1,4-bis(4-hexyloxyphenyl)buta-1,3-diene | 141544-91-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1,4-bis(4-hexyloxyphenyl)buta-1,3-diene
• 英文别名: 1-hexoxy-4-[(1E,3E)-4-(4-hexoxyphenyl)buta-1,3-dienyl]benzene
• CAS: 141544-91-4
• 化学式: C₂₈H₃₈O₂
• 分子量: 406.609
• InChiKey: XNYDQEYPHLLVED-UTLPMFLDSA-N

物化性质

• 沸点：
  556.4±38.0 °C(Predicted)
• 密度：
  0.986±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.4
• 重原子数：
  30
• 可旋转键数：
  15
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,4-bis(4-hexyloxyphenyl)buta-1,3-diene 、 四氰基乙烯 以 二氯甲烷 为溶剂， 反应 2.0h， 以93%的产率得到3,6-bis(4-hexyloxyphenyl)-4,4,5,5-tetracyanocyclohex-1-ene
  参考文献：
  名称：

  Brettle, Roger; Dunmur, David A.; Hindley, Nigel J., Journal of the Chemical Society. Perkin transactions I, 1993, # 7, p. 775 - 782

  摘要：

  DOI：
• 作为产物：
  描述：

  (4-(hexyloxy)phenyl)methanol 在 盐酸 、 potassium tert-butylate 作用下， 以 四氢呋喃 、 Petroleum ether 为溶剂， 生成 1,4-bis(4-hexyloxyphenyl)buta-1,3-diene
  参考文献：
  名称：

  New liquid crystalline compounds based on 1,4-diarylbuta-1,3-dienes

  摘要：

  第一组完全表征的介晶（E,E）-1,4-二芳基丁-1,3-二烯已通过Wadsworth–Emmons反应合成，其一个芳环的对位被烷氧基取代，另一个芳环的对位则被氰基或卤素取代。这些化合物的高双折射率和低粘度的物理特性组合，使其在与已知液晶材料混合时，特别适合用于液晶显示设备中。

  DOI：

  10.1039/c39920000410

文献信息

• New liquid crystalline compounds based on 1,4-diarylbuta-1,3-dienes
  作者：Roger Brettle、David A. Dunmur、Nigel J. Hindley、Charles M. Marson

  DOI：10.1039/c39920000410

  日期：——

  The first group of fully characterised mesogenic (E,E)-1,4-diarylbuta-1,3-dienes, substituted in the para-position of one aryl ring by an alkoxy-group and in the para-position of the other aryl group by a cyano- or halogeno-group has been prepared by a Wadsworth–Emmons procedure; their physical properties of high birefringence and low viscosity in combination make them particularly suitable for use in liquid crystal display devices when mixed with known liquid crystalline materials.

  第一组完全表征的介晶（E,E）-1,4-二芳基丁-1,3-二烯已通过Wadsworth–Emmons反应合成，其一个芳环的对位被烷氧基取代，另一个芳环的对位则被氰基或卤素取代。这些化合物的高双折射率和低粘度的物理特性组合，使其在与已知液晶材料混合时，特别适合用于液晶显示设备中。
• Ink composition, inkjet recording method, printed material, process for producing lithographic printing plate, and lithographic printing plate
  申请人：Tsuchimura Tomotaka

  公开号：US20070242120A1

  公开（公告）日：2007-10-18

  An ink composition is provided that includes a compound represented by Formula (I) or (II). (In Formulae (I) and (II), R 1 and R 2 independently denote a monovalent substituent, R 3 to R 6 independently denote a hydrogen atom or a monovalent substituent, n denotes an integer of 0 to 5, and n′ denotes an integer of 0 to 5; n and n′ are not both 0, when n is 2 or greater a plurality of R 1 s may be identical to or different from each other, and when n′ is 2 or greater a plurality of R 2 s may be identical to or different from each other.) There are also provided an inkjet recording method employing the ink composition, and a process for producing a lithographic printing plate, the process including discharging the ink composition onto a hydrophilic support. A printed material and a lithographic printing plate thus obtained are also included in the present invention.
• CURABLE COMPOSITION, COLOR FILTER AND MANUFACTURING METHOD THEREOF
  申请人：MORI Hisahiro

  公开号：US20080076043A1

  公开（公告）日：2008-03-27

  According to the present invention, there is provided a curable composition, containing a compound (A) having at least one ethylenically unsaturated double bond, a photopolymerization initiator (B), a coloring agent (C), an alkali-soluble resin (D), and a compound (E) having in the molecule a partial structure of urethane, amide or urea.
• CURABLE COMPOSITION, COLOR FILTER USING THE SAME AND MANUFACTUIRNG METHOD THEREFOR, AND SOLID IMAGE PICKUP ELEMENT
  申请人：NAKASHIMA Taeko

  公开号：US20080171272A1

  公开（公告）日：2008-07-17

  The present invention provides a curable composition containing a resin, a compound containing an ethylenically unsaturated double bond and a photopolymerization initiator, wherein the resin is manufactured by polymerizing at least a monomer having a dipole moment of 2.0 or more as a copolymerization component, a color filter using the same and a manufacturing method therefor, and a solid image pickup element.
• Photosensitive Compositions, Curable Compositions, Novel Compounds, Photopolymerizable Compositions, Color Filters, and Planographic Printing Plate Precursors
  申请人：Tsuchimura Tomotaka

  公开号：US20090023085A1

  公开（公告）日：2009-01-22

  A photosensitive composition includes a compound represented by Formula (I) and a curable composition contains the compound of Formula (I) and a polymerizable compound. A compound is represented by a Formula (1) and a photocurable composition contains the compound of Formula (1) and a polymerizable compound. In Formula (I), R, R 1 and R 2 each independently represent a hydrogen atom or a monovalent substituent. In Formula (1), R and B each independently represent a monovalent substituent, A represents a divalent organic group, and Ar represents an aryl group.