Tri(n-Heptyl)carbinol | 5340-53-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Tri(n-Heptyl)carbinol
• 英文别名: 8-Heptylpentadecan-8-ol
• CAS: 5340-53-4
• 化学式: C₂₂H₄₆O
• 分子量: 326.607
• InChiKey: CTXSMOGGQQVIQK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  23
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Tri(n-Heptyl)carbinol 在 碘 作用下， 生成 8-heptyl-pentadec-7-ene
  参考文献：
  名称：

  Mineralogy of Tagish Lake: An ungrouped type 2 carbonaceous chondrite

  摘要：

  Abstract— In this paper we describe the recovery, handling and preliminary mineralogical investigation of the Tagish Lake meteorite. Tagish Lake is a type 2 carbonaceous chondrite which bears similarities to CI1 and CM chondrite groups, but is distinct from both. Abundant phyllosilicates as well as chondrules (however sparse) and common olivine grains in the matrix preclude any other classification. The bulk density of Tagish Lake (1.67 g/cc) is far lower than CI or CM chondrites (2.2‐2.3 and 2.6‐2.9 g/cc, respectively), or any other meteorite for that matter. We have identified two lithologies: a dominant carbonate‐poor lithology and a less‐abundant carbonate‐rich lithology. The meteorite is a breccia at all scales.We have noted similarities between Tagish Lake and some clasts within the enigmatic meteorite Kaidun; possibly there are genetic relationships here worth exploring. In the paper we describe a clast of CM1 material within Tagish Lake which is very similar to a major lithology in Kaidun.

  DOI：

  10.1111/j.1945-5100.2002.tb00852.x
• 作为产物：
  描述：

  HEPTYLMAGNESIUM BROMIDE 、 碳酸二乙酯 在 乙醚 作用下， 生成 Tri(n-Heptyl)carbinol
  参考文献：
  名称：

  Mineralogy of Tagish Lake: An ungrouped type 2 carbonaceous chondrite

  摘要：

  Abstract— In this paper we describe the recovery, handling and preliminary mineralogical investigation of the Tagish Lake meteorite. Tagish Lake is a type 2 carbonaceous chondrite which bears similarities to CI1 and CM chondrite groups, but is distinct from both. Abundant phyllosilicates as well as chondrules (however sparse) and common olivine grains in the matrix preclude any other classification. The bulk density of Tagish Lake (1.67 g/cc) is far lower than CI or CM chondrites (2.2‐2.3 and 2.6‐2.9 g/cc, respectively), or any other meteorite for that matter. We have identified two lithologies: a dominant carbonate‐poor lithology and a less‐abundant carbonate‐rich lithology. The meteorite is a breccia at all scales.We have noted similarities between Tagish Lake and some clasts within the enigmatic meteorite Kaidun; possibly there are genetic relationships here worth exploring. In the paper we describe a clast of CM1 material within Tagish Lake which is very similar to a major lithology in Kaidun.

  DOI：

  10.1111/j.1945-5100.2002.tb00852.x

文献信息

• Synthesis of ketones and tertiary alcohols from trialkylboranes. Use of lithium tris(phenylthio)methanide
  作者：Andrew Pelter、J. Madhusudhana Rao

  DOI：10.1039/c39810001149

  日期：——

  The interaction of lithium tris(phenylthio)-methanide with trialkylboranes followed by oxidation allows the production of ketones or tertiary alcohols in good yields under mild conditions.

  三（苯硫基）甲硫基锂与三烷基硼烷的相互作用，然后进行氧化，可以在温和的条件下以高收率生产酮或叔醇。
• Lithium tris(phenylthio)methane for the homologation of trialkylboranes: Convenient syntheses of ketones and t-carbinols
  作者：Andrew Pelter、J.Madhusudhana Rao

  DOI：10.1016/0022-328x(85)87357-5

  日期：1985.4

  Lithium tris(phenylthio)methane is a readily available, cheap reagent for the production of ketones and t-carbinols from trialkylboranes. The scope and limitations of the reactions are indicated as are some of its unique features.

  三（苯硫基）甲烷锂是一种易于获得的廉价试剂，用于从三烷基硼烷生产酮和叔碳醇。指出了反应的范围和局限性及其一些独特特征。
• Breusch; Baykut, Chemische Berichte, 1955, vol. 88, p. 913,915, 916
  作者：Breusch、Baykut

  DOI：——

  日期：——
• Petrow; Kaplan, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1949, p. 539,544
  作者：Petrow、Kaplan

  DOI：——

  日期：——
• PELTER, A.;RAO, J. M., J. CHEM. SOC. CHEM. COMMUN., 1981, N 21, 1149-1150
  作者：PELTER, A.、RAO, J. M.

  DOI：——

  日期：——