triphenylene-2,11-diol | 1115023-90-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: triphenylene-2,11-diol
• CAS: 1115023-90-9
• 化学式: C₁₈H₁₂O₂
• 分子量: 260.292
• InChiKey: AMBHXBFZKPCREF-UHFFFAOYSA-N

物化性质

• 沸点：
  562.1±23.0 °C(Predicted)
• 密度：
  1.379±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  20
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  triphenylene-2,11-diol 在 1,1'-双(二苯膦基)二茂铁二氯化钯(II)二氯甲烷复合物 、 potassium acetate 、 sodium carbonate 作用下， 以 1,4-二氧六环 、 N,N-二甲基甲酰胺 为溶剂， 反应 22.0h， 生成 2,11-bis(4,4,5,5-tetramethyl-[1,3,2]dioxabororan-2-yl)triphenylene
  参考文献：
  名称：

  EP2679581

  摘要：

  公开号：
• 作为产物：
  描述：

  2,11-dimethoxytriphenylene 在 吡啶盐酸盐 作用下， 反应 2.0h， 以94%的产率得到triphenylene-2,11-diol
  参考文献：
  名称：

  [EN] SINGLE TRIPHENYLENE CHROMOPHORES IN PHOSPHORESCENT LIGHT EMITTING DIODES
  [FR] CHROMOPHORES À TRIPHÉNYLÈNE SIMPLE DANS DES DIODES ÉLECTROLUMINESCENTES PHOSPHORESCENTES

  摘要：

  提供了新型三苯基化合物。具体示例包括多芳基取代的三苯基化合物。一组首选化合物是被非融合芳基取代的三苯基化合物，该芳基具有一个或多个间位取代基，其中每个间位取代基是一个非融合芳基，可选地取代有来自非融合芳基和烷基组的进一步取代基。另一组首选化合物是被非融合杂芳基取代的三苯基化合物，该杂芳基具有一个或多个间位取代基，其中每个间位取代基是一个非融合芳基或杂芳基，可选地取代有来自非融合芳基、非融合杂芳基和烷基组的进一步取代基。预计一些高三重态能量的类似物将与深蓝色磷光掺杂剂配合使用。这些化合物可能在磷光有机发光器件中有用。还提供了一种有机电致发光器件，包括阳极、阴极和位于阳极和阴极之间的发射层，该发射层包括一个磷光材料和一个含有三苯基单元的化合物。

  公开号：

  WO2009021107A1

文献信息

• [EN] SINGLE TRIPHENYLENE CHROMOPHORES IN PHOSPHORESCENT LIGHT EMITTING DIODES<br/>[FR] CHROMOPHORES À TRIPHÉNYLÈNE SIMPLE DANS DES DIODES ÉLECTROLUMINESCENTES PHOSPHORESCENTES
  申请人：UNIVERSAL DISPLAY CORP

  公开号：WO2009021107A1

  公开（公告）日：2009-02-12

  Novel triphenylene compounds are provided. Specific examples include multi-aryl-substituted triphenylenes. A preferred group of compounds are triphenylenes that are substituted with a non-fused aryl group having one or more meta-substituents, where each meta-substituent is a non-fused aryl group optionally substituted with further substituents selected from the group consisting of non-fused aryl groups and alkyl groups. A further preferred group of compounds are triphenylenes that are substituted with a non-fused heteroaryl group having one or more meta-substituents, where each meta-substituent is a non-fused aryl or heteroaryl group optionally substituted with further substituents selected from the group consisting of non-fused aryl groups, non-fused heteroaryl groups, and alkyl groups. Some high triplet energy analogs are expected to work with deep blue phosphorescent dopants. The compounds may be useful in phosphorescent organic light emitting devices. Also provided is an organic electroluminescent device comprising an anode, a cathode, and an emissive layer between the anode and the cathode, the emissive layer comprising a phosphorescent material and a compound having a repeat unit, the repeat unit containing a triphenylene moiety.

  提供了新型三苯基化合物。具体示例包括多芳基取代的三苯基化合物。一组首选化合物是被非融合芳基取代的三苯基化合物，该芳基具有一个或多个间位取代基，其中每个间位取代基是一个非融合芳基，可选地取代有来自非融合芳基和烷基组的进一步取代基。另一组首选化合物是被非融合杂芳基取代的三苯基化合物，该杂芳基具有一个或多个间位取代基，其中每个间位取代基是一个非融合芳基或杂芳基，可选地取代有来自非融合芳基、非融合杂芳基和烷基组的进一步取代基。预计一些高三重态能量的类似物将与深蓝色磷光掺杂剂配合使用。这些化合物可能在磷光有机发光器件中有用。还提供了一种有机电致发光器件，包括阳极、阴极和位于阳极和阴极之间的发射层，该发射层包括一个磷光材料和一个含有三苯基单元的化合物。
• SINGLE TRIPHENYLENE CHROMOPHORES IN PHOSPHORESCENT LIGHT EMITTING DIODES
  申请人：Brooks Jason

  公开号：US20110084599A1

  公开（公告）日：2011-04-14

  Novel triphenylene compounds are provided. Specific examples include multi-aryl-substituted triphenylenes. A preferred group of compounds are triphenylenes that are substituted with a non-fused aryl group having one or more meta-substituents, where each meta-substituent is a non-fused aryl group optionally substituted with further substituents selected from the group consisting of non-fused aryl groups and alkyl groups. A further preferred group of compounds are triphenylenes that are substituted with a non-fused heteroaryl group having one or more meta-substituents, where each meta-substituent is a non-fused aryl or heteroaryl group optionally substituted with further substituents selected from the group consisting of non-fused aryl groups, non-fused heteroaryl groups, and alkyl groups. Some high triplet energy analogs are expected to work with deep blue phosphorescent dopants. The compounds may be useful in phosphorescent organic light emitting devices. Also provided is an organic electroluminescent device comprising an anode, a cathode, and an emissive layer between the anode and the cathode, the emissive layer comprising a phosphorescent material and a compound having a repeat unit, the repeat unit containing a triphenylene moiety.

  提供了新型三苯基烯化合物。具体例子包括多芳基取代的三苯基烯。首选化合物组是取代有一个或多个间位取代基的非融合芳基基团的三苯基烯，其中每个间位取代基是一个非融合芳基基团，可选地取代有选择自非融合芳基基团和烷基的进一步取代基。另一首选化合物组是取代有一个或多个间位取代基的非融合杂芳基基团的三苯基烯，其中每个间位取代基是一个非融合芳基或杂芳基基团，可选地取代有选择自非融合芳基基团、非融合杂芳基基团和烷基的进一步取代基。预计一些高三重态能量的类似物将与深蓝色磷光掺杂剂配合使用。这些化合物可能在磷光有机发光器件中有用。还提供了一种有机电致发光装置，包括阳极、阴极和位于阳极和阴极之间的发射层，该发射层包括磷光材料和具有重复单元的化合物，重复单元含有三苯基烯基团。
• Benzo-Fused Thiophene or Bezon-Fused Furan Compounds Comprising a Triphenylene Group
  申请人：Ma Bin

  公开号：US20100237334A1

  公开（公告）日：2010-09-23

  Triphenylene containing benzo-fused thiophene compounds are provided. Additionally, triphenylene containing benzo-fused furan compounds are provided. The compounds may be useful in organic light emitting devices, particularly as hosts in the emissive layer of such devices, or as materials for enhancement layers in such devices, or both.

  提供了含有苯并噻吩的三苯基乙烯化合物。此外，还提供了含有苯并呋喃的三苯基乙烯化合物。这些化合物可能在有机发光器件中有用，特别是作为发光层中的宿主或作为增强层材料，或者两者兼而有之。
• Benzo-fused thiophene or benzo-fused furan compounds comprising a triphenylene group
  申请人：Ma Bin

  公开号：US08367850B2

  公开（公告）日：2013-02-05

  Triphenylene containing benzo-fused thiophene compounds are provided. Additionally, triphenylene containing benzo-fused furan compounds are provided. The compounds may be useful in organic light emitting devices, particularly as hosts in the emissive layer of such devices, or as materials for enhancement layers in such devices, or both.

  本发明提供了含有苯并噻吩的三苯基乙烯化合物。此外，还提供了含有苯并呋喃的三苯基乙烯化合物。这些化合物可以在有机发光器件中发挥作用，特别是作为发射层中的主机，或作为增强层的材料，或两者兼而有之。
• COMPOUND HAVING SUBSTITUTED TRIPHENYLENE RING STRUCTURE, AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Adachi Chihaya

  公开号：US20140034936A1

  公开（公告）日：2014-02-06

  An organic compound having an excellent electron injection and transport performance is provided as a material for a low-power-consumption organic electroluminescent device. A low-power-consumption organic electroluminescent device is also provided by using the compound. The compound is a compound of general formula (1) or (2) having a substituted bipyridyl and triphenylene ring structure. The organic electroluminescent device includes a pair of electrodes, and one or more organic layers sandwiched between the pair of electrodes, and uses the compound as constituent material of at least one of the organic layers.

  本发明提供了一种具有优异的电子注入和传输性能的有机化合物，作为低功耗有机电致发光器件的材料。通过使用该化合物，还提供了一种低功耗有机电致发光器件。该化合物是一般式（1）或（2）的化合物，具有取代的联吡啶和三苯基烯环结构。该有机电致发光器件包括一对电极和夹在电极对之间的一个或多个有机层，并将该化合物用作至少一个有机层的组分材料。