2-ethoxy-non-1-ene | 54572-81-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-ethoxy-non-1-ene
• 英文别名: 2-Ethoxynon-1-ene
• CAS: 54572-81-5
• 化学式: C₁₁H₂₂O
• 分子量: 170.295
• InChiKey: OAJKVEVDEBDYIT-UHFFFAOYSA-N

物化性质

• 沸点：
  87-88 °C(Press: 15 Torr)
• 密度：
  0.805±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  乙氧基乙炔 以80%的产率得到
  参考文献：
  名称：

  ALEXAKIS A.; CAHIEZ G.; NORMANT J. F.; VILLIERAS J., BULL. SOC. CHIM. FRANCE, 1977, NO 7-8, PART. 2, 693-698

  摘要：

  DOI：

文献信息

• Methylenation of Esters with Bis(iodozincio)methane-TiCl₂-TMEDA System
  作者：Seijiro Matsubara、Katsumi Ukai、Tsuyoshi Mizuno、Kiitiro Utimoto

  DOI：10.1246/cl.1999.825

  日期：1999.8

  Methylenation of ester carbonyl group with bis(iodozincio)methane was examined: a use of TiCl2 and amine as mediators facilitated the reaction to give vinyl ethers in good yields.

  研究了酯羰基与双(碘锌)甲烷的甲基化：使用 TiCl 2 和胺作为介体促进了反应，以良好的产率得到乙烯基醚。
• Probe compound for detecting and isolating enzymes and means and methods using the same
  申请人：Helmholtz-Zentrum für Infektionsforschung GmbH

  公开号：EP2230312A1

  公开（公告）日：2010-09-22

  The present invention relates to a probe compound that can comprise any substrate or metabolite of an enzymatic reaction in addition to an indicator component, such as, for example, a fluorescence dye, or the like. Moreover, the present invention relates to means for detecting enzymes in form of an array, which comprises any number of probe compounds of the invention which each comprise a different metabolite of interconnected metabolites representing the central pathways in all forms of life. Moreover, the present invention relates to a method for detecting enzymes involving the application of cell extracts or the like to the array of the invention which leads to reproducible enzymatic reactions with the substrates. These specific enzymatic reactions trigger the indicator (e.g. a fluorescence signal) and bind the enzymes to the respective cognate substrates. Moreover, the invention relates to means for isolating enzymes in form of nanoparticles coated with the probe compound of the invention. The immobilisation of the cognate substrates or metabolites on the surface of nanoparticles by means of the probe compounds allows capturing and isolating the respective enzyme, e.g. for subsequent sequencing.

  本发明涉及一种探针化合物，它可以包括酶反应的任何底物或代谢物，此外还包括指示成分，例如荧光染料或类似物。此外，本发明还涉及以阵列形式检测酶的方法，该阵列由任意数量的本发明探针化合物组成，每种探针化合物由代表所有生命形式中中心途径的相互关联的代谢物中的不同代谢物组成。此外，本发明还涉及一种检测酶的方法，该方法涉及将细胞提取物或类似物应用于本发明的阵列，从而导致与底物发生可重复的酶反应。这些特定的酶反应会触发指示剂（如荧光信号），并将酶与各自的同源底物结合。此外，本发明还涉及以涂覆有本发明探针化合物的纳米颗粒形式分离酶的方法。通过探针化合物将同源底物或代谢物固定在纳米颗粒表面，可以捕获和分离相应的酶，例如用于后续测序。
• PROCESS FOR MAKING A CONSUMER PRODUCT COMPRISING MODIFIED POLYSACCHARIDES
  申请人：Procter & Gamble International Operations SA

  公开号：EP3604346A1

  公开（公告）日：2020-02-05

  A process for preparing a consumer product comprising a chemically modified polysaccharide, the process comprising the steps of combining a slurry comprising polysaccharide with a reactant to form a polysaccharide-reactant mixture, wherein the reactant comprises an ester group; combining a base with the polysaccharide-reactant mixture to form a polysaccharide-reactant-base mixture; and allowing the polysaccharide-reactant-base mixture to form a transesterified polysaccharide mixture, wherein the transesterified polysaccharide mixture comprises an alcohol.

  一种制备包含化学修饰多糖的消费品的工艺，该工艺包括以下步骤：将包含多糖的浆料与反应物结合形成多糖-反应物混合物，其中反应物包含酯基；将碱与多糖-反应物混合物结合，形成多糖-反应物-碱混合物；以及使多糖-反应物-碱混合物形成转酯化多糖混合物，其中转酯化多糖混合物包括醇。
• Alexakis,A. et al., Bulletin de la Societe Chimique de France, 1977, p. 693 - 698
  作者：Alexakis,A. et al.

  DOI：——

  日期：——
• Probe Compound for Detecting and Isolating Enzymes and Means and Methods Using the Same
  申请人：Golyshin Peter N.

  公开号：US20120231972A1

  公开（公告）日：2012-09-13

  The present invention relates to a probe compound that can comprise any substrate or metabolite of an enzymatic reaction in addition to an indicator component, such as, for example, a fluorescence dye, or the like. Moreover, the present invention relates to means for detecting enzymes in form of an array, which comprises any number of probe compounds of the invention which each comprise a different metabolite of interconnected metabolites representing the central pathways in all forms of life. Moreover, the present invention relates to a method for detecting enzymes involving the application of cell extracts or the like to the array of the invention which leads to reproducible enzymatic reactions with the substrates. These specific enzymatic reactions trigger the indicator (e.g. a fluorescence signal) and bind the enzymes to the respective cognate substrates. Moreover, the invention relates to means for isolating enzymes in form of nanoparticles coated with the probe compound of the invention. The immobilisation of the cognate substrates or metabolites on the surface of nanoparticles by means of the probe compounds allows capturing and isolating the respective enzyme, e.g. for subsequent sequencing.