di-tert-butylindium chloride | 92089-77-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 金属烷基卤化物
• 英文名称: di-tert-butylindium chloride
• 英文别名: Di-tert-butylindiumchlorid；(tert-butyl)2InCl
• CAS: 92089-77-5
• 化学式: C₈H₁₈ClIn
• 分子量: 264.504
• InChiKey: OSIBXWXZFRPKAD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.82
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  di-tert-butylindium chloride 、 叔丁基肼 以 甲苯 为溶剂， 以45%的产率得到(tert-butylhydrazine)di(tert-butyl)indium chloride
  参考文献：
  名称：

  Hydrazin-Addukte mit Dialkylindiumchloriden—Überraschende strukturelle Vielfalt bei einfachen Verbindungen

  摘要：

  二烷基氯化铟试剂 mit Hydrazinderivaten zu unterschiedlichen Addukten, die eine bemerkenswerte strukturelle Vielfalt zeigen。Die aquimolare Umsetzung von Me2InCl mit Phenylhydrazin ergibt das erwartete Monoaddukt [Me2InCl·NH2NHC6H5] (1), in dem der Ligand uber sein NH2-Stickstoffatom an das zentrale ergibt das erwartete Monoaddukt . Bei der entsprechende Reaktion mit tert-Butylhydrazin entsteht dagegen unter

  DOI：

  10.1002/zaac.200300197

文献信息

• Cyclopentadiene Elimination Reactions for the Preparation of Organoindium(III) Derivatives. Crystal and Molecular Structures of Me₂In(acac), (Me₃CCH₂)₂In(acac), (Me)(Me₃CCH₂)In(acac), and [Me₂InNH(t-Bu)]₂
  作者：O. T. Beachley,、David J. MacRae、Melvyn Rowen Churchill、Andrey Yu. Kovalevsky、Eric S. Robirds

  DOI：10.1021/om0304154

  日期：2003.9.1

  The compounds R2InO(t-Bu), R2In(acac), R2InSSiPh3, and R2InPPh2 (R = Me, CH2CMe3) and Me2InNH(t-Bu) have been prepared in nearly quantitative yields by the cyclopentadiene elimination reaction between R2In(C5H5) and the appropriate alcohol, thiol, phosphine or amine. All reactions except those of H2N(t-Bu) occur readily at room temperature. Even though solutions of R2In(C5H5) exist as equilibrium mixtures of R2In(C5H5), RIn(C5H5)(2), In(C5H5)(3), and InR3, neither methane nor neopentane was observed as a product from the above reaction mixtures. A ligand redistribution reaction between Me2In(C5H5) and (Me3CCH2)(2)In(C5H5) was used to prepare (Me)(Me)(Me3CCH2)In(C5H5) that, in turn, was reacted with H(acac) to form (Me)(Me3CCH2)In(acac), an indium compound with three different substituents. The compounds Me2In(acac), (Me3CCH2)(2)In(acac), and (Me)(Me3CCH2)In(acac) exist as centrosymmetric dimers in the solid state, but in benzene solution Me2In(acac) is a monomer-dimer equilibrium mixture, whereas (Me3CCH2)(2)In(acac) is a monomer. The thiolate Me2InSSiPh3 is an equilibrium mixture of dimers and trimers in benzene solution, but (Me3CCH2)(2)InSSiPh3 is a dimer. The phosphide Me2InPPh2 is an equilibrium mixture of monomers and dimers when dissolved in benzene. The tert-butylamide Me2InNH(t-Bu), when dissolved in benzene, is a mixture of monomers and dimers with both cis and trans configurations, but only a dimer with the trans configuration exists in the solid state.
• Schumann, Herbert; Mohtachemi, Reza, Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1984, vol. 39, # 6, p. 798 - 800
  作者：Schumann, Herbert、Mohtachemi, Reza

  DOI：——

  日期：——
• Stoll, Sarah L.; Bott, Simon G.; Barron, Andrew R., Journal of the Chemical Society, Dalton Transactions, 1997, # 8, p. 1315 - 1321
  作者：Stoll, Sarah L.、Bott, Simon G.、Barron, Andrew R.

  DOI：——

  日期：——
• Petrie, MA.; Ruhlandt-Senge, K.; Hope, H., Bulletin de la Societe Chimique de France, 1993, vol. 130, p. 851 - 855
  作者：Petrie, MA.、Ruhlandt-Senge, K.、Hope, H.、Power, PP.

  DOI：——

  日期：——
• SCHUMANN, H.;MOHTACHEMI, R., Z. NATURFORSCH., 1984, 39, N 6, 798-800
  作者：SCHUMANN, H.、MOHTACHEMI, R.

  DOI：——

  日期：——