(Benzoyl)(pentafluorbenzoyl)methan | 23074-28-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: (Benzoyl)(pentafluorbenzoyl)methan
• 英文别名: 1-(2,3,4,5,6-Pentafluorophenyl)-3-phenylpropane-1,3-dione
• CAS: 23074-28-4
• 化学式: C₁₅H₇F₅O₂
• 分子量: 314.211
• InChiKey: VLCJDLCMYIZWOR-UHFFFAOYSA-N

物化性质

• 沸点：
  397.9±42.0 °C(Predicted)
• 密度：
  1.441±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  五氟苯甲酰氯 、 苯乙酮 在 polymer bound piperazine 、 对甲苯磺酸 、 三乙胺 、 盐酸 、 水 作用下， 以 苯 、 二氯甲烷 、 四氢呋喃 为溶剂， 反应 24.33h， 以42%的产率得到(Benzoyl)(pentafluorbenzoyl)methan
  参考文献：
  名称：

  固体-无痕迹的1,3-二酮类的合成相

  摘要：

  通过固相有机合成的烯胺方法已实现了1,3-二酮的无痕合成。因此，哌嗪用作该β-二酮从固体支持物的无痕裂解的连接子。

  DOI：

  10.1016/s0040-4039(02)02720-x

文献信息

• Light emitting device and lighting device using it, image display unit
  申请人：Yabe Akiko

  公开号：US20070132366A1

  公开（公告）日：2007-06-14

  An object of the present invention is to provide a light emitting device which is high in emission intensity and stable, that is to say, a light emitting device in which when an LED or LD having an emission peak at 380 nm to 410 nm is used as an excitation light source of the light emitting device, the emission intensity of a red phosphor does not largely change to some deviation of the emission wavelength of the LED or LD to maintain not only brightness but also a balance at the time when mixed with a blue and green phosphors. The present invention relates to a light emitting device characterized in that the device comprises a phosphor which has Eu 3+ as a luminescent center ion, in which a minimum emission intensity within the excitation wavelength range of 380 nm to 410 nm in an excitation spectrum is 65% or more of a maximum emission intensity, and which has an emission efficiency at 400 nm of 20% or more, and a semiconductor light emitting element which emits light in the region from near-ultraviolet light to visible light.
• Solid-phase synthesis of traceless 1,3-diketones
  作者：Kyung-Ho Park、Linda J Cox

  DOI：10.1016/s0040-4039(02)02720-x

  日期：2003.1

  A traceless synthesis of 1,3-diketones has been achieved through enamine methodology from solid-phase organic synthesis. Thus, piperazine served as a linker for this traceless cleavage of β-diketones from solid support.

  通过固相有机合成的烯胺方法已实现了1,3-二酮的无痕合成。因此，哌嗪用作该β-二酮从固体支持物的无痕裂解的连接子。