cyclohexylmercury bromide | 10192-55-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 金属烷基卤化物
• 英文名称: cyclohexylmercury bromide
• CAS: 10192-55-9
• 化学式: C₆H₁₁BrHg
• 分子量: 363.647
• InChiKey: RYUAWGQSCJCZQT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.13
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  cyclohexylmercury bromide 生成 Dicyclohexylquecksilber
  参考文献：
  名称：

  SAYRE L. M.; JENSEN F. R., J. ORG. CHEM., 1979, 44, NO 2, 228 231

  摘要：

  DOI：

文献信息

• Acyclic Stereocontrol of Free Radical Reactions Involving Alkyl 2-(1-Hydroxyalkyl)propenoates
  作者：FW Eastwood、RD Mifsud、P Perlmutter

  DOI：10.1071/ch9942187

  日期：——

  The addition of cyclohexyl and t-butyl free radicals to silylated derivatives of alkyl 2-(1-hydroxyalkyl) propenoates was found to be stereoselective . In the case of the cyclohexyl radical the stereoselectivity was dependent upon the conditions used to generate the free radical and to quench the intermediate. Stereoselectivity in additions of the t-butyl radical was found to be temperature-dependent. In all cases stereoselectivity increased as the steric bulk of the group attached to the carbinol oxygen increased. A simple model which accounts for the stereoselectivity is proposed.

  研究发现，环己基和叔丁基自由基与 2-（1-羟基烷基）丙烯酸烷基硅烷化衍生物的加成具有立体选择性。环己基自由基的立体选择性取决于生成自由基和淬灭中间体的条件。研究发现，t-丁基自由基加成的立体选择性与温度有关。在所有情况下，立体选择性都会随着连接到羰基氧上的基团立体体积的增加而增加。提出了一个解释立体选择性的简单模型。
• Ryu, Ilhyong; Ryang, Membo; Rhee, Ilsong, Synthetic Communications, 1984, vol. 14, # 12, p. 1175 - 1180
  作者：Ryu, Ilhyong、Ryang, Membo、Rhee, Ilsong、Omura, Haruo、Murai, Shinji、Sonoda, Noboru

  DOI：——

  日期：——
• Oxidative demercuration revisited
  作者：Patricia Hayes、Bill D. Suthers、William Kitching

  DOI：10.1016/s0040-4039(00)01001-7

  日期：2000.8

  A procedure for oxidative demercuration utilising O-2-TEMPO-NaBH4-DMF (0 degrees) is shown to be convenient and efficient for a variety of organomercury(II)halide systems, including spiroacetal structures acquired by intramolecular hydroxy-mercuration, (C) 2000 Elsevier Science Ltd. All rights reserved.
• RYU, ILHYONG;RYANG, MEMBO;RHEE, ILSONG;OMURA, HARUO;MURAI, SHINJI;SONODA,+, SYNTH. COMMUN., 1984, 14, N 12, 1175-1179
  作者：RYU, ILHYONG、RYANG, MEMBO、RHEE, ILSONG、OMURA, HARUO、MURAI, SHINJI、SONODA,+

  DOI：——

  日期：——