1,13-diphenoxytridecane-6,8-dione | 1246655-17-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1,13-diphenoxytridecane-6,8-dione
• 英文别名: 1,13-Diphenoxytridecane-6,8-dione
• CAS: 1246655-17-3
• 化学式: C₂₅H₃₂O₄
• 分子量: 396.527
• InChiKey: FPBCDFSNZQTQDE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  29
• 可旋转键数：
  16
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,13-diphenoxytridecane-6,8-dione 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 以98%的产率得到1,13-dibromotridecane-6,8-dione
  参考文献：
  名称：

  Twofold terminal post-functionalization of acetylacetone with hole- and electron-transporting fragments

  摘要：

  A modular synthetic methodology has been developed to prepare beta-diketones functionalized with hole- and electron-transporting fragments at their two termini. The optical and electrochemical properties of these new beta-diketones are also described in detail. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.06.090
• 作为产物：
  描述：

  4-苯氧基丁基溴 、 乙酰丙酮 在 sodium hydride 、 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 5.0h， 以28%的产率得到1,13-diphenoxytridecane-6,8-dione
  参考文献：
  名称：

  Twofold terminal post-functionalization of acetylacetone with hole- and electron-transporting fragments

  摘要：

  A modular synthetic methodology has been developed to prepare beta-diketones functionalized with hole- and electron-transporting fragments at their two termini. The optical and electrochemical properties of these new beta-diketones are also described in detail. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.06.090

文献信息

• Twofold terminal post-functionalization of acetylacetone with hole- and electron-transporting fragments
  作者：Lingcheng Chen、Junqiao Ding、Yanxiang Cheng、Lixiang Wang、Xiabin Jing、Fosong Wang

  DOI：10.1016/j.tetlet.2010.06.090

  日期：2010.9

  A modular synthetic methodology has been developed to prepare beta-diketones functionalized with hole- and electron-transporting fragments at their two termini. The optical and electrochemical properties of these new beta-diketones are also described in detail. (C) 2010 Elsevier Ltd. All rights reserved.