4-Methyl-undec-1-en-4-ol | 72473-93-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-Methyl-undec-1-en-4-ol
• 英文别名: 4-Methylundec-1-en-4-ol
• CAS: 72473-93-9
• 化学式: C₁₂H₂₄O
• 分子量: 184.322
• InChiKey: GDLZUVHPPDXIOU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-Methyl-undec-1-en-4-ol 以85%的产率得到
  参考文献：
  名称：

  INABA, TERUHIKO;SAKAMOTO, MASAMI;WATANABE, SHOJI;TAKAHASHI, IKUFUMI;FUJIT+, J. CHEM. TECHNOL. AND BIOTECHNOL., 48,(1990) N, C. 483-492

  摘要：

  DOI：
• 作为产物：
  描述：

  十一碳-1-烯-4-酮 以95%的产率得到
  参考文献：
  名称：

  FUJITA TSUTOMU; WATANABE SHOJI; SUGA KYOICHI; INABA TERUHIKO, J. CHEM. TECHNOL. AND BIOTECHNOL., 1979, 29, NO 2, 100-106

  摘要：

  DOI：

文献信息

• Organomanganese (II) reagents XX: Manganese mediated Barbier and Reformatsky like reactions an efficient route to homoallylic alcohols and β-acetoxyesters
  作者：Gérard Cahiez、Pierre-Yves Chavant

  DOI：10.1016/s0040-4039(00)70700-3

  日期：1989.1

  Allylic halides and α-bromoesters react with manganese metal in ethyl acetate; THF can also be used as solvent if a catalytic amount of zinc chloride is added to the reaction mixture. When the reaction is performed in the presence of various aldehydes or ketones, excellent yields of 1,2-addition products are obtained in preparative conditions.

  烯丙基卤化物和α-溴酸酯与锰金属在乙酸乙酯中反应；如果将催化量的氯化锌加入到反应混合物中，则THF也可以用作溶剂。当反应在各种醛或酮的存在下进行时，在制备条件下可获得极好的1,2-加成产物收率。
• 1,8-Bis(allylstannyl)naphthalene Derivatives as Neutral Allylation Agents: Rate Acceleration by Chelation-Induced Lewis Acidity
  作者：Naoki Asao、Pingli Liu、Keiji Maruoka

  DOI：10.1002/anie.199725071

  日期：1997.12.1
• Allylation of ketones with allylstannanes catalyzed by Lewis acid–Lewis base combined reagents
  作者：Ryo Hamasaki、Yukiyasu Chounan、Hiroshi Horino、Yoshinori Yamamoto

  DOI：10.1016/s0040-4039(00)01755-x

  日期：2000.12

  Although the Lewis acid promoted allylation of ketones with allylstannanes gives the corresponding tert-homoallyl alcohols in lower yields in comparison with those of aldehydes, the use of Lewis acid-Lewis base combined catalysts such as Zn(OTf)(2)-2,6-lutidine and Zn(OTf)(2)-pyridine dramatically enhances the yield of the tert-alcohols. (C) 2000 Published by Elsevier Science Ltd.
• CAHIEZ, G.;CHAVANT, P. -Y., TETRAHEDRON LETT., 30,(1989) N2, C. 7373-7376
  作者：CAHIEZ, G.、CHAVANT, P. -Y.

  DOI：——

  日期：——
• INABA, TERUHIKO;SAKAMOTO, MASAMI;WATANABE, SHOJI;TAKAHASHI, IKUFUMI;FUJIT+, J. CHEM. TECHNOL. AND BIOTECHNOL., 48,(1990) N, C. 483-492
  作者：INABA, TERUHIKO、SAKAMOTO, MASAMI、WATANABE, SHOJI、TAKAHASHI, IKUFUMI、FUJIT+

  DOI：——

  日期：——