2-乙氧基甲氧基辛烷 | 69537-84-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 2-乙氧基甲氧基辛烷
• 英文名称: 2-ethoxymethoxy-octane
• 英文别名: 2-(Ethoxymethoxy)octane
• CAS: 69537-84-4
• 化学式: C₁₁H₂₄O₂
• 分子量: 188.31
• InChiKey: DLZDREHZSGFILY-UHFFFAOYSA-N

物化性质

• 沸点：
  210.6±8.0 °C(Predicted)
• 密度：
  0.843±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  13
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  二乙氧基甲烷 、 仲辛醇 在 Nafion-H SAC-13 silica nanocomposite 作用下， 以 甲苯 为溶剂， 以79%的产率得到2-乙氧基甲氧基辛烷
  参考文献：
  名称：

  Efficient and Selective Formation of Mixed Acetals by Nafion‐H SAC‐13 Silica Nanocomposite Solid Acid Catalyst

  摘要：

  Various types of hydroxy compounds can readily be converted to the corresponding mixed acetals with dialkoxymethanes in the presence of SAC-13 solid superacid. The transformation is almost instantaneous, product acetals are isolated in good to excellent yields, and the catalyst can be reused with minor loss of activity. Comparative studies were also carried out with p-toluenesulfonic acid and BF3 (.) OEt2.

  DOI：

  10.1081/scc-200032419

文献信息

• Safiev, O. G.; Zorin, V. V.; Imashev, U. B., Journal of Organic Chemistry USSR (English Translation), 1980, vol. 16, # 7, p. 1192 - 1195
  作者：Safiev, O. G.、Zorin, V. V.、Imashev, U. B.、Zlotskii, S. S.、Terent'ev, A. B.、Rakhmankulov, D. L.

  DOI：——

  日期：——
• Telomerization of ethylene with ethylal
  作者：O. G. Safiev、U. B. Imashev、S. S. Zlotskii、D. L. Rakhmankulov、A. B. Terent'ev

  DOI：10.1007/bf00941103

  日期：1978.12
• Efficient and Selective Formation of Mixed Acetals by Nafion‐H SAC‐13 Silica Nanocomposite Solid Acid Catalyst
  作者：István Ledneczki、Árpád Molnár

  DOI：10.1081/scc-200032419

  日期：2004.1.1

  Various types of hydroxy compounds can readily be converted to the corresponding mixed acetals with dialkoxymethanes in the presence of SAC-13 solid superacid. The transformation is almost instantaneous, product acetals are isolated in good to excellent yields, and the catalyst can be reused with minor loss of activity. Comparative studies were also carried out with p-toluenesulfonic acid and BF3 (.) OEt2.