3-(Dimethylamino)-1-(2-pyridinyl)-1-propanone monohydrochloride | 100366-67-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-(Dimethylamino)-1-(2-pyridinyl)-1-propanone monohydrochloride
• 英文别名: 3-(dimethylamino)-1-pyridin-2-ylpropan-1-one;hydrochloride
• CAS: 100366-67-4
• 化学式: C₁₀H₁₄N₂O*ClH
• 分子量: 214.695
• InChiKey: XVIRIVQQCUAZCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.64
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  33.2
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-(Dimethylamino)-1-(2-pyridinyl)-1-propanone monohydrochloride 、 1-(2-acetyl-6-bromopyridyl)pyridinium iodide 在 ammonium acetate 作用下， 以 甲醇 为溶剂， 反应 3.0h， 以32%的产率得到6-溴-2,2':6',2''-三联吡啶
  参考文献：
  名称：

  Chemistry of heterocyclic compounds. Part 119. Synthesis of halogenated terpyridines and incorporation of the terpyridine nucleus into a polyetheral macrocycle

  摘要：

  DOI：

  10.1021/jo00356a019

文献信息

• NEWKOME, G. R.;HAGER, D. C.;KIEFER, G. E., J. ORG. CHEM., 1986, 51, N 6, 850-853
  作者：NEWKOME, G. R.、HAGER, D. C.、KIEFER, G. E.

  DOI：——

  日期：——
• PLATINUM (II) ISOQUINOLINE-PYRIDINE-BENZENE BASED COMPLEXES, PREPARING METHOD THEREOF, AND ORGANIC LIGHT-EMITTING DIODES MADE THEREFROM
  申请人：Versitech Limited

  公开号：EP2443132A1

  公开（公告）日：2012-04-25
• Platinum (II) Isoqulinoline-Pyridine-Benzene Based Complexes, Methods for Making Same, and Organic Light-Emitting Diodes Including Such Complexes
  申请人：CHE Chi Ming

  公开号：US20100314994A1

  公开（公告）日：2010-12-16

  This invention provides a class of organometallic complexes comprising a tridentate isoquinoline-pyridine-benzene based ligand, a mono-dentate ligand and a platinum (II) center which show high emission quantum efficiency and good thermal stability. This invention also discloses organometallic complexes in organic light-emitting diode (OLED) including them.
• [EN] PLATINUM (II) ISOQUINOLINE-PYRIDINE-BENZENE BASED COMPLEXES, PREPARING METHOD THEREOF, AND ORGANIC LIGHT-EMITTING DIODES MADE THEREFROM<br/>[FR] COMPLEXES DE PLATINE (II) À BASE D'ISOQUINOLÉINE-PYRIDINE-BENZÈNE, LEUR PROCÉDÉ DE PRÉPARATION, ET DIODES ÉLECTROLUMINESCENTES ORGANIQUES PRÉPARÉES À PARTIR DE CES COMPLEXES
  申请人：UNIV HONG KONG

  公开号：WO2010145190A1

  公开（公告）日：2010-12-23

  Organometallic complexes comprising a tridentate isoquinoline-pyridine-benzene based ligand, a monodentate ligand and a platinum (II) center show high emission quantum efficiency and good thermal stability. Organic light-emitting diode made from organometallic complexes is also described.
• Chemistry of heterocyclic compounds. Part 119. Synthesis of halogenated terpyridines and incorporation of the terpyridine nucleus into a polyetheral macrocycle
  作者：George R. Newkome、David C. Hager、Garry E. Kiefer

  DOI：10.1021/jo00356a019

  日期：1986.3