10-ethoxydec-1-ene | 100385-60-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 10-ethoxydec-1-ene
• CAS: 100385-60-2
• 化学式: C₁₂H₂₄O
• 分子量: 184.322
• InChiKey: ZXZNTZOREWWWOW-UHFFFAOYSA-N

物化性质

• 沸点：
  44-46 °C(Press: 0.2 Torr)
• 密度：
  0.808±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  13
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  10-ethoxydec-1-ene 在 溴 作用下， 以 四氯化碳 为溶剂， 生成 1,2-二溴-10-乙氧基癸烷
  参考文献：
  名称：

  Taylor,E.P., Journal of the Chemical Society, 1960, p. 4564 - 4565

  摘要：

  DOI：
• 作为产物：
  描述：

  乙醇 、 1,10-二碘癸烷 在 氢氧化钾 、 potassium carbonate 作用下， 生成 10-ethoxydec-1-ene
  参考文献：
  名称：

  Taylor,E.P., Journal of the Chemical Society, 1960, p. 4564 - 4565

  摘要：

  DOI：

文献信息

• [EN] NOVEL ORGANOLEPTIC COMPOUNDS AND THEIR USE IN FLAVOR AND FRAGRANCE COMPOSITIONS<br/>[FR] NOUVEAUX COMPOSÉS ORGANOLEPTIQUES ET LEUR UTILISATION DANS DES COMPOSITIONS D'ARÔME ET DE FRAGRANCE
  申请人：INT FLAVORS & FRAGRANCES INC

  公开号：WO2015157153A1

  公开（公告）日：2015-10-15

  The present invention is directed to novel organoleptic compounds, a process of augmenting, enhancing or imparting taste to a material selected from the group consisting of a foodstuff, a chewing gum, a dental product, an oral hygiene product and a medicinal product comprising the step of incorporating an olfactory acceptable amount of such novel organoleptic compounds, and a process of improving, enhancing or modifying a fragrance composition through the addition of an olfactory acceptable amount of such novel organoleptic compounds.

  本发明涉及新型感官化合物，一种增强、提升或赋予口味的方法，选择的材料包括食品、口香糖、牙科产品、口腔卫生产品和药品，包括将这种新型感官化合物的嗅觉可接受量并入其中的步骤，以及通过添加这种新型感官化合物的嗅觉可接受量来改进、增强或修改香水组合的方法。
• [EN] NOVEL OCTAHYDROINDENYL PROPANAL COMPOUNDS<br/>[FR] NOUVEAUX COMPOSÉS D'OCTAHYDRO-INDÈNYLE PROPANAL
  申请人：INT FLAVORS & FRAGRANCES INC

  公开号：WO2017066214A1

  公开（公告）日：2017-04-20

  The present invention pertains to novel octahydro-indene compounds and their unexpected advantageous use thereof in enhancing, improving or modifying the fragrance of perfumes, colognes, toilet waters, fabric care products, personal products, and the like.

  本发明涉及新颖的八氢基环己烯化合物及其在提升、改进或修改香水、古龙水、洗手水、织物护理产品、个人护理产品等中的意外有利用途。
• Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition contaning the copolymer, and uses thereof
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP1186619A2

  公开（公告）日：2002-03-13

  The present invention is intended to provide a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an α-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the α-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.

  本发明旨在提供一种对金属或极性树脂具有极佳粘附性和相容性的含极性基团的烯烃共聚物、制备该共聚物的工艺、含有该共聚物的热塑性树脂组合物及其用途。含极性基团的烯烃共聚物包括一个由 2 至 20 个碳原子的 α-烯烃衍生的组成单元和一个由直链、支链或环状含极性基团单体衍生的组成单元，直链、支链或环状含极性基团单体的末端具有极性基团，如羟基或环氧基，和/或一个由大单体衍生的组成单元，大单体的末端具有通过阴离子聚合、开环聚合或缩聚反应获得的聚合物段。含极性基团的烯烃共聚物可通过在茂金属催化剂存在下使α-烯烃与含极性基团的单体和/或大单体聚合来制备。含极性基团的烯烃共聚物和含有该共聚物的热塑性树脂组合物可用于薄膜、板材、改性剂、建筑/土木工程材料、汽车外饰、电气/电子零件、涂层基料、相容剂等。
• Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition containing the copolymer, and uses thereof
  申请人：——

  公开号：US20020156207A1

  公开（公告）日：2002-10-24

  The present invention is intended to provide a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an &agr;-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the &agr;-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.

  本发明旨在提供一种对金属或极性树脂具有极佳粘附性能和极佳相容性的含极性基团的烯烃共聚物、制备该共聚物的工艺、含有该共聚物的热塑性树脂组合物及其用途。含极性基团的烯烃共聚物包括一个由 2 至 20 个碳原子的&agr;-烯烃衍生的组成单元，以及一个由直链、支链或环状含极性基团单体衍生的组成单元，该单体末端具有极性基团，如羟基或环氧基，和/或一个由大单体衍生的组成单元，该大单体末端具有通过阴离子聚合、开环聚合或缩聚反应获得的聚合物段。含极性基团的烯烃共聚物可通过在茂金属催化剂存在下，将&agr;-烯烃与含极性基团的单体和/或大单体进行聚合来制备。含极性基团的烯烃共聚物和含有该共聚物的热塑性树脂组合物可用于薄膜、板材、改性剂、建筑/土木工程材料、汽车外饰、电气/电子零件、涂层基料、相容剂等。
• 10.1021/acs.orglett.4c02282
  作者：Li, Fei、Luo, Yicong、Ren, Jinbao、Yuan, Qianjia、Yan, Deyue、Zhang, Wanbin

  DOI：10.1021/acs.orglett.4c02282

  日期：——

  There are only a few examples being reported for the simultaneous control of central chirality and axial chirality because it is more challenging. Herein, we report an iridium-catalyzed asymmetric hydroarylation of unactivated alkenes with heterobiaryls to simultaneously construct axial and central chirality. The reaction showed a broad substrate scope and delivered the products with satisfactory results

  同时控制中心手性和轴向手性的例子很少，因为它更具挑战性。在此，我们报道了未活化烯烃与杂联芳基的铱催化不对称氢芳基化，以同时构建轴向和中心手性。该反应显示了广泛的底物范围，并得到了令人满意的结果。对照实验的结果表明，FerroLANE配体促进反应沿着特定的改良Chalk-Harrod机制进行。