8-aminoquinoline-5-sulphonic acid | 41606-26-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 8-aminoquinoline-5-sulphonic acid
• 英文别名: 8-amino-5-quinolinesulfonic acid；8-amino-quinoline-5-sulfonic acid；8-Amino-chinolin-5-sulfonsaeure；8-amino-5-quinoline Sulphonic Acid；8-Aminochinolin-5-sulfonsaeure；8-Aminoquinoline-5-sulfonic acid
• CAS: 41606-26-2
• 化学式: C₉H₈N₂O₃S
• 分子量: 224.24
• InChiKey: NLUUWZYRMSDVAE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  102
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  8-aminoquinoline-5-sulphonic acid 在 盐酸 、 乙醇 、 sodium nitrite 作用下， 生成 5-喹啉磺酸
  参考文献：
  名称：

  Cybulski et al., Roczniki Chemii, 1934, vol. 14, p. 1172,1180

  摘要：

  DOI：
• 作为产物：
  描述：

  8-amino-quinoline-5-sulfonic acid amide 在 alkaline solution 作用下， 生成 8-aminoquinoline-5-sulphonic acid
  参考文献：
  名称：

  Migliardi; Tappi, Ricerca Scientifica, 1941, vol. 12, p. 1061,1064

  摘要：

  DOI：

文献信息

• Metallized azo dyes and inks for ink-jet printing containing same
  申请人：Avecia Limited

  公开号：US06712890B2

  公开（公告）日：2004-03-30

  A water soluble compound of Formula (1) or a salt thereof: wherein: Y is an electron withdrawing group; Y1 is H, alkyl or aryl, OR or NR2 in which each R independently is H, optionally substituted alkyl or optionally substituted aryl; or Y and Y1 together form a 5- or 6- membered ring; X1 is a group or atom with co-ordinates with M; M is hexa co-ordinate metal; G is a group of Formula (2), (3) or (4); and L1, L2 and L3, each independently represent ligands required to complete hexa-coordinate geometry around metal M; wherein: S is a water solubilizing group; Ar is a benzene or naphthalene group in which X is located ortho to the azo group; X is a group or atom which co-ordinates with M; Z provides atoms or groups which complete an optionally substituted 5- or 6-membered aromatic heterocyclic ring; Ring A is an optionally substituted aromatic ring; Ring B is an optionally substituted 5- or 6-membered aromatic heterocyclic ring; n is 0, 1, 2 or 3; and the * signify the points of attachment of the groups of Formulae (2), (3) and (4) to the N and M atoms in the compound of Formula (1). The compounds are used in compositions for ink jet printing.

  化合物公式（1）的水溶性化合物或其盐： 其中： Y是电子提取基； Y1是H，烷基或芳基，OR或NR2，其中每个R独立地是H，可选择性取代的烷基或可选择性取代的芳基；或者Y和Y1一起形成5-或6-成员环； X1是具有与M坐标的基团或原子； M是六配位金属； G是公式（2），（3）或（4）的基团； L1，L2和L3各自独立地代表需要完成金属M周围的六配位几何的配体； 其中： S是水溶化基团； Ar是苯或萘基团，其中X位于偶氮基的邻位； X是具有与M坐标的基团或原子； Z提供原子或基团，以完成可选择性取代的5-或6-成员芳香杂环环； 环A是可选择性取代的芳香环； 环B是可选择性取代的5-或6-成员芳香杂环环； n为0、1、2或3； *表示公式（2）、（3）和（4）的基团连接到化合物公式（1）中的N和M原子的连接点。 这些化合物用于喷墨打印的组合物中。
• Photographic products and processes employing nondiffusible yellow azo
  申请人：Eastman Kodak Company

  公开号：US04407931A1

  公开（公告）日：1983-10-04

  Photographic elements, diffusion transfer assemblages, coordination complexes and processes are described which employ a novel nondiffusible compound having a releasable yellow dye moiety or precursor thereof, the compound having the formula: ##STR1## wherein: (a) X represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic fused ring; (b) Z represents alkyl, substituted alkyl, aryl or substituted aryl; (c) R represents CN or J--L; (d) J represents a bivalent ##STR2## group; (e) L represents alkyl, substituted alkyl, aryl, substituted aryl, or can be taken together with Z to complete a carbonyl-containing 5- or 6-membered heterocyclic or carbocyclic ring; (f) Z.sup.1 represents the same groups as Z; (g) each CAR independently represents a ballasted carrier moiety capable of releasing the diffusible yellow dye moiety or precursor thereof as a function of development of a silver halide emulsion layer under alkaline conditions; (h) each n is 0 or 1, with the proviso that at least one n is 1; (i) Lig is a monoanionic tridentate ligand; and (j) Me is a polyvalent, hexacoordinate metal ion.

  本文描述了一种使用新型非扩散化合物的摄影元素、扩散转移组合物、配位化合物和过程，该化合物具有可释放黄色染料基团或其前体的结构式：##STR1## 其中：(a) X代表必要的原子，以完成一个5-或6-成员的芳香杂环融合环；(b) Z代表烷基、取代烷基、芳基或取代芳基；(c) R代表CN或J-L；(d) J代表二价的##STR2##基团；(e) L代表烷基、取代烷基、芳基、取代芳基，或可以与Z一起完成含羰基的5-或6-成员杂环或碳环；(f) Z.sup.1代表与Z相同的基团；(g) 每个CAR独立地表示一个重负荷载体基团，能够在碱性条件下随着银卤化物乳剂层的显影而释放扩散性黄色染料基团或其前体；(h) 每个n为0或1，但至少有一个n为1；(i) Lig是一个单阴离子三齿配体；(j) Me是一个多价、六配位的金属离子。
• Photographic products and processes employing novel nondiffusible yellow
  申请人：Eastman Kodak Company

  公开号：US04418131A1

  公开（公告）日：1983-11-29

  Photographic elements, diffusion transfer assemblages, coordination complexes and processes are described which employ a novel nondiffusible compound having a releasable yellow dye moiety or precursor thereof, the compound having the formula: ##STR1## wherein: (a) X represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic fused ring; (b) Z represents alkyl, substituted alkyl, aryl or substituted aryl; (c) R represents CN or J-L; (d) J represents a bivalent ##STR2## (e) L represents alkyl, substituted alkyl, aryl, substituted aryl, or can be taken together with Z to complete a carbonyl-containing 5- or 6-membered heterocyclic or carbocyclic ring; (f) Z.sup.1 represents the same groups as Z; (g) each CAR independently represents a ballasted carrier moiety capable of releasing the diffusible yellow dye moiety or precursor thereof as a function of development of a silver halide emulsion layer under alkaline conditions; (h) each n is 0 or 1, with the proviso that at least one n is 1; (i) Lig is a monoanionic tridentate ligand; and (j) Me is a polyvalent, hexacoordinate metal ion.

  本文描述了使用一种新型非扩散化合物的摄影元素、扩散转移组合物、配位复合物和过程，该化合物具有可释放的黄色染料基团或其前体，该化合物的化学式为：##STR1## 其中：（a）X代表必要的原子，以完成5-或6-成员的芳香杂环融合环；（b）Z代表烷基，取代烷基，芳基或取代芳基；（c）R代表CN或J-L；（d）J代表双价的##STR2##（e）L代表烷基，取代烷基，芳基，取代芳基，或可以与Z一起完成含羰基的5-或6-成员杂环或碳环；（f）Z.sup.1代表与Z相同的基团；（g）每个CAR独立地表示一个负载平衡载体基团，能够根据碱性条件下银卤化物乳剂层的显影功能释放可扩散的黄色染料基团或其前体；（h）每个n为0或1，但至少有一个n为1；（i）Lig是一种单阴离子三齿配体；（j）Me是一种多价、六配位的金属离子。
• Nondiffusible yellow metallized azo dye-releasing compounds
  申请人：Eastman Kodak Company

  公开号：US04481141A1

  公开（公告）日：1984-11-06

  Photographic elements, diffusion transfer assemblages, coordination complexes and processes are described which employ a novel nondiffusible compound having a releasable yellow dye moiety or precursor thereof, the compound having the formula: ##STR1## wherein: (a) X represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic fused ring; (b) Z represents alkyl, substituted alkyl, aryl or substituted aryl; (c) R represents CN or J-L; (d) J represents a bivalent ##STR2## (e) L represents alkyl, substituted alkyl, aryl, substituted aryl, or can be taken together with Z to complete a carbonyl-containing 5- or 6-membered heterocyclic or carbocyclic ring; (f) Z.sup.1 represents the same groups as Z; (g) each CAR independently represents a ballasted carrier moiety capable of releasing the diffusible yellow dye moiety or precursor thereof as a function of development of a silver halide emulsion layer under alkaline conditions; (h) each n is 0 or 1, with the proviso that at least one n is 1; (i) Lig is a monoanionic tridentate ligand; and (j) Me is a polyvalent, hexacoordinate metal ion.

  本发明涉及一种新型的不可扩散化合物，其具有可释放的黄色染料基团或其前体，其中描述了摄影元素、扩散转移组合物、配位化合物和过程，该化合物的化学式为：##STR1## 其中：(a) X代表必要的原子以完成一个5-或6-成员芳香杂环融合环；(b) Z代表烷基、取代烷基、芳基或取代芳基；(c) R代表CN或J-L；(d) J代表二价的##STR2## (e) L代表烷基、取代烷基、芳基、取代芳基，或可以与Z一起完成含有羰基的5-或6-成员杂环或碳环；(f) Z.sup.1代表与Z相同的基团；(g) 每个CAR独立地表示一个平衡载体基团，能够在碱性条件下随着银卤化物乳剂层的显影释放可扩散的黄色染料基团或其前体；(h) 每个n为0或1，但至少有一个n为1；(i) Lig是一种单阴离子三齿配体；(j) Me是一种多价的、六配位的金属离子。
• Compositions
  申请人：Avecia Limited

  公开号：US20020130937A1

  公开（公告）日：2002-09-19

  A water soluble compound of Formula (1) or a salt thereof: wherein: Y is an electron withdrawing group; Y 1 is H, alkyl or aryl, OR or NR 2 in which each R independently is H, optionally substituted alkyl or optionally substituted aryl; or Y and Y 1 together form a 5- or 6- membered ring; X 1 is a group or atom with co-ordinates with M; M is hexa co-ordinate metal; G is a group of Formula (2), (3) or (4); and L 1 , L 2 and L 3 , each independently represent ligands required to complete hexa-coordinate geometry around metal M; wherein: S is a water solubilizing group; Ar is a benzene or naphthalene group in which X is located ortho to the azo group; X is a group or atom which co-ordinates with M; Z provides atoms or groups which complete an optionally substituted 5- or 6-membered aromatic heterocyclic ring; Ring A is an optionally substituted aromatic ring; Ring B is an optionally substituted 5- or 6-membered aromatic heterocyclic ring; n is 0, 1, 2 or 3; and the * signify the points of attachment of the groups of Formulae (2), (3) and (4) to the N and M atoms in the compound of Formula (1). The compounds are used in compositions for ink jet printing.

  一种水溶性的化合物Formula（1）或其盐：其中：Y是一个电子提取基团；Y1是H，烷基或芳基，OR或NR2其中每个R独立地是H，可选择性取代的烷基或可选择性取代的芳基；或者Y和Y1一起形成一个5或6成员环；X1是一个带有M坐标的基团或原子；M是六配位金属；G是Formula（2），（3）或（4）的基团；L1，L2和L3分别表示需要完成金属M周围六配位几何的配体；其中：S是一个水溶解基团；Ar是苯或萘基团，其中X位于偶氮基团的正交位置；X是一个带有M坐标的基团或原子；Z提供原子或基团，以完成可选择性取代的5或6成员芳香杂环环；环A是可选择性取代的芳香环；环B是可选择性取代的5或6成员芳香杂环环；n为0，1，2或3；星号表示Formula（2），（3）和（4）的基团连接到化合物Formula（1）中的N和M原子的连接点。这些化合物用于喷墨打印的组成物中。