endo-1-methyl-5-norbornen-2-ol | 29750-14-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: endo-1-methyl-5-norbornen-2-ol
• 英文别名: 1-Methyl-norbornen-5-ol-(2)；2-Hydroxy-methylbicyclo[2.2.1]hept-5-ene；1-methylbicyclo[2.2.1]hept-5-en-2-ol
• CAS: 29750-14-9
• 化学式: C₈H₁₂O
• 分子量: 124.183
• InChiKey: DWPMBDKQFRROGO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  endo-1-methyl-5-norbornen-2-ol 、 丙炔 在 CO₂(CO) 作用下， 以 异辛烷 为溶剂， 反应 48.0h， 生成 5-Hydroxy-2,4-dimethyl-3a,4,5,6,7,7a-hexahydro-4,7-methano-inden-1-one 、 6-Hydroxy-2,7-dimethyl-3a,4,5,6,7,7a-hexahydro-4,7-methano-inden-1-one
  参考文献：
  名称：

  Pauson-Khand cycloaddition of norbornenones and norbornenols: electronic effect on regioselectivity

  摘要：

  DOI：

  10.1021/jo00236a045

文献信息

• METHOD FOR PRODUCING NORBORNENE MONOMER COMPOSITION, NORBORNENE POLYMER PREPARED THEREFROM, OPTICAL FILM COMPRISING THE NORBORNENE POLYMER, AND METHOD FOR PRODUCING THE NORBORNENE POLYMER
  申请人：CHUN Sung-Ho

  公开号：US20080319157A1

  公开（公告）日：2008-12-25

  Disclosed is a method for producing a norbornene monomer composition, a norbornene polymer produced using the norbornene monomer composition, an optical film including the norbornene polymer, and a method for producing the norbornene polymer. The method includes reacting a reaction solution that contains cyclopentadiene, dicyclopentadiene, or a mixture of cyclopentadiene and dicyclopentadiene, an acetate compound, and a solvent so that a content of an exo isomer is 50 mol % or more. Variables such as a reaction temperature, a reaction time, a molar ratio between reactants, and addition of a solvent are controlled so that the exo isomer is contained in content of 50 mol % or more. Accordingly, it is possible to industrially produce an acetate norbornene addition polymer by using the acetate norbornene monomer composition containing the exo isomer in content of 50 mol % or more.
• Method for Preparing Norbornene Monomer Composition, Norbornene Polymer Prepared Therefrom, Optical Film Comprising the Norbornene Polymer, and Method for Preparing the Norbornene Polymer
  申请人：Choi Dai-Seung

  公开号：US20100010177A1

  公开（公告）日：2010-01-14

  Disclosed is a method for producing a norbornene monomer composition, a norbornene polymer produced using the norbornene monomer composition, an optical film including the norbornene polymer, and a method for producing the norbornene polymer. The method includes reacting a reaction solution that contains cyclopentadiene, dicyclopentadiene, or a mixture of cyclopentadiene and dicyclopentadiene, an acetate compound, and a solvent so that a content of an exo isomer is 50 mol % or more. Variables such as a reaction temperature, a reaction time, a molar ratio between reactants, and addition of a solvent are controlled so that the exo isomer is contained in content of 50 mol % or more. Accordingly, it is possible to industrially produce an acetate norbornene addition polymer by using the acetate norbornene monomer composition containing the exo isomer in content of 50 mol % or more.
• US8207283B2
  申请人：——

  公开号：US8207283B2

  公开（公告）日：2012-06-26
• US8207279B2
  申请人：——

  公开号：US8207279B2

  公开（公告）日：2012-06-26
• [EN] METHOD FOR PREPARING NORBORNENE MONOMER COMPOSITION, NORBORNENE POLYMER PREPARED THEREFROM, OPTICAL FILM COMPRISING THE NORBORNENE POLYMER, AND METHOD FOR PREPARING THE NORBORNENE POLYMER<br/>[FR] PROCÉDÉ DE PRÉPARATION D'UNE COMPOSITION DE MONOMÈRE DE NORBORNÈNE, POLYMÈRE DE NORBORNÈNE AINSI PRÉPARÉ, FILM OPTIQUE COMPRENANT LEDIT POLYMÈRE ET PROCÉDÉ DE PRÉPARATION DE CE POLYMÈRE
  申请人：LG CHEMICAL LTD

  公开号：WO2008002066A1

  公开（公告）日：2008-01-03

  [EN] Disclosed is a method for producing a norbornene monomer composition, a norbornene polymer produced using the norbornene monomer composition, an optical film including the norbornene polymer, and a method for producing the norbornene polymer. The method includes reacting a reaction solution that contains cyclopentadiene, dicyclopentadiene, or a mixture of cyclopentadiene and dicyclopentadiene, an acetate compound, and a solvent so that a content of an exo isomer is 50 mol% or more. Variables such as a reaction temperature, a reaction time, a molar ratio between reactants, and addition of a solvent are controlled so that the exo isomer is contained in content of 50 mol% or more. Accordingly, it is possible to industrially produce an acetate norbornene addition polymer by using the acetate norbornene monomer composition containing the exo isomer in content of 50 mol% or more.
  [FR] L'invention concerne un procédé de production d'une composition de monomère de norbornène, un polymère de norbornène produit au moyen de ladite composition, un film optique contenant ledit polymère, et un procédé de production de ce polymère. Le procédé consiste à faire réagir une solution de réaction qui contient cyclopentadiène, dicyclopentadiène, ou un mélange de cyclopentadiène et de dicyclopentadiène, un composé d'acétate, et un solvant de manière qu'un contenu d'un isomère exo est égal ou supérieur à 50% molaire. Des variables, comme une température de réaction, un temps de réaction, un rapport molaire entre réactifs, et l'addition d'un solvant sont ajustés de façon que l'isomère exo contenu représente au moins 50% molaire. Par conséquent, il est possible de produire industriellement un polymère d'addition de norbornène d'acétate au moyen de la composition de monomère de norbornène d'acétate contenant au moins 50% molaire de l'isomère exo.