环己烷十二醇 | 54890-03-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 环己烷十二醇
• 英文名称: dodecahydroxycyclohexane
• 英文别名: Trichinoyl-hexahydrat (Cyclohexan-hexaon-hexahydrat)；cyclohexanedodecanol；cyclohexanedodecaol；Cyclohexandodecaol；Hexaketohexamethylen；Cyclohexanhexon；Trichinoyl；Cyclohexanedodecol；cyclohexane-1,1,2,2,3,3,4,4,5,5,6,6-dodecol
• CAS: 54890-03-8
• 化学式: C₆H₁₂O₁₂
• 分子量: 276.154
• InChiKey: MZIPHGCOJCDHPI-UHFFFAOYSA-N

物化性质

• 沸点：
  137.4±40.0 °C(Predicted)
• 密度：
  4.535±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -8.3
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  243
• 氢给体数：
  12
• 氢受体数：
  12

安全信息

• 海关编码：
  2906199090

反应信息

• 作为反应物：
  描述：

  环己烷十二醇 在 盐酸 、 tin(ll) chloride 作用下， 生成 六羟基苯
  参考文献：
  名称：

  Nietzki; Benckiser, Chemische Berichte, 1885, vol. 18, p. 500

  摘要：

  DOI：
• 作为产物：
  描述：

  六羟基苯 在 氯 作用下， 生成 环己烷十二醇
  参考文献：
  名称：

  Lerch, Justus Liebigs Annalen der Chemie, 1862, vol. 124, p. 34

  摘要：

  DOI：

文献信息

• Double Tridentate Complex of Triquinoyl with Boric Acid
  作者：Toshio Goto、Masanori Nagao

  DOI：10.1246/bcsj.47.246

  日期：1974.1

  Triquinoyl forms with boric acid a strongly acid double-tridentate complex, dipotassium salt of which is almost insoluble in water. The formation of this complex supports dodecahydroxycyclohexane structure for triquinoyl.

  三奎酰与硼酸形成一种强酸性的双三齿配位络合物，其二钾盐几乎不溶于水。该络合物的形成支持三奎酰具有十二羟基环己烷结构。
• Process for prevention and remediation of subterranean-formed metal-polymer complexes
  申请人：ROCKWATER ENERGY SOLUTIONS, LLC

  公开号：US11518928B2

  公开（公告）日：2022-12-06

  A completion/stimulation/production fluid and injection mixture blend is disclosed. The blend may include an aqueous fluid, a polymer system and an injection mixture that includes a polyol, a natural sugar, an artificial sugar, or a combination thereof.

  公开了一种完井/刺激/生产流体和注入混合物混合物。混合物可包括水性流体、聚合物系统和注入混合物，其中注入混合物包括多元醇、天然糖、人造糖或它们的组合。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.8, 8.4, page 122 - 128
  作者：

  DOI：——

  日期：——
• Highly conductive PEDOT:PSS films prepared through a treatment with geminal diols or amphiphilic fluoro compounds
  作者：Yijie Xia、Jianyong Ouyang

  DOI：10.1016/j.orgel.2012.05.039

  日期：2012.10

  Poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) films with high conductivity can have important application as the transparent electrode of optoelectronic devices. In this paper, we report the significant conductivity enhancement of PEDOT:PSS through a treatment with germinal diols which have two hydroxyl groups connected to one carbon atom or amphiphilic fluoro compounds which have hydrophobic fluorocarbon groups and hydrophilic hydroxyl or carboxylic groups. Several compounds, including hexafluoroacetone, cyclohexanehexone, formaldehyde, acetaldehyde, and perfluorobenzophenone, which could convert into geminal diols, were used to treat PEDOT:PSS films. The conductivity enhancements are generally consistent with the equilibrium constants for the conversion of these compounds into geminal diols. PEDOT:PSS films were also treated with several amphiphilic fluoro compounds. The conductivity was significantly enhanced when PEDOT:PSS films were treated with hexafluoroisopropanol, trifluroacetic acid and heptafluorobutyric acid, while it hardly changed when they were treated with 2,2,2-trifluoroethanol. Conductivities of more than 1000 S cm(-1) were observed on the treated PEDOT:PSS films. The mechanism for the conductivity enhancement of PEDOT:PSS through the treatment with geminal diols or amphiphilic fluoro compounds is attributed to the phase segregation of PSSH from PEDOT: PSS and conformational change of the PEDOT chains as the results of the compounds-induced reduction in the Coulombic attraction between the positively charged PEDOT and negatively charged PSS chains. (c) 2012 Elsevier B.V. All rights reserved.
• Nietzki; Benckiser, Chemische Berichte, 1885, vol. 18, p. 506,1842
  作者：Nietzki、Benckiser

  DOI：——

  日期：——