1-(cyclohex-1-en-1-yl)octan-1-one | 30857-57-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(cyclohex-1-en-1-yl)octan-1-one
• 英文别名: Cyclohexen-(1)-yl-heptyl-keton；1-(cyclohex-1-enyl)octan-1-one；1-(cyclohexen-1-yl)octan-1-one
• CAS: 30857-57-9
• 化学式: C₁₄H₂₄O
• 分子量: 208.344
• InChiKey: UMUOPKZOJXZCHI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(cyclohex-1-en-1-yl)octan-1-one 在 水 、 氢溴酸 、 氢氧化钾 作用下， 以 乙醚 为溶剂， 以78%的产率得到1-(7-oxabicyclo[4.1.0]hept-1-yl)octan-1-one
  参考文献：
  名称：

  Induced halogenation of alkyl cyclohexenyl ketones involving metal halides, hydrohalogenic acids, and hydrogen peroxide

  摘要：

  The induced halogenation and hydroxyhalogenation of alkyl cyclohexenyl ketones in a system [MHlg + HHlg or HHlg]-H(2)O(2) or in NaOCl was performed and optimum reaction conditions were established. Under mild conditions the electrophilic addition of the halogen or the acid occurred at the multiple bond of the ring with the formation of the corresponding dihalo or hydroxyhalo derivatives of cycloaliphatic ketones. From the compounds obtained epoxy- and dioxyketones of aliphatic series were prepared. Chloro(bromo)hydrins of ketones from the alkylcyclohexane series and oxiranes based thereon are reactive compounds and can be employed as synthons in the organic synthesis.

  DOI：

  10.1134/s107042800902002x
• 作为产物：
  描述：

  辛酰氯 、 环己烯 以 四氯化碳 为溶剂， 以33%的产率得到1-(cyclohex-1-en-1-yl)octan-1-one
  参考文献：
  名称：

  Induced halogenation of alkyl cyclohexenyl ketones involving metal halides, hydrohalogenic acids, and hydrogen peroxide

  摘要：

  The induced halogenation and hydroxyhalogenation of alkyl cyclohexenyl ketones in a system [MHlg + HHlg or HHlg]-H(2)O(2) or in NaOCl was performed and optimum reaction conditions were established. Under mild conditions the electrophilic addition of the halogen or the acid occurred at the multiple bond of the ring with the formation of the corresponding dihalo or hydroxyhalo derivatives of cycloaliphatic ketones. From the compounds obtained epoxy- and dioxyketones of aliphatic series were prepared. Chloro(bromo)hydrins of ketones from the alkylcyclohexane series and oxiranes based thereon are reactive compounds and can be employed as synthons in the organic synthesis.

  DOI：

  10.1134/s107042800902002x

文献信息

• .ALPHA.,.BETA.-Epoxy sulfoxides as useful intermediates in organic synthesis. 26. Ring-opening fluorination of .ALPHA.,.BETA.-epoxy sulfoxides: A novel synthesis of .ALPHA.-fluoroketones.
  作者：Tsuyoshi SATOH、Jun-ichi SHISHIKURA、Koji YAMAKAWA

  DOI：10.1248/cpb.38.1798

  日期：——

  Treatment of α, β-epoxy sulfoxides (sulfinyl oxilanes) with KHF2 and BF3·OEt2 in CHCl3 gave α-fluoroketones in moderate to good yields.

  用KHF2和BF3·OEt2在CHCl3中处理α, β-环氧亚磺酸酯（亚磺酰环氧烷）可以得到中等至良好的α-氟酮产率。
• Ink composition, inkjet recording method, printed material, process for producing lithographic plate, and lithographic printing plate
  申请人：FUJIFILM Corporation

  公开号：EP1762599A1

  公开（公告）日：2007-03-14

  An ink composition is provided that includes a cationically polymerizable compound (a), a compound (b) that generates an acid when exposed to radiation, a colorant (c), and a salt of a weak acid having a pKa of 4 to 8 (d). There is also provided an inkjet recording method that includes a step of discharging the ink composition onto a recording medium, and a step of irradiating the discharged ink composition with radiation so as to cure the ink composition.

  提供了一种墨水组合物，其中包括阳离子可聚合化合物 (a)、暴露于辐射时产生酸的化合物 (b)、着色剂 (c) 和 pKa 为 4 至 8 的弱酸盐 (d)。还提供了一种喷墨记录方法，该方法包括将墨水组合物排放到记录介质上的步骤，以及用辐射照射排放的墨水组合物以固化墨水组合物的步骤。
• Acylation of Alkenes with the Aid of AlCl₃ and 2,6-Dibromopyridine
  作者：Shinya Tanaka、Tsukasa Kunisawa、Yuji Yoshii、Tetsutaro Hattori

  DOI：10.1021/acs.orglett.9b02688

  日期：2019.11.1

  Friedel-Crafts-type acylation of alkenes with acyl chlorides has been successfully conducted with a wide substrate scope by the combined use of AlCl3 and 2,6-dibromopyridine. Trisubstituted alkenes afford allylketones or vinylketones depending on the presence or absence of hydrogen atom(s) at the beta-position to the acylation site, while monosubstituted alkenes exclusively afford vinylketones.
• Ink composition and inkjet recording method
  申请人：Fujifilm Corporation

  公开号：EP2169018B1

  公开（公告）日：2012-01-18
• Induced halogenation of alkyl cyclohexenyl ketones involving metal halides, hydrohalogenic acids, and hydrogen peroxide
  作者：O. A. Sadygov、Kh. M. Alimardanov

  DOI：10.1134/s107042800902002x

  日期：2009.2

  The induced halogenation and hydroxyhalogenation of alkyl cyclohexenyl ketones in a system [MHlg + HHlg or HHlg]-H(2)O(2) or in NaOCl was performed and optimum reaction conditions were established. Under mild conditions the electrophilic addition of the halogen or the acid occurred at the multiple bond of the ring with the formation of the corresponding dihalo or hydroxyhalo derivatives of cycloaliphatic ketones. From the compounds obtained epoxy- and dioxyketones of aliphatic series were prepared. Chloro(bromo)hydrins of ketones from the alkylcyclohexane series and oxiranes based thereon are reactive compounds and can be employed as synthons in the organic synthesis.