2-甲基丙烯酸与2-甲基丙烯酸丁酯的共聚物 | 26284-14-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2-甲基丙烯酸与2-甲基丙烯酸丁酯的共聚物
• 英文名称: Butyl 2-methylprop-2-enoate;2-methylprop-2-enoic acid
• CAS: 26284-14-0
• 化学式: C12H20O4
• 分子量: 228.28
• InChiKey: VOOQRJIZEJHBGL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.55
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  甲基丙烯酸 、 甲基丙烯酸丁酯 、 异丙醇 、 、 偶氮二异丁腈 、 在 氮 作用下， 以 丙酮 为溶剂， 反应 15.5h， 以to give a polymer with a composition of 80/20 butyl methacrylate/methacrylic acid having 47.0% of solids的产率得到2-甲基丙烯酸与2-甲基丙烯酸丁酯的共聚物
  参考文献：
  名称：

  INK-JET INK COMPRISING ENCAPSULATED CROSS-LINKED PIGMENT DISPERSIONS

  摘要：

  本公开涉及一种喷墨墨水，该喷墨墨水是由含有分散剂的颜料分散液和由与交联剂交联的聚合物涂覆的颜料制成的。该聚合物在应用介质中膨胀，从而提高颜料分散液的稳定性。

  公开号：

  US20130225739A1

文献信息

• Procedure summary of water-based polymer resin doped titanium dioxide nanotubes as application corrosion coating.
  申请人：INSTITUTO MEXICANO DEL PETROLEO

  公开号：US20140039092A1

  公开（公告）日：2014-02-06

  The present invention relates to the application of polymeric resins and TiO2 doped with polymeric resins as coatings for external metal surfaces for industrial use, by selecting the following metals: stainless steel, carbon steel and copper. Focuses specifically on the synthesis of a polymeric resin waterborne corrosion consisting of nano-structured polymer particles formed with two or more acrylic monomers, vinyl or styrenic a functionalizing agent and a crosslinking agent from 1.0 to 20% w each. Doping addition is made of the same polymeric resins, which are incorporated in nanotubes of titanium dioxide in concentrations ranging from 50 to 10,000 ppm. The polymeric resin is water based corrosion synthesized by emulsion polymerization techniques and is during the synthesis process is introduced nanotube loading of titanium dioxide, which allowing the dispersion in the polymer matrix. Polymer dispersions obtained in this way are used as anti-corrosion coatings 100% water based.

  本发明涉及将聚合物树脂和掺有聚合物树脂的TiO2应用于选择以下金属（不锈钢、碳钢和铜）的工业用外部金属表面涂层。具体关注的是合成由两种或更多丙烯酸单体、乙烯基或苯乙烯官能化剂和交联剂形成的纳米结构聚合物颗粒的水基防腐蚀聚合物树脂。掺杂添加物由相同的聚合物树脂组成，这些聚合物树脂以50至10,000 ppm的浓度被纳入二氧化钛纳米管中。聚合物树脂是通过乳液聚合技术合成的水基防腐蚀，合成过程中引入了二氧化钛纳米管的负载，从而允许其在聚合物基质中分散。以这种方式获得的聚合物分散液被用作100%水基防腐蚀涂层。
• ENCAPSULATED CROSS-LINKED PIGMENT DISPERSIONS
  申请人：Spinelli Harry Joseph

  公开号：US20130214197A1

  公开（公告）日：2013-08-22

  The present disclosure provides pigment dispersions containing a dispersant, and a pigment coated by a polymer that is cross-linked with a crosslinker. The polymer swells in an application medium resulting in improved, stability for the pigment dispersions.

  本公开提供一种颜料分散液，其中包含分散剂和被交联剂交联的聚合物包覆的颜料。该聚合物在应用介质中膨胀，从而提高了颜料分散液的稳定性。
• PROCEDURE SUMMARY OF WATER-BASED POLYMER RESIN DOPED TITANIUM DIOXIDE NANOTUBES AS APPLICATION CORROSION COATING
  申请人：INSTITUTO MEXICANO DEL PETROLEO

  公开号：US20160272819A1

  公开（公告）日：2016-09-22

  The present invention relates to the application of polymeric resins and TiO2 doped with polymeric resins as coatings for external metal surfaces for industrial use, mainly by selecting the following metals: stainless steel, carbon steel and copper. Focuses specifically on the synthesis of a polymeric resin waterborne corrosion consisting of nano-structured polymer particles formed with two or more acrylic monomers, vinyl or styrenic a functionalizing agent and a crosslinking agent from 1.0 to 20% wt. each. Doping addition is made of the same polymeric resins, which are incorporated in nanotubes of titanium dioxide in concentrations ranging from 50 to 10,000 ppm. The polymeric resin is water based corrosion synthesized by emulsion polymerization techniques and is during the synthesis process is introduced nanotube loading of titanium dioxide (which are synthesized according to U.S. Pat. No. 7,645,439 B2), which allowing the dispersion in the polymer matrix. Polymer dispersions obtained in this way are used as anti-corrosion coatings 100% water based.

  本发明涉及聚合物树脂和掺杂聚合物树脂的TiO2作为外部金属表面的涂层应用于工业用途，主要选择以下金属：不锈钢、碳钢和铜。具体关注由两种或更多丙烯酸单体、乙烯基或苯乙烯官能化剂和交联剂形成的纳米结构聚合物颗粒组成的水基防腐蚀聚合物树脂的合成，每种成分的质量分数为1.0%至20%。掺杂添加是由相同的聚合物树脂制成的，其浓度范围从50至10,000 ppm，这些聚合物树脂被纳米管状二氧化钛所包含。聚合物树脂是通过乳液聚合技术合成的水基防腐蚀，合成过程中引入了纳米管状二氧化钛的负载（根据美国专利号7,645,439 B2合成），从而使其分散在聚合物基质中。以这种方式获得的聚合物分散液被用作100%水基的防腐涂层。
• "Living" polymers and process for their preparation
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0068887A1

  公开（公告）日：1983-01-05

  Process for preparing «living» polymers from acrylic- type or maleimide monomers and organosilicon, -tin or -germanium initiators, and the «living» polymers prepared thereby.

  用丙烯酸类或马来酰亚胺类单体和有机硅、锡或锗引发剂制备 "活 "聚合物的工艺，以及由此制备的 "活 "聚合物。
• Silver halide color photographic light-sensitive material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0161626A2

  公开（公告）日：1985-11-21

  A silver halide color photographic light-sensitive material containing a specific naphthol cyan dye forming coupler is disclosed. Dye images formed by this coupler are excellent in fastness to heat and light and in sharpness, and are free from adverse influences of a bleaching solution having weak oxidative activity or a fatigued bleaching solution.

  本发明公开了一种含有特定萘酚青染料形成耦合剂的卤化银彩色感光材料。由这种耦合剂形成的染料图像具有优异的耐热性、耐光性和清晰度，并且不受氧化活性弱的漂白液或疲劳漂白液的不利影响。