2-Oxo-5-phenyl-3-vinyl-4,5-dihydrofuran | 142038-51-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: 2-Oxo-5-phenyl-3-vinyl-4,5-dihydrofuran
• 英文别名: 3-Ethenyl-5-phenyloxolan-2-one
• CAS: 142038-51-5
• 化学式: C₁₂H₁₂O₂
• 分子量: 188.226
• InChiKey: FIXVOZNYPUHZAQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  乙烯基乙酸 、 氧化苯乙烯 以70%的产率得到
  参考文献：
  名称：

  FUJITA, TSUTOMU;WATANABE, SHOJI;SUGA, KYOICHI;ISHIKAME, KEINOSUKE;SUGAHAR+, CHEM. AND IND., 1983, N 23, 897

  摘要：

  DOI：

文献信息

• Ring expansion of tert-butyl 1-vinylcyclopropane-1-carboxylates to .alpha.-ethylidenebutyrolactones
  作者：Huw M. L. Davies、Baihua Hu

  DOI：10.1021/jo00041a050

  日期：1992.7
• METHOD FOR PRODUCING CYCLIC UNSATURATED COMPOUND
  申请人：Yonehara Koji

  公开号：US20090299009A1

  公开（公告）日：2009-12-03

  The present invention provides a method for producing a cyclic unsaturated compound, which sufficiently suppresses generation of acyclic unsaturated compounds and permits excellent yield and reaction rate. Such a method for producing a cyclic unsaturated compound is a method for producing a cyclic unsaturated compound by reacting an α,β-unsaturated carboxylic acid with an unsaturated organic compound, wherein the method comprises a step of reacting the α,β-unsaturated carboxylic acid with the unsaturated organic compound in the presence of a catalyst.
• US8093409B2
  申请人：——

  公开号：US8093409B2

  公开（公告）日：2012-01-10
• [EN] METHOD FOR PRODUCING CYCLIC UNSATURATED COMPOUND<br/>[FR] PROCÉDÉ DE PRODUCTION D'UN COMPOSÉ INSATURÉ CYCLIQUE
  申请人：NIPPON CATALYTIC CHEM IND

  公开号：WO2008023823A1

  公开（公告）日：2008-02-28

  [EN] The present invention provides a method for producing a cyclic unsaturated compound, which sufficiently suppresses generation of acyclic unsaturated compounds and permits excellent yield and reaction rate. Such a method for producing a cyclic unsaturated compound is a method for producing a cyclic unsaturated compound by reacting an a, ß-unsaturated carboxylic acid with an unsaturated organic compound, wherein the method comprises a step of reacting the a, ß-unsaturated carboxylic acid with the unsaturated organic compound in the presence of a catalyst.
  [FR] La présente invention concerne un procédé de production d'un composé insaturé cyclique, permettant de supprimer efficacement la génération de composés insaturés acycliques et d'obtenir un rendement et une vitesse de réaction élevés. Ce procédé vise à produire un composé insaturé cyclique par réaction d'un acide carboxylique a,ß-insaturé avec un composé organique insaturé, ledit procédé consistant à faire réagir l'acide carboxylique a,ß-insaturé avec le composé organique insaturé en présence d'un catalyseur.
• FUJITA, TSUTOMU;WATANABE, SHOJI;SUGA, KYOICHI;ISHIKAME, KEINOSUKE;SUGAHAR+, CHEM. AND IND., 1983, N 23, 897
  作者：FUJITA, TSUTOMU、WATANABE, SHOJI、SUGA, KYOICHI、ISHIKAME, KEINOSUKE、SUGAHAR+

  DOI：——

  日期：——