(Z)-9-Tetradecenyl nitrate | 143816-21-1

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: (Z)-9-Tetradecenyl nitrate
• 英文别名: [(Z)-tetradec-9-enyl] nitrate
• CAS: 143816-21-1
• 化学式: C₁₄H₂₇NO₃
• 分子量: 257.373
• InChiKey: GOXHVGMEFOPASR-WAYWQWQTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  18
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  55
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  9-十四碳炔-1-醇 在 Lindlar's catalyst 氢气 、 硝酸 、 乙酸酐 作用下， 以 Petroleum ether 为溶剂， 生成 (Z)-9-Tetradecenyl nitrate
  参考文献：
  名称：

  Nitrate esters: Novel sex pheromone components of the cotton leafperforator, Bucculatrix thurberiella busck. (Lepidoptera: Lyonetiidae)

  摘要：

  (Z)-9-Tetradecenyl nitrate and (Z)-8-tridecenyl nitrate have been identified in volatiles from virgin female cotton leafperforator moths, Bucculatrix thurberiella, and shown to elicit electroantennogram responses from male moths. A 100:2 blend of the synthetic compounds is highly attractive to male moths in the field, and these compounds are proposed to be components of the female sex pheromone.

  DOI：

  10.1016/s0040-4039(00)61292-3

文献信息

• PRODUCTION OF FATTY OLEFIN DERIVATIVES VIA OLEFIN METATHESIS
  申请人：PROVIVI, INC.

  公开号：US20170137365A1

  公开（公告）日：2017-05-18

  In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I with a metathesis reaction partner according to Formula IIb in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb: and b) converting the metathesis product to the fatty olefin derivative. Each R 1 is independently selected from H, C 1-18 alkyl, and C 2-18 alkenyl; R 2b is C 1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.

  在一个方面，该发明提供了一种合成脂肪烯衍生物的方法。该方法包括：a）在存在一种烯烃催化剂的条件下，将符合式I的烯烃与符合式IIb的交换反应伙伴接触，以形成符合式IIIb的交换产物；并b）将交换产物转化为脂肪烯衍生物。每个R1独立地选择自H、C1-18烷基和C2-18烯基；R2为C1-8烷基；下标y为0至17之间的整数；下标z为0至17之间的整数。在某些实施方式中，交换催化剂为钨催化剂或钼催化剂。在各种实施方式中，脂肪烯衍生物为信息素。还描述了信息素组合物及其使用方法。
• Production of fatty olefin derivatives via olefin metathesis
  申请人：Provivi, Inc.

  公开号：US10596562B2

  公开（公告）日：2020-03-24

  In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I with a metathesis reaction partner according to Formula IIb in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb: and b) converting the metathesis product to the fatty olefin derivative. Each R1 is independently selected from H, C1-18 alkyl, and C2-18 alkenyl; R2b is C1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.

  一方面，本发明提供了一种合成脂肪烯烃衍生物的方法。该方法包括： a) 将符合式 I 的烯烃 与符合式 IIb 的偏析反应物接触 在偏析催化剂存在下，在足以形成符合式 IIIb 的偏析产物的条件下： 和 b) 将偏析产物转化为脂肪烯烃衍生物。每个 R1 独立选自 H、C1-18 烷基和 C2-18 烯基；R2b 是 C1-8 烷基；下标 y 是 0 至 17 的整数；下标 z 是 0 至 17 的整数。在某些实施方案中，偏合成催化剂是钨催化剂或钼催化剂。在各种实施方案中，脂肪烯烃衍生物是信息素。还描述了信息素组合物及其使用方法。
• US9776179B2
  申请人：——

  公开号：US9776179B2

  公开（公告）日：2017-10-03
• [EN] INSECTICIDAL AND ACARICIDAL COMPOSITIONS WITH UV BLOCKERS AND PHEROMONES<br/>[FR] COMPOSITIONS INSECTICIDES ET ACARICIDES A FILTRES ANTI-UV ET A PHEROMONES
  申请人：SIRENE CALL PTY LTD

  公开号：WO2005016385A1

  公开（公告）日：2005-02-24

  The invention is a composition consisting of at least one pesticidally active compound, at least one pheromone, at least one liquid UV absorber that is only sparingly miscible in water and least one optical brightener that is also only sparingly miscible with water, castor oil and at least two viscosity regulators. The composition remains viscous and sticky after application. The composition is very suitable for controlling undesirable Ecto-Parasites from the order Acarina on livestock, notably cattle and domestic animals as well as members of the order Artiodactyle (deer) without harming the treated animal or adversely impacting on the environment or the ecology, or creating pesticide residues.
• Nitrate esters: Novel sex pheromone components of the cotton leafperforator, Bucculatrix thurberiella busck. (Lepidoptera: Lyonetiidae)
  作者：David R. Hall、Peter S. Beevor、Derek G. Campion、David J. Chamberlain、Alan Cork、Rosemary D. White、Aurelio Almestar、Thomas J. Henneberry

  DOI：10.1016/s0040-4039(00)61292-3

  日期：1992.8

  (Z)-9-Tetradecenyl nitrate and (Z)-8-tridecenyl nitrate have been identified in volatiles from virgin female cotton leafperforator moths, Bucculatrix thurberiella, and shown to elicit electroantennogram responses from male moths. A 100:2 blend of the synthetic compounds is highly attractive to male moths in the field, and these compounds are proposed to be components of the female sex pheromone.