8-azidooctane-1-thiol | 1428533-94-1

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: 8-azidooctane-1-thiol
• 英文别名: 8-Azidooctane-1-thiol
• CAS: 1428533-94-1
• 化学式: C₈H₁₇N₃S
• 分子量: 187.309
• InChiKey: ZDYFFZROLBHBLL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  15.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  8-溴-1-辛醇 在 sodium azide 、 硫脲 、 三氟乙酸酐 作用下， 以 四氢呋喃 、 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 28.41h， 生成 8-azidooctane-1-thiol
  参考文献：
  名称：

  Reactions in Elastomeric Nanoreactors Reveal the Role of Force on the Kinetics of the Huisgen Reaction on Surfaces

  摘要：

  The force dependence of the copper-free Huisgen cycloaddition between an alkyne and a surface-bound azide was examined in elastomeric nanoreactors. These studies revealed that pressure and chain length are critical factors that determine the reaction rate. These experiments demonstrate the central role of pressure and surface structure on interfacial processes that are increasingly important in biology, materials science, and nanotechnology.

  DOI：

  10.1021/ja504137u

文献信息

• ASYMMETRIC CYANINE DYES FOR PHOTOVOLTAIC APPLICATIONS
  申请人：Caputo Giuseppe

  公开号：US20140246094A1

  公开（公告）日：2014-09-04

  Asymmetric dyes of the D-π-A type have the Formula (1), including the valence tautomers thereof. The dyes of Formula (1) are suitable for use in dye-sensitized solar cells (DSSC), in photoelectrochemical devices or in photonic devices. A solar cell and a device for photoelectric conversion contain an asymmetric dye of Formula (1). The dyes of Formula (1) are also suitable for conjugating with optically active nanoparticles (NP).
• Reactions in Elastomeric Nanoreactors Reveal the Role of Force on the Kinetics of the Huisgen Reaction on Surfaces
  作者：Xu Han、Shudan Bian、Yong Liang、K. N. Houk、Adam B. Braunschweig

  DOI：10.1021/ja504137u

  日期：2014.7.30

  The force dependence of the copper-free Huisgen cycloaddition between an alkyne and a surface-bound azide was examined in elastomeric nanoreactors. These studies revealed that pressure and chain length are critical factors that determine the reaction rate. These experiments demonstrate the central role of pressure and surface structure on interfacial processes that are increasingly important in biology, materials science, and nanotechnology.