4-Octene, 4-ethyl- | 89880-82-0

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 4-Octene, 4-ethyl-
• 英文别名: 4-ethyloct-4-ene
• CAS: 89880-82-0
• 化学式: C₁₀H₂₀
• 分子量: 140.269
• InChiKey: SCGMACYSUWTWRP-UHFFFAOYSA-N

物化性质

• 沸点：
  168.2±7.0 °C(Predicted)
• 密度：
  0.750±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-ethyl-2,3-dipropylaluminacyclopent-2-ene 在 三氟化硼乙醚 作用下， 以 正己烷 为溶剂， 反应 1.0h， 生成 4-Octene, 4-ethyl-
  参考文献：
  名称：

  Synthesis of substituted 2,3-dihydro-1H-boroles by transmetalation of aluminacyclopent-2-enes with BF3·Et2O

  摘要：

  A procedure was developed for selective synthesis of 4,5-dialkyl-1-fluoro-2,3-dihydro-1H-boroles via transmetalation of the corresponding aluminacyclopent-2-enes with BF3 center dot Et2O. 4,5-Dialkyl-1-fluoro-2,3-dihydro-1H-boroles were isolated as complexes with BEtF2. 4-Alkyl-5-dimethylaminomethyl-1-fluoro-2,3-dihydro-1H-boroles were synthesized for the first time.

  DOI：

  10.1134/s1070428012060024

文献信息

• Joint cycloalumination of ethylene and other unsaturated compounds with EtAlCl2 in the presence of Cp2ZrCl2. Synthesis of aluminacarbocycles
  作者：A. G. Ibragimov、L. O. Khafizova、L. I. Khusainova、T. V. Tyumkina、U. M. Dzhemilev

  DOI：10.1134/s1070428010040032

  日期：2010.4

  A procedure has been developed for the selective synthesis of five-membered aluminum-containing heterocycles, 2,3-dialkyl-1-ethylaluminacyclopent-2-enes, 3-alkyl-1-ethylaluminacyclopentanes, 2-alkylidene-1-ethylaluminacyclopentanes, and 3-alkyl-1-ethyl-2-methylidenealuminacyclopentanes, via joint cycloalumination of ethylene and other unsaturated compounds (acetylenes, olefins, and allenes) with EtAlCl2 in the presence of Cp2ZrCl2 as catalyst.