6-n-decyl-2-hydroxynaphthalene | 146204-27-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 6-n-decyl-2-hydroxynaphthalene
• 英文别名: 6-decylnaphthalen-2-ol；6-Decyl-2-hydroxynaphthalene
• CAS: 146204-27-5
• 化学式: C₂₀H₂₈O
• 分子量: 284.442
• InChiKey: HDPIFCMWWRJOFY-UHFFFAOYSA-N

物化性质

• 沸点：
  428.8±14.0 °C(Predicted)
• 密度：
  0.991±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  21
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  6-n-decyl-2-hydroxynaphthalene 在 吡啶 、 正丁基锂 、 三溴化硼 、 sodium hydride 作用下， 以 四氢呋喃 、 正己烷 、 二氯甲烷 、 mineral oil 为溶剂， 反应 44.09h， 生成 6-decyl-3-methylthio-2-naphthyl trifluoromethanesulfonate
  参考文献：
  名称：

  NOVEL HETEROCYCLIC COMPOUND, METHOD FOR PRODUCING INTERMEDIATE THEREFOR, AND USE THEREOF

  摘要：

  公开号：

  EP2679592B1
• 作为产物：
  描述：

  2-decanoyl-6-methoxynaphthalene 在 氢氧化钾 、 氢溴酸 、 一水合肼 、 溶剂黄146 作用下， 以 乙二醇 为溶剂， 生成 6-n-decyl-2-hydroxynaphthalene
  参考文献：
  名称：

  Synthesis and Characterization of Liquid Crystalline Semiconducting Materials, Dialkyl-2-phenylnaphthalene Derivatives—Mesomorphic behavior and Charge carrier transport

  摘要：

  For establishment of high electronic charge carrier transport at ambient temperature, dialkyl derivatives of 2-phenylnaphthalene have been synthesized and characterized their liquid crystalline behaviors and photoelectrical properties. These materials exhibited smectic mesophases (Smectic A, B and E phases), at fairly low temperature range extended down below ambient temperature. Fast electronic transport of positive carriers was observed in SmE phase of 2-(4'-octylphenyl)-6-butylnaphthalene at 30degreesC, whose mobility was over 10(-2) cm(2)/Vs.

  DOI：

  10.1080/15421400490435251

文献信息

• Liquid crystal compounds and compositions
  申请人：SANYO CHEMICAL INDUSTRIES LTD.

  公开号：EP0517498A1

  公开（公告）日：1992-12-09

  Liquid crystal naphtalene compounds, represented by the following formula (1) are disclosed.         R-Z-A-NAP-Z′-R′   (1) In the formula (1), R is an alkyl group containing 1 to 18 carbon atoms; R′ is an alkyl group containing 1 to 21 carbon atoms; NAP represents 2,6-naphthylene group; A, Z and Z′ are as follows: 1) A is Pyr> and (a) Z is - or # and Z′ is O, or (b) Z is - and Z′ is COO; 2) if A is Pym>, (a) Z is - and Z′ is O, or (b) Z is O and Z′ is -, O or #; 3) A is FPhF and (a) Z is - or O and Z′ is -, O or COO, (b) Z is OCO and Z′ is - or O, or (c) Z is # and Z′ is O; 4) A is PhF and (a) Z is - or # and Z′ is O, (b) Z is O and Z′ is -, or (c) Z is - and Z′ is COO; 5) A is FPh and (a) Z is O and Z′ is-, (b) Z is -, O, # or OCO and Z′ is O, or (c) Z is O and Z′ is COO; 6) A is

  液晶萘化合物的化学式如下所示：R-Z-A-NAP-Z′-R′。在这个化学式中，R是含有1到18个碳原子的烷基基团；R′是含有1到21个碳原子的烷基基团；NAP代表2,6-萘基团；A、Z和Z′的具体定义如下： 1）如果A是Pyr，(a) Z是-或#，Z′是O；或者(b) Z是-，Z′是COO； 2）如果A是Pym，(a) Z是-，Z′是O；或者(b) Z是O，Z′是-、O或#； 3）如果A是FPhF，(a) Z是-或O，Z′是-、O或COO；(b) Z是OCO，Z′是-或O；或者(c) Z是#，Z′是O； 4）如果A是PhF，(a) Z是-或#，Z′是O；(b) Z是O，Z′是-；或者(c) Z是-，Z′是COO； 5）如果A是FPh，(a) Z是O，Z′是-；(b) Z是-、O、#或OCO，Z′是O；或者(c) Z是O，Z′是COO； 6）如果A是
• The Interrupted Pummerer Reaction in a Sulfoxide‐Catalyzed Oxidative Coupling of 2‐Naphthols
  作者：Zhen He、Alexander P. Pulis、David J. Procter

  DOI：10.1002/anie.201903492

  日期：2019.6.3

  A benzothiophene S‐oxide catalyst, generated in situ by sulfur oxidation with H2O2, mediates the oxidative coupling of 2‐naphthols. Key to the catalytic process is the capture and inversion of reactivity of a 2‐naphthol partner, using an interrupted Pummerer reaction of an unusual benzothiophene S‐oxide, followed by subsequent coupling with a second partner. The new catalytic manifold has been showcased

  通过H 2 O 2硫氧化原位生成的苯并噻吩S-氧化物催化剂介导2-萘酚的氧化偶联。催化过程的关键是使用不寻常的苯并噻吩S-氧化物中断的Pummerer反应，然后与第二个配偶偶合，捕获和转化2-萘酚配偶的反应性。新的催化歧管已在生物活性天然产物（±）-尼莫酮和（±）-异麦酮的合成中得到展示。尽管Pummerer反应被广泛使用，但它们在催化中的应用却很少，我们的方法代表了一种新的无金属C-C键形成的催化流形。
• Novel Heterocyclic Compound, Method For Producing Intermediate Therefor, And Use Thereof
  申请人：Takimiya Kazuo

  公开号：US20130330876A1

  公开（公告）日：2013-12-12

  Provided are a novel heterocyclic compound represented by formula (1), and a field-effect transistor having a semiconductor layer comprising the aforementioned compound. Also provided is a method for producing an intermediate enabling the production of the aforementioned novel heterocyclic compound. (In the formula, R 1 and R 2 represent a hydrogen atom, a C 2-16 alkyl group or an aryl group. However, when R 1 each independently represents a C 2-16 alkyl group or an aryl group, R 2 represents a hydrogen atom or each independently represents an aryl group; and when R 1 represents a hydrogen atom, R 2 each independently represents an aryl group.)

  提供了一种由式（1）表示的新型杂环化合物，以及具有包含上述化合物的半导体层的场效应晶体管。还提供了一种生产中间体以便生产上述新型杂环化合物的方法。（在式中，R1和R2表示氢原子，C2-16烷基或芳基。但是，当R1各自独立表示C2-16烷基或芳基时，R2表示氢原子或各自独立表示芳基;当R1表示氢原子时，R2各自独立表示芳基。）
• Heterocyclic dinaphtho thieno thiophene (DNTT) compounds for use as organic semiconductor thin films in field effect transistors and related methods
  申请人：Takimiya Kazuo

  公开号：US09018630B2

  公开（公告）日：2015-04-28

  Provided are a novel heterocyclic compound represented by formula (1), and a field-effect transistor having a semiconductor layer comprising the aforementioned compound. Also provided is a method for producing an intermediate enabling the production of the aforementioned novel heterocyclic compound. (In the formula, R1 and R2 represent a hydrogen atom, a C2-16 alkyl group or an aryl group. However, when R1 each independently represents a C2-16 alkyl group or an aryl group, R2 represents a hydrogen atom or each independently represents an aryl group; and when R1 represents a hydrogen atom, R2 each independently represents an aryl group.)

  提供了一种由式(1)表示的新型杂环化合物，以及具有包括上述化合物的半导体层的场效应晶体管。还提供了一种生产使上述新型杂环化合物的生产成为可能的中间体的方法。(在式中，R1和R2代表氢原子、C2-16烷基或芳基。但是，当R1各自独立地表示C2-16烷基或芳基时，R2表示氢原子或各自独立地表示芳基；当R1表示氢原子时，R2各自独立地表示芳基。)
• Novel heterocyclic compound, method for producing intermediate therefor, and use thereof
  申请人：NIPPON KAYAKU KABUSHIKI KAISHA

  公开号：EP2889301A1

  公开（公告）日：2015-07-01

  Provided are a novel heterocyclic compound represented by formula (1), and a field-effect transistor having a semiconductor layer comprising the aforementioned compound. Also provided is a method for producing an intermediate enabling the production of the aforementioned novel heterocyclic compound. In the formula (1), each R1 independently represents a C2-16 alkyl group and each R2 represents a hydrogen atom.

  本发明提供了一种由式（1）表示的新型杂环化合物，以及一种具有包含上述化合物的半导体层的场效应晶体管。还提供了一种生产上述新型杂环化合物的中间体的方法。在式 (1) 中，每个 R1 独立地代表一个 C2-16 烷基，每个 R2 代表一个氢原子。