α-pelargonyloxyethyl tert-butylperoxide | 87327-82-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: α-pelargonyloxyethyl tert-butylperoxide
• 英文别名: 1-(tert-Butylperoxy)ethyl nonanoate；1-tert-butylperoxyethyl nonanoate
• CAS: 87327-82-0
• 化学式: C₁₅H₃₀O₄
• 分子量: 274.401
• InChiKey: QKZOGKYJKRDQNU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  19
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  α-pelargonyloxyethyl tert-butylperoxide 在 二乙胺 作用下， 以 氯苯 为溶剂， 生成 叔丁醇 、 壬酸 、 alkaline earth salt of/the/ methylsulfuric acid 、 methane
  参考文献：
  名称：

  Turovskii, A. A.; Kucher, R. V.; Kushch, O. V, Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, p. 654 - 657

  摘要：

  DOI：
• 作为产物：
  描述：

  壬酸 、 2-(1-氯乙基过氧)-2-甲基丙烷 在 三乙胺 作用下， 以 氯仿 为溶剂， 以92%的产率得到α-pelargonyloxyethyl tert-butylperoxide
  参考文献：
  名称：

  Synthesis of α-hydroxyalkyl peroxide esters and ethers as initiators of radical processes

  摘要：

  alpha-Hydroxyalkyl peroxide esters and ethers containing, along with the peroxy bond, also acyloxy and alkoxy groups, are effective initiators of radical processes. The initiation efficiency is due to the capability of these molecules to generate simultaneously oxygen- and carbon-centered radicals capable of hydrogen abstraction from the substrate and of addition to > C=CaOE (c) bonds. The selectivity of the synthesis of alpha-hydroxyalkyl peroxide esters and ethers is mainly determined by the steps of the synthesis and isolation of the intermediate alpha-chloroalkyl peroxides, because of their high reactivity. Experimental conditions allowing control of the synthesis of alpha-hydroxyalkyl peroxide esters and ethers were found.

  DOI：

  10.1134/s1070427214120167

文献信息

• ALEJNIKOVA, T. P.;NAVROTSKIJ, V. A.;KARGINA, L. V., XIMIYA I TEXNOL. EHLEMENTOORGAN. POLUPRODUKTOV I POLIMEROV, VOLGOGRAD, 19+
  作者：ALEJNIKOVA, T. P.、NAVROTSKIJ, V. A.、KARGINA, L. V.

  DOI：——

  日期：——
• Synthesis of α-hydroxyalkyl peroxide esters and ethers as initiators of radical processes
  作者：T. P. Aleinikova、V. A. Navrotskii

  DOI：10.1134/s1070427214120167

  日期：2014.12

  alpha-Hydroxyalkyl peroxide esters and ethers containing, along with the peroxy bond, also acyloxy and alkoxy groups, are effective initiators of radical processes. The initiation efficiency is due to the capability of these molecules to generate simultaneously oxygen- and carbon-centered radicals capable of hydrogen abstraction from the substrate and of addition to > C=CaOE (c) bonds. The selectivity of the synthesis of alpha-hydroxyalkyl peroxide esters and ethers is mainly determined by the steps of the synthesis and isolation of the intermediate alpha-chloroalkyl peroxides, because of their high reactivity. Experimental conditions allowing control of the synthesis of alpha-hydroxyalkyl peroxide esters and ethers were found.
• Turovskii, A. A.; Kucher, R. V.; Kushch, O. V, Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, p. 654 - 657
  作者：Turovskii, A. A.、Kucher, R. V.、Kushch, O. V、Turovskii, N. A.

  DOI：——

  日期：——