+ and Tb3+ complexes of these calixarenes, photoexcitation of the antenna can induce lanthanide emission via intramolecular energy transfer. Although the higher energy of the Tb3+ luminescent state makes it more difficult to sensitize than in the case of Eu3+, especially a triphenylene antenna is found to have strong sensitizing ability toward not only Eu3+ but also Tb3+, allowing excitation of the lanthanide with wavelengths extending to 350 nm.

  DOI：

  10.1021/ja00142a004

文献信息

• [EN] HOLE INJECTOR POLYMERS<br/>[FR] POLYMERES INJECTEURS DE TROUS
  申请人：THOMSON-CSF

  公开号：WO1999065961A1

  公开（公告）日：1999-12-23

  (EN) The invention relates to a new type of material that can be used for visual presentation in electroluminescent displays. The invention consists of straight-chain polymers containing active groups in terms of hole injection in an electroluminescent material. The above-mentioned active groups can be of a monopyrazoline or monoamine type.(FR) L'invention concerne un nouveau type de matériaux susceptibles d'être utilisés en visualisation dans des écrans électroluminescents. Il s'agit de polymères à chaînes latérales comportant des groupements actifs en terme d'injection de trous dans un matériau électroluminescent. Ces groupements actifs peuvent être de type monopyrazoline ou de type monoamine.
• New Sensitizer-Modified Calix[4]arenes Enabling Near-UV Excitation of Complexed Luminescent Lanthanide Ions
  作者：Frank J. Steemers、Willem Verboom、David N. Reinhoudt、Erik B. van der Tol、Jan W. Verhoeven

  DOI：10.1021/ja00142a004

  日期：1995.9

  The synthesis is described of a series of calix[4]arenes with three different sensitizer chromophores (''antenna'') attached to the lower rim via a short spacer. In the Eu3+ and Tb3+ complexes of these calixarenes, photoexcitation of the antenna can induce lanthanide emission via intramolecular energy transfer. Although the higher energy of the Tb3+ luminescent state makes it more difficult to sensitize than in the case of Eu3+, especially a triphenylene antenna is found to have strong sensitizing ability toward not only Eu3+ but also Tb3+, allowing excitation of the lanthanide with wavelengths extending to 350 nm.