2-[2-[2-(1,1-Difluoro-2-prop-2-enoxyethoxy)-1,1,2,2-tetrafluoroethoxy]-1,1,2,2-tetrafluoroethoxy]-2,2-difluoroethanol | 1194789-73-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代醇
• 英文名称: 2-[2-[2-(1,1-Difluoro-2-prop-2-enoxyethoxy)-1,1,2,2-tetrafluoroethoxy]-1,1,2,2-tetrafluoroethoxy]-2,2-difluoroethanol
• 英文别名: 2-[2-[2-(1,1-difluoro-2-prop-2-enoxyethoxy)-1,1,2,2-tetrafluoroethoxy]-1,1,2,2-tetrafluoroethoxy]-2,2-difluoroethanol
• CAS: 1194789-73-5
• 化学式: C₁₁H₁₀F₁₂O₅
• 分子量: 450.178
• InChiKey: IIFJRKAXANNLTL-UHFFFAOYSA-N

物化性质

• 沸点：
  344.3±37.0 °C(Predicted)
• 密度：
  1.532±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  28
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  57.2
• 氢给体数：
  1
• 氢受体数：
  17

反应信息

• 作为反应物：
  描述：

  2,4,6,8-四甲基环四硅氧烷 、 2-[2-[2-(1,1-Difluoro-2-prop-2-enoxyethoxy)-1,1,2,2-tetrafluoroethoxy]-1,1,2,2-tetrafluoroethoxy]-2,2-difluoroethanol 在 铂(0)-1,3-二乙烯-1,1,3,3-四甲基二硅氧烷 作用下， 以 甲苯 为溶剂， 以62%的产率得到
  参考文献：
  名称：

  Fluorinated Polymers Derived from Tetrafunctional Cyclic Siloxanes Possessing Low Optical Loss and High Thermo-Optic Property

  摘要：

  We have prepared UV-curable fluorinated polymeric materials based on tetrafunctional cyclic siloxanes substituted with perfluoropolyether structure in order to have low optical loss, low birefringence, high thermo-optic coefficient, and good thermal stability. Perfluoropolyether structure with hydroxyl as one end and allyl as the other was prepared by reaction between fluorinated diols and allyl bromide. Then it was reacted with cyclic siloxane with platinum catalyst in a fairly high yield. The terminal hydroxyl was converted to acryl by reaction with acryloyl chloride. Transparent and stable films were obtained from the fluorinated monomers by UV irradiation. The photo-cured film was found to be thermally durable up to 300 degrees C, where 2% weight loss occurred. The polymer films showed -1.59 x 10 (4) /K of thermo-optic coefficient, 0.0002 of birefringence, and 0.121 dB/cm of optical loss, which were measured by prism coupler at 1550 nm of laser source.

  DOI：

  10.1080/15421400903584234
• 作为产物：
  描述：

  1H,1H,11H,11H-全氟-3,6,9-三噁十一烷-1,11-二醇 、 3-溴丙烯 在 sodium hydroxide 作用下， 以 四氢呋喃 为溶剂， 反应 15.0h， 以47%的产率得到2-[2-[2-(1,1-Difluoro-2-prop-2-enoxyethoxy)-1,1,2,2-tetrafluoroethoxy]-1,1,2,2-tetrafluoroethoxy]-2,2-difluoroethanol
  参考文献：
  名称：

  Fluorinated Polymers Derived from Tetrafunctional Cyclic Siloxanes Possessing Low Optical Loss and High Thermo-Optic Property

  摘要：

  We have prepared UV-curable fluorinated polymeric materials based on tetrafunctional cyclic siloxanes substituted with perfluoropolyether structure in order to have low optical loss, low birefringence, high thermo-optic coefficient, and good thermal stability. Perfluoropolyether structure with hydroxyl as one end and allyl as the other was prepared by reaction between fluorinated diols and allyl bromide. Then it was reacted with cyclic siloxane with platinum catalyst in a fairly high yield. The terminal hydroxyl was converted to acryl by reaction with acryloyl chloride. Transparent and stable films were obtained from the fluorinated monomers by UV irradiation. The photo-cured film was found to be thermally durable up to 300 degrees C, where 2% weight loss occurred. The polymer films showed -1.59 x 10 (4) /K of thermo-optic coefficient, 0.0002 of birefringence, and 0.121 dB/cm of optical loss, which were measured by prism coupler at 1550 nm of laser source.

  DOI：

  10.1080/15421400903584234

文献信息

• Fluorinated Polymers Derived from Tetrafunctional Cyclic Siloxanes Possessing Low Optical Loss and High Thermo-Optic Property
  作者：Hyun Kyung Ju、Yongku Kang、Changjin Lee、Dong Wook Kim

  DOI：10.1080/15421400903584234

  日期：2010.4.13

  We have prepared UV-curable fluorinated polymeric materials based on tetrafunctional cyclic siloxanes substituted with perfluoropolyether structure in order to have low optical loss, low birefringence, high thermo-optic coefficient, and good thermal stability. Perfluoropolyether structure with hydroxyl as one end and allyl as the other was prepared by reaction between fluorinated diols and allyl bromide. Then it was reacted with cyclic siloxane with platinum catalyst in a fairly high yield. The terminal hydroxyl was converted to acryl by reaction with acryloyl chloride. Transparent and stable films were obtained from the fluorinated monomers by UV irradiation. The photo-cured film was found to be thermally durable up to 300 degrees C, where 2% weight loss occurred. The polymer films showed -1.59 x 10 (4) /K of thermo-optic coefficient, 0.0002 of birefringence, and 0.121 dB/cm of optical loss, which were measured by prism coupler at 1550 nm of laser source.