N-(4-vinylphenyl)-N′-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic diimide | 653693-73-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N-(4-vinylphenyl)-N′-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic diimide
• 英文别名: 7-(4-Ethenylphenyl)-18-tridecan-7-yl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• CAS: 653693-73-3
• 化学式: C₄₅H₄₂N₂O₄
• 分子量: 674.839
• InChiKey: IAULIUARRGGUCP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.9
• 重原子数：
  51
• 可旋转键数：
  13
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  十三烷-7-胺 、 4-乙烯苯胺 、 3,4,9,10-苝四羧酸二酐 在 咪唑 作用下， 反应 2.0h， 以41%的产率得到N-(4-vinylphenyl)-N′-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic diimide
  参考文献：
  名称：

  One-Step Synthesis of Unsymmetrical N-Alkyl-N′-aryl Perylene Diimides

  摘要：

  An efficient and facile protocol for the synthesis of unsymmetrical N-alkyl-N'-aryl perylene diimides is reported that circumvents the need for multiple reaction steps. A number of unsymmetrical perylene diimides containing a solubilizing swallowtail alkyl group and a variety of substituted aryl groups can be prepared in a single step from a simple mixture of amines.

  DOI：

  10.1021/jo500945k

文献信息

• Use of fluorescent polymers for the treatment of human hair
  申请人：Speckbacher Markus

  公开号：US20080187505A1

  公开（公告）日：2008-08-07

  The invention relates to the use of fluorescent polymers for the treatment of human hair, especially for the improvement of hair gloss or the brilliance of human hair or for hair diagnosis as well as corresponding hair treatment agents. The invention also relates to new fluorescent polymers as well as radically polymerizable fluorescent dyes for their preparation, especially those based on vinyl-substituted naphthalene bislactams and vinyl-substituted perylene hexacarboxylic acid trisimides.
• One-Step Synthesis of Unsymmetrical <i>N</i>-Alkyl-<i>N</i>′-aryl Perylene Diimides
  作者：Maxwell J. Robb、Brandon Newton、Brett P. Fors、Craig J. Hawker

  DOI：10.1021/jo500945k

  日期：2014.7.3

  An efficient and facile protocol for the synthesis of unsymmetrical N-alkyl-N'-aryl perylene diimides is reported that circumvents the need for multiple reaction steps. A number of unsymmetrical perylene diimides containing a solubilizing swallowtail alkyl group and a variety of substituted aryl groups can be prepared in a single step from a simple mixture of amines.