tris(2-di(tert-butyl)phosphinoethyl)phosphine | 1360110-13-9

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: tris(2-di(tert-butyl)phosphinoethyl)phosphine
• 英文别名: P(CH2CH2PtBu2)3；Tris(2-ditert-butylphosphanylethyl)phosphane；tris(2-ditert-butylphosphanylethyl)phosphane
• CAS: 1360110-13-9
• 化学式: C₃₀H₆₆P₄
• 分子量: 550.749
• InChiKey: BLRNQLHBKHQRGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  34
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  tris(triphenylphosphine)ruthenium(II) chloride 、 tris(2-di(tert-butyl)phosphinoethyl)phosphine 以 四氢呋喃 为溶剂， 以45%的产率得到dichloro(tris(2-di(tert-butyl)phosphinoethyl)phosphine-κ3P)ruthenium(II)
  参考文献：
  名称：

  New Superhindered Polydentate Polyphosphine Ligands P(CH₂CH₂P^tBu₂)₃, PhP(CH₂CH₂P^tBu₂)₂, P(CH₂CH₂CH₂P^tBu₂)₃, and their Ruthenium(II) Chloride Complexes

  摘要：

  The synthesis and characterization of the extremely hindered phosphine ligands, P((CH2CH2PBu2)-Bu-t)(3) ((PP3tBu)-P-2, 1), PhP((CH2CH2PBu2)-Bu-t)(2) (PhP(2)p(2)(tBu), 2), and P((CH2CH2CH2PBu2)-Bu-t)(3) ((PP3tBu)-P-3, 3) are reported, along with the synthesis and characterization of ruthenium chloro complexes RuCl2((PP3tBu)-P-2) (4), RuCl2((PhPP2tBu)-P-2) (5), and RuCl2((PP3tBu)-P-3) (6). The bulky (PP3tBu)-P-2 (1) and (PP3tBu)-P-3 (3) ligands are the most sterically encumbered PP3-type ligands so far synthesized, and in all cases, only three phosphorus donors are able to bind to the metal center. Complexes RuCl2((PhPP2tBu)-P-2) (5) and RuCl2((PP3tBu)-P-3) (6) were characterized by crystallography. Low temperature solution and solid state P-31{H-1} NMR were used to demonstrate that the structure of RuCl2((PP3tBu)-P-3) (4) is probably analogous to that of RuCl2((PP3tBu)-P-3) (5) which had been structurally characterized.

  DOI：

  10.1021/ic2027169
• 作为产物：
  描述：

  三乙烯基膦 、 二-叔丁基膦 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 、 乙醚 、 正己烷 为溶剂， 反应 1.0h， 以78%的产率得到tris(2-di(tert-butyl)phosphinoethyl)phosphine
  参考文献：
  名称：

  New Superhindered Polydentate Polyphosphine Ligands P(CH₂CH₂P^tBu₂)₃, PhP(CH₂CH₂P^tBu₂)₂, P(CH₂CH₂CH₂P^tBu₂)₃, and their Ruthenium(II) Chloride Complexes

  摘要：

  The synthesis and characterization of the extremely hindered phosphine ligands, P((CH2CH2PBu2)-Bu-t)(3) ((PP3tBu)-P-2, 1), PhP((CH2CH2PBu2)-Bu-t)(2) (PhP(2)p(2)(tBu), 2), and P((CH2CH2CH2PBu2)-Bu-t)(3) ((PP3tBu)-P-3, 3) are reported, along with the synthesis and characterization of ruthenium chloro complexes RuCl2((PP3tBu)-P-2) (4), RuCl2((PhPP2tBu)-P-2) (5), and RuCl2((PP3tBu)-P-3) (6). The bulky (PP3tBu)-P-2 (1) and (PP3tBu)-P-3 (3) ligands are the most sterically encumbered PP3-type ligands so far synthesized, and in all cases, only three phosphorus donors are able to bind to the metal center. Complexes RuCl2((PhPP2tBu)-P-2) (5) and RuCl2((PP3tBu)-P-3) (6) were characterized by crystallography. Low temperature solution and solid state P-31{H-1} NMR were used to demonstrate that the structure of RuCl2((PP3tBu)-P-3) (4) is probably analogous to that of RuCl2((PP3tBu)-P-3) (5) which had been structurally characterized.

  DOI：

  10.1021/ic2027169

文献信息

• New Superhindered Polydentate Polyphosphine Ligands P(CH₂CH₂P^<i>t</i>Bu₂)₃, PhP(CH₂CH₂P^<i>t</i>Bu₂)₂, P(CH₂CH₂CH₂P^<i>t</i>Bu₂)₃, and their Ruthenium(II) Chloride Complexes
  作者：Ryan Gilbert-Wilson、Leslie D. Field、Mohan M. Bhadbhade

  DOI：10.1021/ic2027169

  日期：2012.3.5

  The synthesis and characterization of the extremely hindered phosphine ligands, P((CH2CH2PBu2)-Bu-t)(3) ((PP3tBu)-P-2, 1), PhP((CH2CH2PBu2)-Bu-t)(2) (PhP(2)p(2)(tBu), 2), and P((CH2CH2CH2PBu2)-Bu-t)(3) ((PP3tBu)-P-3, 3) are reported, along with the synthesis and characterization of ruthenium chloro complexes RuCl2((PP3tBu)-P-2) (4), RuCl2((PhPP2tBu)-P-2) (5), and RuCl2((PP3tBu)-P-3) (6). The bulky (PP3tBu)-P-2 (1) and (PP3tBu)-P-3 (3) ligands are the most sterically encumbered PP3-type ligands so far synthesized, and in all cases, only three phosphorus donors are able to bind to the metal center. Complexes RuCl2((PhPP2tBu)-P-2) (5) and RuCl2((PP3tBu)-P-3) (6) were characterized by crystallography. Low temperature solution and solid state P-31H-1} NMR were used to demonstrate that the structure of RuCl2((PP3tBu)-P-3) (4) is probably analogous to that of RuCl2((PP3tBu)-P-3) (5) which had been structurally characterized.