1,1,1-trichloro-2-hydroxy-undecan-4-one | 857473-66-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,1,1-trichloro-2-hydroxy-undecan-4-one
• 英文别名: 1,1,1-Trichlor-2-hydroxy-undecan-4-on；1,1,1-Trichloro-2-hydroxyundecan-4-one；1,1,1-trichloro-2-hydroxyundecan-4-one
• CAS: 857473-66-6
• 化学式: C₁₁H₁₉Cl₃O₂
• 分子量: 289.63
• InChiKey: QIUVBETZAYCJAZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,1,1-trichloro-2-hydroxy-undecan-4-one 在 氢氧化钾 作用下， 生成 (E)-4-oxoundec-2-enoic acid
  参考文献：
  名称：

  Random Packs and Their Use in Modeling Heterogeneous Solid Propellant Combustion

  摘要：

  It is shown that random packs of spheres of various sizes can be constructed that model ammonium-perchloratein-binder propellants in the sense that both the size distributions and the packing fractions of industrial propellant packs can be matched, Strategies for dealing with fractional numbers of large particles are addressed, as are strategies for dealing with a large number of very fine particles (fine powder), Fine powder is necessary in a three-dimensional pack to achieve the required stoichiometric ratio of ammonium perchlorate to fuel binder, but is not necessary in a two-dimensional (disk) pack, Some preliminary calculations of the two-dimensional combustion field supported by a disk pack are presented, in which full coupling between the gas phase, the condensed phase, and the retreating nonplanar propellant surface is accounted for.

  DOI：

  10.2514/2.5820
• 作为产物：
  描述：

  2-甲基辛醛 、 三氯乙醛 在 溶剂黄146 作用下， 生成 1,1,1-trichloro-2-hydroxy-undecan-4-one
  参考文献：
  名称：

  Random Packs and Their Use in Modeling Heterogeneous Solid Propellant Combustion

  摘要：

  It is shown that random packs of spheres of various sizes can be constructed that model ammonium-perchloratein-binder propellants in the sense that both the size distributions and the packing fractions of industrial propellant packs can be matched, Strategies for dealing with fractional numbers of large particles are addressed, as are strategies for dealing with a large number of very fine particles (fine powder), Fine powder is necessary in a three-dimensional pack to achieve the required stoichiometric ratio of ammonium perchlorate to fuel binder, but is not necessary in a two-dimensional (disk) pack, Some preliminary calculations of the two-dimensional combustion field supported by a disk pack are presented, in which full coupling between the gas phase, the condensed phase, and the retreating nonplanar propellant surface is accounted for.

  DOI：

  10.2514/2.5820

文献信息

• Process for preparing alpha-halogenated retones
  申请人：——

  公开号：US20030144541A1

  公开（公告）日：2003-07-31

  The invention concerns a method for preparing &agr;-halogenated ketones from secondary &agr;-halogenated alcohols. More particularly, the invention concerns the preparation of &agr;-trihalogenated ketones from secondary &agr;-trihalogenated alcohols. The method for preparing said &agr;-halogenated ketone is characterized in that it consists in oxidizing in liquid phase, a secondary &agr;-halogenated alcohol, using molecular oxygen or a gas containing same, in the presence of a catalyst based on a metal M 1 selected among metals of group 1b and 8 of the periodic system of elements and optionally an activating element.

  本发明涉及一种从次级α-卤代醇制备α-卤代酮的方法。更具体地，本发明涉及从次级α-三卤代醇制备α-三卤代酮的方法。制备所述α-卤代酮的方法的特征在于，在液相中使用分子氧或含有分子氧的气体，在金属M1基催化剂的存在下，氧化次级α-卤代醇，并且金属M1被选自元素周期表中的1b和8组金属，可选激活元素。
• PROCEDE DE PREPARATION DE CETONES ALPHA-HALOGENEES
  申请人：RHODIA CHIMIE

  公开号：EP1250303A1

  公开（公告）日：2002-10-23
• [EN] METHOD FOR PREPARING ALPHA-HALOGENATED KETONES<br/>[FR] PROCEDE DE PREPARATION DE CETONES ALPHA-HALOGENEES
  申请人：RHODIA CHIMIE SA

  公开号：WO2001055067A1

  公开（公告）日：2001-08-02

  La présente invention a pour objet un procédé de préparation de cétones α-halogènées à partir d'alcools secondaires α-halogénés. L'invention vise plus particulièrement la préparation de cétones α-trihalogénées à partir d'alcools secondaires α-trihalogénés. Le procédé de préparation d'une cétone α-halogénée selon l'invention est caractérisé par le fait qu'il consiste à oxyder en phase liquide, un alcool secondaire α-halogéné, à l'aide d'oxygène moléculaire ou un gaz en contenant, en présence d'un catalyseur à base d'un métal M1 choisi parmi les métaux du groupe 1b et 8 de la classification périodique des éléments et éventuellement d'un activateur.
• Random Packs and Their Use in Modeling Heterogeneous Solid Propellant Combustion
  作者：S. Kochevets、J. Buckmaster、T. L. Jackson、A. Hegab

  DOI：10.2514/2.5820

  日期：2001.7

  It is shown that random packs of spheres of various sizes can be constructed that model ammonium-perchloratein-binder propellants in the sense that both the size distributions and the packing fractions of industrial propellant packs can be matched, Strategies for dealing with fractional numbers of large particles are addressed, as are strategies for dealing with a large number of very fine particles (fine powder), Fine powder is necessary in a three-dimensional pack to achieve the required stoichiometric ratio of ammonium perchlorate to fuel binder, but is not necessary in a two-dimensional (disk) pack, Some preliminary calculations of the two-dimensional combustion field supported by a disk pack are presented, in which full coupling between the gas phase, the condensed phase, and the retreating nonplanar propellant surface is accounted for.