2-(2-{2-[1,1-difluoro-2-(2,3,5,6-tetrafluoro-4-vinyl-phenoxy)-ethoxy]-1,1,2,2-tetrafluoro-ethoxy}-1,1,2,2-tetrafluoro-ethoxy)-2,2-difluoro-ethanol | 1234306-88-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-(2-{2-[1,1-difluoro-2-(2,3,5,6-tetrafluoro-4-vinyl-phenoxy)-ethoxy]-1,1,2,2-tetrafluoro-ethoxy}-1,1,2,2-tetrafluoro-ethoxy)-2,2-difluoro-ethanol
• 英文别名: 2,2,4,4,5,5,7,7,8,8,10,10-Dodecafluoro-11-(4-vinyl-2,3,5,6-tetrafluorophenoxy)-3,6,9-trioxaundecane-1-ol；2-[2-[2-[2-(4-ethenyl-2,3,5,6-tetrafluorophenoxy)-1,1-difluoroethoxy]-1,1,2,2-tetrafluoroethoxy]-1,1,2,2-tetrafluoroethoxy]-2,2-difluoroethanol
• CAS: 1234306-88-7
• 化学式: C₁₆H₈F₁₆O₅
• 分子量: 584.211
• InChiKey: KKLMMIYTTSSBQP-UHFFFAOYSA-N

物化性质

• 沸点：
  428.1±45.0 °C(Predicted)
• 密度：
  1.650±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  37
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  57.2
• 氢给体数：
  1
• 氢受体数：
  21

反应信息

• 作为反应物：
  描述：

  十氟联苯 、 2-(2-{2-[1,1-difluoro-2-(2,3,5,6-tetrafluoro-4-vinyl-phenoxy)-ethoxy]-1,1,2,2-tetrafluoro-ethoxy}-1,1,2,2-tetrafluoro-ethoxy)-2,2-difluoro-ethanol 在 calcium hydride 、 cesium fluoride 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 48.0h， 以95%的产率得到2,3,5,6,2′,3′,5′,6′-octafluoro-4,4′-bis-[2-(2-{2-[1,1-difluoro-2-(2,3,5,6-tetrafluoro-4-vinyl-phenoxy)-ethoxy]-1,1,2,2-tetrafluoro-ethoxy}-1,1,2,2-tetrafluoro-ethoxy)-2,2-difluoro-ethoxy]-biphenyl
  参考文献：
  名称：

  Highly fluorinated and photocrosslinkable liquid prepolymers for flexible optical waveguides

  摘要：

  我们对用于柔性光波导的高氟化液态预聚物及其紫外固化薄膜进行了评估。Two liquid prepolymers, 2,3,5,6,2′,3′,5′,6′-octafluoro-4,4′-bis-[2-{2-[1,1-difluoro-2-(2,3,5,6-tetrafluoro-4-vinyl-phenoxy)-ethoxy]-1,1,2,2-tetrafluoro-ethoxy}-2,2-difluoro-ethoxy]-biphenyl (7) and 2,3,5,6,2′,3′,5′,6′-octafluoro-4,4′-bis-[2-(2-{2-[1,1-difluoro-2-(2,2-(2-{2-[1,1-二氟-2-(2,3,5,6-四氟-4-乙烯基-苯氧基)-乙氧基]-1,1,2,2-四氟-乙氧基}-1,1,2,2-四氟-乙氧基)-2,2-二氟-乙氧基]-联苯 (8) 由十氟联苯、2,3,4,5,6-五氟苯乙烯和氟化三乙二醇或氟化四乙二醇合成。这些预聚物经光固化后可形成柔韧透明的薄膜。用这些预聚物制成的薄膜的折射率受其混合成分的控制，在波长为 1.31 μm 时为 1.417-1.437。在波长为 1.31 μm 时，用预聚物 7 和 8 制备的薄膜的光学损耗分别为 0.25 和 0.23 dB cm-1。薄膜在 400 °C 以上的温度下具有热稳定性。用预聚物 7 和 8 制备的薄膜的极限应力、初始模量和伸长率分别为 17.1 兆帕、1.25 千兆帕和 1.5%，以及 12.3 兆帕、0.44 千兆帕和 6.9%。用这些预聚物制造的光波导无需任何基底膜即可弯曲，弯曲半径为 1.5 毫米时的光损耗低于 0.2 分贝。通过研究用液态预聚物制造的柔性光波导中的光传输，我们确定液态预聚物可能是柔性光波导应用的理想候选材料。

  DOI：

  10.1039/c0jm02604b
• 作为产物：
  描述：

  1H,1H,11H,11H-全氟-3,6,9-三噁十一烷-1,11-二醇 、 2,3,4,5,6-五氟苯乙烯 在 potassium carbonate 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 24.0h， 以45%的产率得到2-(2-{2-[1,1-difluoro-2-(2,3,5,6-tetrafluoro-4-vinyl-phenoxy)-ethoxy]-1,1,2,2-tetrafluoro-ethoxy}-1,1,2,2-tetrafluoro-ethoxy)-2,2-difluoro-ethanol
  参考文献：
  名称：

  Highly fluorinated and photocrosslinkable liquid prepolymers for flexible optical waveguides

  摘要：

  我们对用于柔性光波导的高氟化液态预聚物及其紫外固化薄膜进行了评估。Two liquid prepolymers, 2,3,5,6,2′,3′,5′,6′-octafluoro-4,4′-bis-[2-{2-[1,1-difluoro-2-(2,3,5,6-tetrafluoro-4-vinyl-phenoxy)-ethoxy]-1,1,2,2-tetrafluoro-ethoxy}-2,2-difluoro-ethoxy]-biphenyl (7) and 2,3,5,6,2′,3′,5′,6′-octafluoro-4,4′-bis-[2-(2-{2-[1,1-difluoro-2-(2,2-(2-{2-[1,1-二氟-2-(2,3,5,6-四氟-4-乙烯基-苯氧基)-乙氧基]-1,1,2,2-四氟-乙氧基}-1,1,2,2-四氟-乙氧基)-2,2-二氟-乙氧基]-联苯 (8) 由十氟联苯、2,3,4,5,6-五氟苯乙烯和氟化三乙二醇或氟化四乙二醇合成。这些预聚物经光固化后可形成柔韧透明的薄膜。用这些预聚物制成的薄膜的折射率受其混合成分的控制，在波长为 1.31 μm 时为 1.417-1.437。在波长为 1.31 μm 时，用预聚物 7 和 8 制备的薄膜的光学损耗分别为 0.25 和 0.23 dB cm-1。薄膜在 400 °C 以上的温度下具有热稳定性。用预聚物 7 和 8 制备的薄膜的极限应力、初始模量和伸长率分别为 17.1 兆帕、1.25 千兆帕和 1.5%，以及 12.3 兆帕、0.44 千兆帕和 6.9%。用这些预聚物制造的光波导无需任何基底膜即可弯曲，弯曲半径为 1.5 毫米时的光损耗低于 0.2 分贝。通过研究用液态预聚物制造的柔性光波导中的光传输，我们确定液态预聚物可能是柔性光波导应用的理想候选材料。

  DOI：

  10.1039/c0jm02604b

文献信息

• Blend prepared by mixing a prepolymer and a vinyl monomer and a polymer sheet obtained therefrom
  申请人：ELECTRONICS AND TELECOMMUNICATIONS RESEARCH INSTITUTE

  公开号：US09864104B2

  公开（公告）日：2018-01-09

  Disclosed is a blend prepared by mixing a prepolymer and a vinyl monomer, wherein the prepolymer is prepared by a condensation reaction between a first compound represented by the formula Ar—H, where Ar comprises (a) a crosslinkable moiety at one end, (b) a moiety selected from the group consisting of —O—, —S—, —COO—, —CO—, —COS—, —SO2—, and —NH—, and (c) one or two repeating units selected from the group consisting of: where A is carbon or nitrogen, and X is hydrogen or halogen; and a second compound consisting of an aromatic moiety. Additionally disclosed is a polymer sheet that is a crosslinked product composed of the blend.

  本文披露了一种混合物，由预聚物和乙烯单体混合制备而成。其中，预聚物通过第一化合物（化学式为Ar-H）和第二化合物（含有芳香基团）之间的缩合反应制备而成。其中Ar在一端包含可交联的基团(a)，在另一端包含选自以下基团组合的基团(b)：—O—、—S—、—COO—、—CO—、—COS—、—SO2—和—NH—，以及选自以下重复单元组合的一个或两个重复单元(c)：其中A为碳或氮，X为氢或卤素。此外，本文还披露了一种由该混合物交联而成的聚合物片。
• Composition for forming film having wrinkle structure and method of forming the film
  申请人：ELECTRONICS AND TELECOMMUNICATIONS RESEARCH INSTITUTE

  公开号：US10472276B2

  公开（公告）日：2019-11-12

  A composition for forming film having wrinkle structure and a method of forming the film are disclosed. The composition includes photo-curable agent and photoinitiator dissolved in the photo-curable agent. The cut off wavelength of light transmittance of the photo-curable agent is greater than the cut off wavelength of light absorbance of the photoinitiator. Photo-cured thin film is formed at the upper portion of composition layer at an initial time period of irradiation. By subsequent contraction, the photo-cured thin film forms wrinkles. The wrinkle structure is controlled by the relation of the cut off wavelength of light transmittance of the photo-curable agent and the cut off wavelength of light absorbance of the photoinitiator, the photo-curing rate of the composition and the thickness of the composition layer, and the photoinitiator concentration, etc., before photo-curing. The film may increase the emission efficiency of LED and OLED and the sensing effect of sensor.

  本发明公开了一种用于形成具有皱纹结构的薄膜的组合物和形成薄膜的方法。该组合物包括光固化剂和溶解在光固化剂中的光引发剂。光固化剂的透光截止波长大于光引发剂的吸光截止波长。光固化薄膜在照射的初始阶段形成于成分层的上部。通过随后的收缩，光固化薄膜形成皱纹。皱纹结构由光固化剂透光截止波长和光引发剂吸光截止波长的关系、光固化前成分的光固化速率和成分层厚度以及光引发剂浓度等因素控制。该薄膜可提高 LED 和 OLED 的发射效率以及传感器的传感效果。
• COMPOUND CONTAINING CROSSLINKABLE MOIETIES, PREPOLYMER, BLEND AND POLYMER SHEET OBTAINED THEREFROM, AND WAVEGUIDE FOR OPTICAL INTERCONNECTION
  申请人：PARK Seung Koo

  公开号：US20100172623A1

  公开（公告）日：2010-07-08

  A compound containing a crosslinkable moiety, a curable prepolymer, a blend, and a polymer sheet obtained therefrom, and an optical waveguide for optical interconnection. The compound is represented by the formula below: Ar—H wherein Ar includes a crosslinkable moiety at one end, a moiety selected from the group consisting of —O—, —S—, —COO—, —CO—, —COS—, —SO 2 —, and —NH—, and one or two repeating units selected from the group consisting of the following repeating units: wherein A in the repeating unit is carbon or nitrogen, and X is hydrogen or halogen. At least one of the core and the cladding in the optical waveguide includes the polymer sheet.
• Compound containing crosslinkable moieties, prepolymer, blend and polymer sheet obtained therefrom, and waveguide for optical interconnection
  申请人：Electronics and Telecommunications Research Institute

  公开号：US20140219625A1

  公开（公告）日：2014-08-07

  An optical waveguide for optical interconnection including a polymer sheet comprising a crosslinked product of a prepolymer, the prepolymer prepared by condensation reaction between a first compound represented by the formula Ar—H, where Ar comprises (a) a crosslinkable moiety at one end, (b) a moiety selected from the group consisting of —O—, —S—, —COO—, —CO—, —COS—, —SO 2 —, and —NH—, and (c) one or two repeating units selected from the group consisting of: where A is carbon or nitrogen, and X is hydrogen or halogen; and a second compound consisting of an aromatic moiety.
• COMPOSITION FOR FORMING FILM HAVING WRINKLE STRUCTURE AND METHOD OF FORMING THE FILM
  申请人：ELECTRONICS AND TELECOMMUNICATIONS RESEARCH INSTITUTE

  公开号：US20160159686A1

  公开（公告）日：2016-06-09

  A composition for forming film having wrinkle structure and a method of forming the film are disclosed. The composition includes photo-curable agent and photoinitiator dissolved in the photo-curable agent. The cut off wavelength of light transmittance of the photo-curable agent is greater than the cut off wavelength of light absorbance of the photoinitiator. Photo-cured thin film is formed at the upper portion of composition layer at an initial time period of irradiation. By subsequent contraction, the photo-cured thin film forms wrinkles. The wrinkle structure is controlled by the relation of the cut off wavelength of light transmittance of the photo-curable agent and the cut off wavelength of light absorbance of the photoinitiator, the photo-curing rate of the composition and the thickness of the composition layer, and the photoinitiator concentration, etc., before photo-curing. The film may increase the emission efficiency of LED and OLED and the sensing effect of sensor.