4-(7,10-diphenylfluoranthen-8-yl)benzenamine | 1333998-38-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 4-(7,10-diphenylfluoranthen-8-yl)benzenamine
• 英文别名: 4-(7,10-Diphenylfluoranthen-8-yl)aniline；4-(7,10-diphenylfluoranthen-8-yl)aniline
• CAS: 1333998-38-1
• 化学式: C₃₄H₂₃N
• 分子量: 445.563
• InChiKey: KKJXCKRICBIROC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  35
• 可旋转键数：
  3
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-(2-甲酰基-4-甲基-1,8-萘啶-7-基)乙酰胺 、 4-(7,10-diphenylfluoranthen-8-yl)benzenamine 以 甲醇 为溶剂， 反应 5.0h， 以71%的产率得到(E)-N-(7-((4-(7,10-diphenylfluoranthen-8-yl)phenylimino)methyl)-5-methyl-1,8-naphthyridin-2-yl)acetamide
  参考文献：
  名称：

  An ‘off–on’ fluorescent chemosensor of selectivity to Cr3+ and its application to MCF-7 cells

  摘要：

  A 'switching-on' fluorescent chemosensor for the selective and sensitive signaling of intraceullar Cr3+ has been designed and synthesized exploiting the guest-induced prohibition of the photoinduced electron transfer process between naphthyridine moiety and 7,10-diphenylfluoranthene moiety, the system shows a Cr3+-selective chelation-enhanced fluorescence response not only in ethanol but in cell. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2011.07.008
• 作为产物：
  描述：

  4[(三甲基硅基)乙炔基]苯胺 在 potassium hydroxide 作用下， 以 四氢呋喃 、 甲醇 、 邻二甲苯 为溶剂， 反应 20.0h， 生成 4-(7,10-diphenylfluoranthen-8-yl)benzenamine
  参考文献：
  名称：

  A fluorescent color/intensity changed chemosensor for Fe3+ by photo-induced electron transfer (PET) inhibition of fluoranthene derivative

  摘要：

  A fluorescent color/intensity changed fluoranthene derivative chemosensor for Fe3+ has been prepared and confirmed by H-1-NMR, C-13-NMR, HRMS, and crystal data, which displays a high selectivity and antidisturbance for Fe3+ among environmentally and biologically relevant metal ions. Fluorescence studies show that fluorescent emission peak blue shifts about 100 nm with fluorescent intensity enhancing 75-fold, indicating a Fe3+-selective dual-emission behavior. Further study demonstrates the detection limit on fluorescence response of the sensor to Fe3+ is down to 10(-7) M range. The fluorescence signals of chemosensor can be restored with o-phenanthroline, showing the binding of chemosensor and Fe3+ is really chemically reversible. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.11.007

文献信息

• [EN] COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE COMPRISING SAME<br/>[FR] COMPOSÉ ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LE COMPRENANT<br/>[KO] 화합물 및 이를 포함하는 유기 발광 소자
  申请人：LG CHEMICAL LTD

  公开号：WO2021241900A1

  公开（公告）日：2021-12-02

  본 명세서는 화학식 1의 화합물 및 이를 포함하는 유기 발광 소자에 관한 것이다.
• An ‘off–on’ fluorescent chemosensor of selectivity to Cr3+ and its application to MCF-7 cells
  作者：Zhanxian Li、Wanying Zhao、Yuna Zhang、Lifeng Zhang、Mingming Yu、Jinxia Liu、Hongyan Zhang

  DOI：10.1016/j.tet.2011.07.008

  日期：2011.9

  A 'switching-on' fluorescent chemosensor for the selective and sensitive signaling of intraceullar Cr3+ has been designed and synthesized exploiting the guest-induced prohibition of the photoinduced electron transfer process between naphthyridine moiety and 7,10-diphenylfluoranthene moiety, the system shows a Cr3+-selective chelation-enhanced fluorescence response not only in ethanol but in cell. (C) 2011 Elsevier Ltd. All rights reserved.
• A fluorescent color/intensity changed chemosensor for Fe3+ by photo-induced electron transfer (PET) inhibition of fluoranthene derivative
  作者：Zhanxian Li、Lifeng Zhang、Xiaoya Li、Yongkai Guo、Zhonghai Ni、Jianhong Chen、Liuhe Wei、Mingming Yu

  DOI：10.1016/j.dyepig.2011.11.007

  日期：2012.7

  A fluorescent color/intensity changed fluoranthene derivative chemosensor for Fe3+ has been prepared and confirmed by H-1-NMR, C-13-NMR, HRMS, and crystal data, which displays a high selectivity and antidisturbance for Fe3+ among environmentally and biologically relevant metal ions. Fluorescence studies show that fluorescent emission peak blue shifts about 100 nm with fluorescent intensity enhancing 75-fold, indicating a Fe3+-selective dual-emission behavior. Further study demonstrates the detection limit on fluorescence response of the sensor to Fe3+ is down to 10(-7) M range. The fluorescence signals of chemosensor can be restored with o-phenanthroline, showing the binding of chemosensor and Fe3+ is really chemically reversible. (C) 2011 Elsevier Ltd. All rights reserved.