m-xylenediammonium galactarate | 709038-84-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: m-xylenediammonium galactarate
• 英文别名: m-Xylylenediammonium galactarate；[3-(azaniumylmethyl)phenyl]methylazanium;(2S,3R,4S,5R)-2,3,4,5-tetrahydroxyhexanedioate
• CAS: 709038-84-6
• 化学式: C₆H₁₀O₈*C₈H₁₂N₂
• 分子量: 346.337
• InChiKey: YNNYTIVKFFQFOK-OPDGLEOBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -6.9
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  217
• 氢给体数：
  6
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  甲醇 、 m-xylenediammonium galactarate 在 乙酰氯 作用下， 反应 4.0h， 生成 1,3-phenylenedimethanamine dihydrochloride 、 dimethyl galactarate
  参考文献：
  名称：

  Synthesis of Poly(galactaramides) from Alkylene- and Substituted Alkylenediammonium Galactarates

  摘要：

  Polyhydroxypolyamides (PHPAs) represent a class of synthetic polyamides derived from aldaric acid and diamine monomer units. This paper describes the synthesis of some poly(galactaramides), a class of polyhydroxypolyamides, that employs alkylene and substituted alkylenediammonium galactarate salts, with 1:1 molar equivalency of the diacid and diamine monomer components, as precursors for the polyamides. The salts were treated with acid/alcohol and then base in order to initiate the polymerization in methanol. The polyamides, labeled as prepolyamides, precipitated from solution and were then subjected to a second polymerization (postpolymerization) in a different solvent to produce a generally larger polyamide, labeled as a postpolyamide.

  DOI：

  10.1080/07328300903080749
• 作为产物：
  描述：

  间苯二甲胺 、 meso-galactaric acid 在 水 作用下， 以 水 为溶剂， 反应 40.0h， 以to give white solid, m-xylylenediammonium galactarate 14, 6.016 g, 17.372 mmol, 72.88%)的产率得到m-xylenediammonium galactarate
  参考文献：
  名称：

  Method for preparing high molecular weight random polyhydroxypolyamides

  摘要：

  高分子量随机聚羟基聚酰胺（PHPAs）是通过创建预聚物进一步聚合而产生的。随机预聚物是由化学计量比为1：1的起始材料形成的。起始材料是1：1化学计量平衡的酯化醛酸：lkylene或alkylene衍生的二胺盐。或者，起始材料是酯化的化学计量平衡的二酸：二胺盐和N'-氨基烷基（或烷基衍生）-D-aldaramic酸末端羧酸盐混合物。起始材料在碱性醇中使用第二胺聚合。聚合材料或随机预聚物被分离，然后在溶剂中进一步聚合，通常是醇和非醇的混合溶剂，以获得高分子量的PHPAs。

  公开号：

  US20040158029A1

文献信息

• Method for preparing high molecular weight random polyhydroxypolyamides
  申请人：——

  公开号：US20040158029A1

  公开（公告）日：2004-08-12

  High molecular weight random polyhydroxypolyamides (PHPAs) are produced by creating prepolymers which are further polymerized. Random prepolymers are formed from a stoichiometrically molar balance (1:1) starting material. The starting material is a 1:1 stoichiometrically balanced esterified aldaric acid:lkylene or alkylene derived diammonium salt. Alternatively, the starting material is an esterified stoichiometrically balanced diacid:diamine salt and a N′-ammoniumalkyl (or alkyl derived)-D-aldaramic acid terminal carboxylate zwitterionic salt mixture. The starting materials are polymerized in a basic alcohol using a second amine. The polymerized material, or the random prepolymers, are isolated and then further polymerized in a solvent, typically a mixed solvent of an alcohol and non-alcohol, to obtain the high molecular weight PHPAs.

  高分子量随机聚羟基聚酰胺（PHPAs）是通过创建预聚物进一步聚合而产生的。随机预聚物是由化学计量比为1：1的起始材料形成的。起始材料是1：1化学计量平衡的酯化醛酸：lkylene或alkylene衍生的二胺盐。或者，起始材料是酯化的化学计量平衡的二酸：二胺盐和N'-氨基烷基（或烷基衍生）-D-aldaramic酸末端羧酸盐混合物。起始材料在碱性醇中使用第二胺聚合。聚合材料或随机预聚物被分离，然后在溶剂中进一步聚合，通常是醇和非醇的混合溶剂，以获得高分子量的PHPAs。
• Synthesis of Poly(galactaramides) from Alkylene- and Substituted Alkylenediammonium Galactarates
  作者：Donald E. Kiely、Arvind Vishwanathan、Bevan P. Jarman、Merilyn Manley-Harris

  DOI：10.1080/07328300903080749

  日期：2009.7.29

  Polyhydroxypolyamides (PHPAs) represent a class of synthetic polyamides derived from aldaric acid and diamine monomer units. This paper describes the synthesis of some poly(galactaramides), a class of polyhydroxypolyamides, that employs alkylene and substituted alkylenediammonium galactarate salts, with 1:1 molar equivalency of the diacid and diamine monomer components, as precursors for the polyamides. The salts were treated with acid/alcohol and then base in order to initiate the polymerization in methanol. The polyamides, labeled as prepolyamides, precipitated from solution and were then subjected to a second polymerization (postpolymerization) in a different solvent to produce a generally larger polyamide, labeled as a postpolyamide.