2,2-dimethyl-6,6-difluoro-6-trifluoromethoxyhexane-3,5-dione | 61894-06-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,2-dimethyl-6,6-difluoro-6-trifluoromethoxyhexane-3,5-dione
• 英文别名: 1-trifluoromethoxy-1,1-difluoro-5,5-dimethylhexanedione-2,4；1,1-Difluoro-5,5-dimethyl-1-(trifluoromethoxy)hexane-2,4-dione
• CAS: 61894-06-2
• 化学式: C₉H₁₁F₅O₃
• 分子量: 262.177
• InChiKey: MMQBZJXQJGQEHQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  neodymium(III) chloride 、 2,2-dimethyl-6,6-difluoro-6-trifluoromethoxyhexane-3,5-dione 以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  IR Luminescence of Nd3+, Sm3+, and Yb3+ β-Diketonates in Different Aggregate States

  摘要：

  The influence of the aggregate state on the IR luminescence is studied for the Nd(III), Sm(III), and Yb(III) complexes with the thienyl, phenyl, and alkyl derivatives of acetylacetone in solutions and as sorbates on the polymer matrix. It is found that the luminescence intensity of the sorbates of the complexes is 2-3 orders of magnitude higher than that in solutions due to the elimination of diffusion and respective intermolecular nonradiative losses of the excitation energy.

  DOI：

  10.1134/s1070328417090056
• 作为产物：
  描述：

  Difluor-trifluormethoxy-essigsaeure-methylester 、 频哪酮 以41%的产率得到
  参考文献：
  名称：

  SHIVANYUK, A. F.;KUDRYAVTSEVA, L. S.;LOZINSKIJ, M. O.;NEPLYUEV, V. M.;FIA+, YKP. XIM. ZH., 1981, 47, N 10, 1078-1085

  摘要：

  DOI：

文献信息

• Goryushko, A. G.; Davidenko, N. K.; Kudryavtseva, L. S., Russian Journal of Inorganic Chemistry, 1980, vol. 25, p. 1327 - 1331
  作者：Goryushko, A. G.、Davidenko, N. K.、Kudryavtseva, L. S.、Lozinskii, M. O.、Lugina, L. N.、Fialkov, Yu. A.

  DOI：——

  日期：——
• Mass spectrometric study of fluorinated ?-diketonates of europium
  作者：V. S. Khomenko、M. O. Lozinskii、Yu. A. Fialkov、T. A. Rasshinina、V. P. Suboch

  DOI：10.1007/bf00516854

  日期：——
• IR Luminescence of Nd3+, Sm3+, and Yb3+ β-Diketonates in Different Aggregate States
  作者：S. B. Meshkova、P. G. Doga、A. A. Kucher

  DOI：10.1134/s1070328417090056

  日期：2017.10

  The influence of the aggregate state on the IR luminescence is studied for the Nd(III), Sm(III), and Yb(III) complexes with the thienyl, phenyl, and alkyl derivatives of acetylacetone in solutions and as sorbates on the polymer matrix. It is found that the luminescence intensity of the sorbates of the complexes is 2-3 orders of magnitude higher than that in solutions due to the elimination of diffusion and respective intermolecular nonradiative losses of the excitation energy.
• SHIVANYUK, A. F.;KUDRYAVTSEVA, L. S.;LOZINSKIJ, M. O.;NEPLYUEV, V. M.;FIA+, YKP. XIM. ZH., 1981, 47, N 10, 1078-1085
  作者：SHIVANYUK, A. F.、KUDRYAVTSEVA, L. S.、LOZINSKIJ, M. O.、NEPLYUEV, V. M.、FIA+

  DOI：——

  日期：——